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2- Chloroethyl Chloromethyl Ether

Table 39. 2-Chloroethoxycyclopropanes from (2-Chloroethyl) Chloromethyl Ether, Lithium 2,2,6,6-Tet-ramethylpiperidide and Alkenes... Table 39. 2-Chloroethoxycyclopropanes from (2-Chloroethyl) Chloromethyl Ether, Lithium 2,2,6,6-Tet-ramethylpiperidide and Alkenes...
Cyclopropane derivatives have been prepared using alkenes, cm-dihalides, and copper. This is a convenient and useful procedure, e.g. cis-cyclo-octene was converted into bicyclo[6,l,0]nonane (77%) and into a mixture of endo- and cxo-9-methoxy-carbonylbicyclo[6,l,0]nonanes (71 % exo. endo = 1.3 1) using di-iodomethane and methyl dibromoacetate, respectively. An improved procedure for the conversion of alkenes into cyclopropanols uses lithium 2,2,6,6-tetramethylpiperidide and 2-chloroethyl chloromethyl ether, e.g. cycloheptene was converted into the 2-chloro-ethyl ether of bicyclo[5,l,0]octan-8-ol (62% exo.endo = 1.8 1). ... [Pg.223]

Related Reagents. Benzyl Chloromethyl Sulfide r-Butyl Chloromethyl Ether 2-Chloroethyl Chloromethyl Ether Chloromethyl Methyl Ether Chloromethyl Methyl Sulfide (p-Methoxy-benzyloxy)methyl Chloride 2-Methoxyethoxymethyl Chloride 2-(Trimethylsilyl)ethoxymethyl Chloride. [Pg.51]

Cydopropanols. This new carbenoid reaction has been extended to a synthesis of cyclopropanols by use of /S-chloroethyl chloromethyl ether as the carbenoid precursor. The final step involves cleavage of a /S-chloroethyl ether with n-butyllithium, a reaction first used by Schollkopf. ... [Pg.111]

Chlorobenzene Producers Association (CPA), 270 p-Chlorobenzotrichloride, 39 Chlorobenzotrifluorides, 39 Chlorobromomethane, 39 Chlorodifluorobromomethane, 39 Chlorodifluoroethane, 39 Chlorodifluoromethane, 39 Chlorodiphenyl, 39 Chloroethanol, 39 2-Chloroethyl vinyl ether, 39 Chlorofluorocarbons, 39 Chloroform, 40 Chloromethyl anilines, 40 Chloromethyl ether, 40 Chloromethyl methyl ether, 40 2-(4-Chloro-2-methylphenoxy) propionic acid, 40 Chloromethyl phenyl isocyanate, 40... [Pg.327]

Bis(2-diisopropylaminoethyl) Disulfide Bis(2-diisopropylaminoethyl) Sulfide Bis(2-fluoroethyl) 2-Chloroethylamine Bis(2-fluoroethyl)methylamine Bis(2-hydroxyethyl) Sulfide Bis(2-hydroxyethyl) Thioether Bis(2-hydroxyethyl)amine Bis(2-hydroxyethyl)methylamine Bis(2-propenyl) Sulfide Bis(bromomethyl) Ether Bis(chloromethyl) Ether Bis(cyclohexyl)carbodiimide Bis(ethenyl)sulfone Bis(trichloromethyl) Carbonate Bis(/3-bromoethyl) Sulfide Bis(/3-chloroethyl)ethylamine Bis(/3-Chloroethyl)methylamine Bis(/3-chloroethylthio)ethane Bis(/3-mercaptoethyl) Sulfide... [Pg.635]

Chloroethyl benzoate, 30,11 a-Chloroethyl ethyl ether, 36, 60 Chlorohydroquinone, 35, 27 -Chloromandelic acid, 35,14 Chloromethylation, 30, 68 2-Chloro-2-methylcyclohexanone, 37, 8... [Pg.46]

Widespread chlorine-containing polymers would include, 1) stable molding material for practical use such as polyvinyl chloride (PVC), polyvinylidene chloride and poly(epichlorohydrin)(PECH) and, 2) reactive polymers capable to introduce additional functional groups via their active chlorines such as chloromethyl polystyrene, poly (3-chloroethyl vinyl-ether) and poly (vinyl chloroacetate). While the latter, especially the chloromethyl polystyrene, has been widely used recently for the synthesis of variety of functional polymers, we should like to talk in this article about the chemical modification of the former, mainly of PVC and PECH, which was developed in our laboratory. [Pg.41]

Beryllium and certain beryllium compounds A,A- w-(2-Chloroethyl)-2-naphthylamine (chlornaphazine) Bis(chloromethyl) ether and chloromethyl methyl ether 1,4-Butanediol dimethylsulfonate (Myleran )... [Pg.234]

Diffiuex investigated a synthesis of cyclic poly(vinyl ether) using cationic polymerization [26,28]. The reaction process is depicted in Fig. 9. They studied on the living cationic polymerization of 2-chloroethyl vinyl ether (CEVE) initiated with the HI adduct of 4-(vinylbenzyloxy)butyl vinyl ether prepared by reacting chloromethyl styrene with sodium salt of 4-hydroxy-butyl vinyl ether in THF at 80 °C. By the cationic polymerization of CEVE, o /o-hetcrofunclional linear polymer precursor of cyclic poly(CEVE) was produced. The MWDs of the polymers were unimodal and very narrow (< 1.2),... [Pg.132]

N,N-Bisbromomagnesiumaniline, 33 Bischler-Napieralski reaction, 394 Bis(2-chloroethyl)ether, 142 Bischloromethylation, 84 Bis(chloromethyl) ether, 83 Bis-(1,5-cyclooctadiene)nickel(0), 33-35 Bis(dibutylacetoxytin)oxide, 393,394... [Pg.317]

Beryllium and beryllium compounds Bis(2-chloroethyl) sulfide Bis(chloromethyl) ether... [Pg.2573]

Bis(2-chloroisopropyl)ether exhibited moderately toxic and carcinogenic actions in test animals. The acute inhalation toxicity of this compound is considerably lower than those of bis(chloromethyl)ether and bis (chloroethyl)ether. Exposure to its vapors can cause irritation of the eyes and upper respiratory tract. Inhalation of 700 ppm of this compound in air for 5 hours proved fatal to rats. [Pg.431]

N,N-Bis(2-chloroethyl)-2-naphthylamine (Chlomapazine) Bischloroethyl nitrosourea (BCNU) (Carmustine) Bis(chloromethyl)ether... [Pg.231]

See other pages where 2- Chloroethyl Chloromethyl Ether is mentioned: [Pg.159]    [Pg.159]    [Pg.222]    [Pg.421]    [Pg.421]    [Pg.26]    [Pg.88]    [Pg.97]    [Pg.59]    [Pg.169]    [Pg.49]    [Pg.222]    [Pg.2417]    [Pg.425]    [Pg.52]    [Pg.108]    [Pg.147]    [Pg.2192]   
See also in sourсe #XX -- [ Pg.14 , Pg.51 , Pg.98 , Pg.266 , Pg.431 ]



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2-Chloroethyl ether

Chloromethyl

Chloromethyl ether

Chloromethylated

Chloromethylation

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