Coatings continued tests

TABLE 10.7 Specific Test Methods for Coatings Continued)... 

Using a suitable thermal stabilizer package, the PP coating can withstand a continuous operating temperature up to 120°C. In order to predict the lifetime of the thermal stabilized coating, accelerated tests are performed at 150°C in an oven v th forced air and the Arrhenius theoretical equation is used ... 

When copper under nickel coatings are tested, the first endpoint (a copper spot) gives the thickness of nickel, after which the test is continued to the endpoint for copi>er as described previously. 

Unlike coatings made from thermoplastic powders which require only a visual inspection to see whether the coating is satisfactory, thermosetting powder coatings require additional examination to determine whether the coating has achieved its full physical properties. Simple mechanical tests may be used, as is the practice with conventional paint finishes, but, particularly for epoxy powder coatings, it is normal to use chemical resistance as a criterion for suitability. A common method is to swab the coating continuously for 30 seconds with a cotton wool pad soaked in methyl isobutyl ketone. Any deterioration of... 

The war itself also drove the development of improved and miniaturised electronic components for creating oscillators and amplifiers and, ultimately, semiconductors, which made practical the electronic systems needed in portable eddy current test instruments. The refinement of those systems continues to the present day and advances continue to be triggered by performance improvements of components and systems. In the same way that today s pocket calculator outperforms the large, hot room full of intercormected thermionic valves that I first saw in the 50 s, so it is with eddy current instrumentation. Today s handheld eddy current inspection instrument is a powerful tool which has the capability needed in a crack detector, corrosion detector, metal sorter, conductivity meter, coating thickness meter and so on. 

Eor steel and other ferromagnetic materials, property deterrnination is more difficult. Other tests are made to measure the continuity of protective metallic coatings. Residual stresses induced in welded stmctures and in components in service owing to chemical attack may contribute to early failure. 

Table 4-15 lists base materials Elliott has tested. This list, which is continually being expanded, includes low alloy steels, high alloy iron base, nickel base, cobalt base materials, and odiers. Table 4-16 shows some of the coatings Elliott has tested. The list indicates die supplier, coating designation, and major components of the coating composition. 

Even small traces of certain corrosion stimulants, notably soluble chlorides and sulphates, can maintain a continuing corrosion process under a paint film because the salts accelerate the initial dissolution of ferrous iron (and other metal ions) but are not immobilised in the hydrated oxide corrosion products. Filiform corrosion is the most spectacular example of this phenomenon, but progressive spread, preceded by blistering, is also observed from scratches or other breaks in a coating, for example during salt spray tests. 

The most widely used accelerated tests are based on salt spray, and are covered by several Government Specifications. BS 1391 1952 (recently withdrawn) gives details of a hand-atomiser salt-spray test which employs synthetic sea-water and also of a sulphur-dioxide corrosion test. A continuous salt-spray test is described in ASTM B 117-61 and BS AU 148 Part 2(1969). Phosphate coatings are occasionally tested by continuous salt spray without a sealing oil film and are expected to withstand one or two hours spray without showing signs of rust the value of such a test in cases where sealing is normally undertaken is extremely doubtful. 

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