Combined arrays

Agrafiotis, D.K. and Lobanov, V.S. Ultrafast algorithm for designing focused combinational arrays./. Chem. Inf Comput. Sci. 2000, 40,1030-1038. 

Borkowski and Lucas (1997) further explored the construction of combined array designs. The important contribution in their approach was to set up a framework for the different requirements on design resolution for different types of effects in robust design experiments. They proposed the concept of mixed resolution to characterize separately the resolution of the design for effects involving only design factors, only noise factors, or interactions between design and noise factors. 

Complete general-purpose array-deleclor-based specirophoiomciers are available commercially for 50(X) to 10,000 and up. Several instrument companies combine array-detector systems with fiber-optic prt)bcs that transport the light to and from the sample. 

Performance has been greatly improved by the introduction of hybrid instruments that combine arrays of one or more quadrupole elements with TOF analyzers. In these types of configuration, MALDI-ions are initially desorbed into a source region at an intermediate pressure of about one to a few millibars, where they experience coUisional cooUng to Umit fragmentation. From the source region they are extracted into a quadmpole mass filter and subsequently are transmitted... 

Since the development of grazing incidence x-ray diffraction, much of the convincing evidence for long-range positional order in layers has come from this technique. Structural relaxations from distorted hexagonal structure toward a relaxed array have been seen in heneicosanol [215]. Rice and co-workers combine grazing incidence x-ray diffraction with molecular dynamics simulations to understand several ordering transitions [178,215-219]. 

To obtain an effective algorithm for substructure searching the factorial degree of the brute force algorithm has to be drastically deaeased. In the next sections we discuss several approaches where combination leads to a much more effective and apphcable approach for substructure searching. In the process of searching the isomorphism between Gq and a substructure of Gx, the partial mappings Gq —> Gj can be used as well. In these cases, not all atoms from Gq are mapped and, for those which are not, the array value Mj is set to 0. 

Slater showed that spinorbitals, arrayed as a determinant, change sign on election exchange so as to obey the Pauli principle. If we wi ite a linear combination of two spinorbitals as a determinant where we assume the space parts are the same but the spin parts are not the same... 

A multipoint ion collector (also called the detector) consists of a large number of miniature electron multiplier elements assembled, or constructed, side by side over a plane. A multipoint collector can be an array, which detects a dispersed beam of ions simultaneously over a range of m/z values and is frequently used with a sector-type mass spectrometer. Alternatively, a microchannel plate collector detects all ions of one m/z value. When combined with a TOP analyzer, the microchannel plate affords an almost instantaneous mass spectrum. Because of their construction and operation, microchannel plate detectors are cheaper to fit and maintain. Multipoint detectors are particularly useful for situations in which ionization occurs within a very short space of time, as with some ionization sources, or in which only trace quantities of any substance are available. For such fleeting availability of ions, only multipoint collectors can measure a whole spectrum or part of a spectrum satisfactorily in the short time available. 

The abihty to tap an array of iron units to provide flexibiUty in all parts of the business cycle is a topic of great interest in keeping costs of raw steel down in the international arena. This is being combined with efforts to reduce the time for a given process by even a few seconds. 

A progressive etching technique (39,40), combined with x-ray diffraction analysis, revealed the presence of a number of a polytypes within a single crystal of sihcon carbide. Work using lattice imaging techniques via transmission electron microscopy has shown that a-siUcon carbide formed by transformation from the P-phase (cubic) can consist of a number of the a polytypes in a syntactic array (41). 

There has been a tremendous change in the last two decades as computers have taken over the tedious calculations involved in color measurement. Indeed, microprocessors either are built into or are connected to all modem instmments, so that the operator may merely need to specify, for example, x,j, Y or T, i , b or T, (A, b, either for the 2° or the 10° observer, and for a specific standard illiiminant, to obtain the desired color coordinates or color differences, all of which can be stored for later reference or computation. The use of high intensity filtered Xenon flash lamps and array detectors combined with computers has resulted in almost instantaneous measurement in many instances. 

As for oil and gas, the burner is the principal device required to successfully fire pulverized coal. The two primary types of pulverized-coal burners are circular concentric and vertical jet-nozzle array burners. Circular concentric burners are the most modem and employ swid flow to promote mixing and to improve flame stabiUty. Circular burners can be single or dual register. The latter type was designed and developed for NO reduction. Either one of these burner types can be equipped to fire any combination of the three principal fuels, ie, coal, oil and gas. However, firing pulverized coal with oil in the same burner should be restricted to short emergency periods because of possible coke formation on the pulverized-coal element (71,72). 

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