Coefficient of wear

Sasaki [223] studied the influence of humidity on friction and wear behavior of SiC/SiC couples. It was shown that humidity decreased the coefficient of friction from 0.5 (dry air) to 0.2 (wet air), simultaneously a decrease in the coefficient of wear was observed from 10 (dry air) to 10 mm N m . ... 

It resembles polytetrafiuoroethylene and fiuorinated ethylene propylene in its chemical resistance, electrical properties, and coefficient of friction. Its strength, hardness, and wear resistance are about equal to the former plastic and superior to that of the latter at temperatures above 150°C. 

Positive-displacement meters are normally rated for a limited temperature range. Meters can be constmcted for high or low temperature use by adjusting the design clearance to allow for differences in the coefficient of thermal expansion of the parts. Owing to small operating clearances, filters are commonly installed before these meters to minimize seal wear and resulting loss of accuracy. 

Surface Fluorination of Polymers. Fluorocarbon-coated objects have many practical appHcations because the chemically adherent surface provides increased thermal stabiHty, resistance to oxidation and corrosive chemicals and solvents, decreased coefficient of friction and thus decreased wear, and decreased permeabiHty to gas flow. Unusual surface effects can be obtained by fluorinating the polymer surfaces only partially (74). 

Static friction decreases with an increase in load, and the static coefficient of friction is lower than the dynamic coefficient. The tendency to creep must be considered carefliUy in FEP products designed for service under continuous stresses. Creep can be minimized by suitable fillers. Fillets are also used to improve wear resistance and stiffness. Compositions such as 30% bronze-fiUed FEP, 20% graphite-filled FEP, and 10% glass-fiber-filled FEP offer high PV values ( 400(kPa-m)/s) and are suitable for beatings. 

Unfilled Teflon PFA has been tested in mechanical appHcations using Teflon FEP-100 as a control (24). Tests were mn on molded thmst bearings at 689.5 kPa (100 psi) against AISI 1080, Rc 20,16AA steel, and at ambient conditions in air without lubrication. A limiting PV value of 5000 was found. Wear factors and dynamic coefficients of friction are shown in Table 4. 

Velocity, m /min Wear factor Dynamic K X 10-", 1/Pa " coefficient of friction Test duration, h... 

PTFE is outstanding in this group. In thin films it provides the lowest coefficient of friction (0.03—0.1) of any polymer, is effective from —200 to 250°C, and is generally unreactive chemically. The low friction is attributed to the smooth molecular profile of PTFE chains which allows easy sliding (57). Typical apphcations include chemical and food processing equipment, electrical components, and as a component to provide improved friction and wear in other resin systems. 

For wear resistance and low friction, coatings of PTFE or M0S2 generally have been satisfactory. Use of low thermal expansion filler in PTFE helps minimise cracking and loss of adhesion from metal substrates with their lower coefficients of expansion. 

Friction Materials. PhenoHc friction materials are made from mol ding compounds developed to meet the extraordinary demands required by friction elements in the transportation industries. Friction materials are used for brake linings, clutch facings, and transmission bands. A moderately high coefficient of friction, which is temperature-independent, is needed. In addition, the material must be high in strength, low in wear and abrasion, and resistant to moisture and hydrauHc fluids. 

A hard, mst-resistant shaft of at least 0.25 micrometer finish is usually required. Common shaft surfaces are hardened tool steel, chrome plate, high strength bronze, and carbide and ceramic overlays. Test results over a broad speed range from 0.05 to 47 m/s (10 to 9200 fpm) iadicate that a coefficient of friction of 0.16—0.20 and a wear factor of 14 X 10 m /N(70x 10 ° in. min/ft-lb-h) are typical for dry operation of weU appHed grades of carbon—graphite (29). 

Hard plating is noted for its excellent hardness, wear resistance, and low coefficient of friction. Decorative plating retains its brilliance because air exposure immediately forms a thin, invisible protective oxide film. The chromium is not appHed directiy to the surface of the base metal but rather over a nickel (see Nickel and nickel alloys) plate, which in turn is laid over a copper (qv) plate. Because the chromium plate is not free of cracks, pores, and similar imperfections, the intermediate nickel layer must provide the basic protection. Indeed, optimum performance is obtained when a controlled but high density (40—80 microcrack intersections per linear millimeter) of microcracks is achieved in the chromium lea ding to reduced local galvanic current density at the imperfections and increased cathode polarization. A duplex nickel layer containing small amounts of sulfur is generally used. In addition to... 

The friction and wear of plastics are extremely complex subjects which depend markedly on the nature of the application and the properties of the material. The frictional properties of plastics differ considerably from those of metals. Even reinforced plastics have modulus values which are much lower than metals. Hence metal/thermoplastic friction is characterised by adhesion and deformation which results in frictional forces that are not proportional to load but rather to speed. Table 1.7 gives some typical coefficients of friction for plastics. 

Coefficients of friction and relative wear rates for plastics... 

One of the major advantages of the worm gear is low wear, which is due mostly to a full-fluid lubricant film. In addition, friction can be further reduced using metals having low coefficients of friction. For example, the wheel is typically made of bronze and the worm of highly finished hardened steel. 

Fretting at very low temperatures (4K) has been investigated. The situation appears to be similar to that in high vacuum. An oxide film does not grow at this temperature and so coefficients of friction are high due to adhesion but little wear occurs . 

---