Clay reinforcement morphology

Kaneko, M. L. Q. A. Romero, R. B. Do Carmo Goncalves, M., High Molar Mass Silicone Rubber Reinforced with Montmorillonite Clay Masterbatches Morphology and Mechanical Properties. Eur. Polym. J. 2010, 46, 881-890. 

Volume 1 of this book is comprised of 25 chapters, and discusses the different types of natural rubber based blends and IPNs. The first seven chapters discuss the general aspects of natural rubber blends like their miscibility, manufacturing methods, production and morphology development. The next ten chapters describe exclusively the properties of natural rubber blends with different polymers like thermoplastic, acrylic plastic, block or graft copolymers, etc. Chapter 18 deals entirely with clay reinforcement in natural rubber blends. Chapters 19 to 23 explain the major techniques used for characterizing various natural rubber based blends. The final two chapters give a brief explanation of life cycle analysis and the application of natural rubber based blends and IPNs. 

Schematic illustration of clay and CNTs morphology in chitosan nanocomposites is shown in Figure 4.8. In the composites based on chitosan/CNTs containing 0.4 wt % CNTs, nanotubes can be well dispersed in chitosan, but no filler network could be formed due to its low concentration (Figure 4.8a). In the composites based on chitosan/clay containing 3 wt % clay, formation of 2D clay platelets network is possible (Figure 4.8b). In chitosan/clay-CNTs ternary nanocomposites, ID CNTs are confined in 2D clay platelets network, which results in a much jammed and conjugated 3D clay-CNTs network (Figure 4.8c). The interactions and networks in the system can be divided into (1) clay-clay network, (2) clay-CNTs network, (3) CNTs-polymer-clay bridging, (4) polymer-polymer network. The formation of different networks and interactions could be the main reason for the observed synergistic reinforcement of CNT and clay...

The extent of exfoliation and dispersion of the clay platelets in a nanocomposite where the polymer matrix is reinforced by highly anisotropic dispersed silicate plateletes [19] are affected critically by the kinetic barriers in these systems. In this example, kinetic barriers often have the detrimental effect of not allowing the most favorable morphology to be attained. 

S-H. Wu, F-Y. Wang, C-C.M. Ma, W-C. Chang, C-T. Kuo, H-C. Kuan, and W-J. Chen, Mechanical, thermal and morphological properties of glass fiber and carbon fiber reinforced polyamide-6 and polyamide-6/clay nanocomposites, Mater. Lett., 49, 327-333 (2001). 

The reinforcement of polypropylene and other thermoplastics with inorganic particles such as talc and glass is a common method of material property enhancement. Polymer clay nanocomposites extend this strategy to the nanoscale. The anisometric shape and approximately 1 nm width of the clay platelets dramatically increase the amount of interfacial contact between the clay and the polymer matrix. Thus the clay surface can mediate changes in matrix polymer conformation, crystal structure, and crystal morphology through interfacial mechanisms that are absent in classical polymer composite materials. For these reasons, it is believed that nanocomposite materials with the clay platelets dispersed as isolated, exfoliated platelets are optimal for end-use properties. 

Crosslinked NR nanocomposites were prepared with montmorillonite. Morphology was characterized using transmission electron microscopy (TEM), wide-angle X-ray scattering (WAXS), and dynamic mechanical analysis (DMA). X-ray scattering patterns revealed clay intercalation and TEM showed dispersion with partial delamination. The loss modulus peak broadened with clay content, while Tg remain constant. Montmorillonite reinforced the rubber. The DMA exhibited non-linear behaviour typified as a Payne effect (see Section 20.11) that increased with clay content and was more pronounced for this type of nanocomposite. Viscoelastic behaviour was observed under large strains via recovery and stress relaxation. ... 

A number of reviews have been studied on the potential of natural fibers such as sisal, kenaf, hemp, flax, bamboo, and jute for the preparation of thermoplastic composites. In this work, however sisal fiber (SF) has been used as reinforcement due to easily availability and comparatively low cost. The xmtreated and treated SF-reinforced RPP composites have been prepared and investigated their thermal, mechanical, morphological, weathering and impact properties. An improved mechanical, thermal, and morphological property has been observed for chemical treated SF as well as clay loaded RPP. The analysis revealed that SF-reinforced RPP composites with enhanced properties can be successfully achieved which warrants to replace the synthetic fillers-based conventional thermoplastic composites. These SF-based RPP composites can be the material of choice in the field of aeronautic, automobiles, civil engineering, etc., due to its low cost, low density, non-toxicity, recyclability, acceptable strength, high specific properties, and minimum waste disposal problems. 

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