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Benzyl Chloromethyl Sulfide

Formaldehyde dibenzyl dithioacetal, m.p. 55° (from 2-propanol), is formed analogously in 90% yield (4.8 g) from benzyl chloromethyl sulfide (3.5 g) and a-toluenethiol (3 g). [Pg.642]

Related Reagents. Benzyl Chloromethyl Sulfide r-Butyl Chloromethyl Ether 2-Chloroethyl Chloromethyl Ether Chloromethyl Methyl Ether Chloromethyl Methyl Sulfide (p-Methoxy-benzyloxy)methyl Chloride 2-Methoxyethoxymethyl Chloride 2-(Trimethylsilyl)ethoxymethyl Chloride. [Pg.51]

Formaldehyde benzyl ethyl dithioacetal Chloromethyl ethyl sulfide (11 g) and a-toluene-thiol (12.4 g) react very vigorously, with evolution of hydrogen chloride, and control by cooling is necessary. After being kept overnight, the mixture is fractionated in a vacuum, affording the dithioacetal, b.p. 165°/19 mm, in 60% yield. [Pg.642]


See other pages where Benzyl Chloromethyl Sulfide is mentioned: [Pg.59]    [Pg.135]    [Pg.116]    [Pg.1897]    [Pg.61]   
See also in sourсe #XX -- [ Pg.51 , Pg.98 , Pg.266 ]




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