Cobalt complexes carbon disulfide

The (cobalt carbonyl)-(carbon disulfide) complexes prepared in this laboratory by KLUMPP and coworkers (5, 6) belong apparently to a different class of sulfur-containing cobalt carbonyl derivatives. 

When the Claus reaction is carried out in aqueous solution, the chemistry is complex and involves polythionic acid intermediates (105,211). A modification of the Claus process (by Shell) uses hydrogen or a mixture of hydrogen and carbon monoxide to reduce sulfur dioxide, carbonyl sulfide, carbon disulfide, and sulfur mixtures that occur in Claus process off-gases to hydrogen sulfide over a cobalt molybdate catalyst at ca 300°C (230). 

The formation of complexes of l,2,3,4-thiatriazole-5-thiol has been well described in CHEC-II(1996) 1,2,3,4-thiatriazole-5-thiol can form complexes with various metals such as palladium, nickel, platinum, cobalt, zinc, etc. <1996CHEC-II(4)691>. These complexes can be prepared either by cycloaddition reactions of carbon disulfide with metal complexes of azide anion (Equation 20) or directly from the sodium salt of l,2,3,4-thiatriazole-5-thiol with metal salts. For instance, the palladium-thiatriazole complex 179 can be obtained as shown in Equation (20) or it may be formed from palladium(ll) nitrate, triphenylphosphine, and sodium thiatriazolate-5-thiolate. It should be noted that complexes of azide ion react with carbon disulfide much faster than sodium azide itself. 

Table 6 Structures Cobalt-Carbon Disulfide Complexes ...

Protein-Based Adhesives. Protein-based adhesives are normally used as structural adhesives they are all polyamino acids that are derived from blood, fish skin, casein [9000-71-9], soybeans, or animal hides, bones, and connective tissue (collagen). Setting or cross-linking methods typically used are insolubilization by means of hydrated lime and denaturation. Denaturation methods require energy7 which can come from heat, pressure, or radiation, as well as chemical denaturants such as carbon disulfide [75-15-0] or thiourea [62-56-6]. Complexing salts such as those based upon cobalt, copper, or chromium have also been used. Formaldehyde and formaldehyde donors such as hexametliylenetetraamine can be used to form cross-links. Removal of water from a protein will also often denature the material. 

On the other hand, the well-known 5-methylheptatrienyl-butadiene-cobalt(I) complex [Co( /, 7 -CH3C7Hio)( 7 -C4H6)] has been proved recently to be a very highly active catalyst for the formation of syndiotactic 1,2-polybutadiene [51]. The activity increases strongly with the acceptor properties of the solvent in the order heptane < toluene < dichloromethane < carbon disulfide, and can be extremely enhanced by the addition of alumoxane. 

Cobalt(—I) complexes arsenic ligands, 769 bipyridyl, 691 cyanides, 646 phenanthroline, 691 phosphines bidentate, 728 monodentate, 718 multidentate, 738 tridentate, 738 phosphinites, 747 phosphites, 747 phosphonites, 747 terpyridyl, 691 Cobalt(O) Complexes arsenic ligands, 769 bipyridyl, 691 carbon disulfide, 646 cyanides, 646 phenanthroline, 691 phosphines, 718 bidentate, 728 multidentate, 738 tridentate, 738... 

Liganded cobalt complexes react with carbon disulfide by addition across one of the C=S bonds to give relatively stable complexes 10. The same complex reacts with carbonyl sulfide to give a liganded carbonyl complex 11 andMesPS. In the reaction of carbon sulfose-lenide at -20 °C the adduct 12 as well as the thiocarbonyl complex 13 are formed, indicating that carbon sulfoselenide can be used for the synthesis of thiocarbonyl compounds. 

It is not clear when dithiocarbamates were first prepared, but certainly they have been known for at least 150 years, since as early as 1850 Debus reported the synthesis of dithiocarbamic acids (1). The first synthesis of a transition metal dithiocarbamate complex is also unclear, however, in a seminal paper in 1907, Delepine (2) reported on the synthesis of a range of aliphatic dithiocarbamates and also the salts of di-iTo-butyldithiocarbamate with transition metals including chromium, molybdenum, iron, manganese, cobalt, nickel, copper, zinc, platinum, cadmium, mercury, silver, and gold. He also noted that while dithiocarbamate salts of the alkali and alkali earth elements were water soluble, those of the transition metals and also the p-block metals and lanthanides were precipitated from water, to give salts soluble in ether and chloroform, and even in some cases, in benzene and carbon disulfide. 

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