Chicken aroma

The symmetrical compounds (17, R = R = R ) are formed from an aldehyde and ammonium sulfide (2,29,35) or hydrogen sulfide and ammonia (33), Thialdine (17, R - R - R = Me) is an important aroma compound found in the volatiles of beef broth (48), pressure-cooked meat (49), and fried chicken (50), It is also obtained from acetaldehyde (2,29,37) or from B-mercaptoacetaldehyde and ammonium sulfide (37), In our experiments, it was synthesized as a white powder from a reaction of acetaldehyde with ammonium sulfide in 60% yield. 

In addition to the straight-chain saturated aldehydes, a number of branched-chain and unsaturated aliphatic aldehydes are important as fragrance and flavoring materials. The double unsaturated 2-trviolet leaf aldehyde (the dominant component of cucumber aroma), is one of the most potent fragrance and flavoring substances it is, therefore, only used in very small amounts. 2-frfatty odor character is indispensible in chicken meat flavor compositions. 

Pyridine has been isolated in the volatile components from cooked beef ( sukiyaki ) in Japan (Shibamoto etal., 1981), fried chicken in the United States (Tang et al., 1983), fried bacon (Ho et al., 1983), Beaufort cheese (Dumont Adda, 1978), black tea aroma (Vitzthum et al., 1975) and coffee aroma (Aeschbacher et al., 1989). 

It appears, then, that there is a general, meaty aroma, common to cooked beef, pork, and lamb (and probably poultry), attributable to the pyrolysis of the mixture of low molecular weight nitrogenous and carbonyl compounds extracted from the lean meat by cold water. But the aromas of roast beef, roast pork, roast lamb, and roast chicken are unmistakably different. The chemical composition of the muscular fat deposits of these animals differ appreciably, and it is to these lipid components that we must look to account for the specific flavor differences. Heating the carefully separated fat alone does not give a meaty aroma at all, much less an animal-specific one. It is the subsequent reactions of pyrolysis products of nonlipid components that give the characteristic aromas and flavors of roasted meats (20). 

Lipid decomposition volatiles. Reactions of sugar and amino acids give rise to odor profiles that are, at best, common to all cooked or roasted meats. The water soluble materials extracted from chicken, pork, or beef give reasonably similar meat flavor. To develop a species specific aroma one needs to study the lipid fraction and the volatiles produced from those lipids. The work of Hornstein and Crowe (10) reported that the free fatty acids and carbonyls generated by heating will establish the specific species flavor profiles. 

An integrated GC/IR/MS instrument is a powerful tool for rapid identification of thermally generated aroma compounds. Fourier transform infrared spectroscopy (GC/IR) provides a complementary technique to mass spectrometry (MS) for the characterization of volatile flavor components in complex mixtures. Recent improvements in GC/IR instruments have made it possible to construct an integrated GC/IR/HS system in which the sensitivity of the two spectroscopic detectors is roughly equal. The combined system offers direct correlation of IR and MS chromatograms, functional group analysis, substantial time savings, and the potential for an expert systems approach to identification of flavor components. Performance of the technique is illustrated with applications to the analysis of volatile flavor components in charbroiled chicken. 

The flavor industry has introduced, over the years, methods of developing meat flavors by processing appropriate precursors under carefully controlled reaction conditions. As a result, meat flavors having a remarkably genuine meat character in the beef, chicken and pork tonalities are available for the food industry. It has repeatedly been stated that the Maillard reaction is particularly important for the formation of meat flavors. However, of the 600 volatile compounds isolated from natural beef aroma, only 12% of them find their origin in sugar/amino acid interactions and of these 70% are pyrazine derivatives. 

These carbonyl compounds are potent aroma chemicals which not only contribute to cooked meat flavor, but also are involved in the formation of other strongly odorous compounds. An example of this was given by Pippen and Mecchi [14] who observed that when hydrogen sulfide is passed through molten chicken fat, a chicken meat-like aroma is formed. 

The basic fraction of the volatiles identified in the fried pork bundle contained 16 alkylpryazines. Among them, methylpyrazine (nutty, roasted), 2,5-dimethylpyrazine (grilled chicken, roasted peanut), 2,6-dimethylpyrazine (ether-like), 2,3,5-trimethylpyrazine (nutty, roasted) and 2-ethyl-6-methylpyrazine (grassy) were predominant. The combination of these alkylpyrazines may cause the characteristic cooked meat aroma of Chinese fried pork bundle. Quantitative analyses showed that alkylpyrazine formed during the final frying stages, as shown in Table II. 

R. Kerscher W. Grosch, Comparison of the Aromas of Cooked Beef, Pork, and Chicken. In Frontiers of Flavour Science, The Proceedings of the 9th Weurman Flavour Research Symposium, Freising, Germany, 22-25 June 1999 P. Schieberle,... 

Isobutyl-3,5-diisopropylpyridine was identified in fried chicken and has a roasted cocoa-like aroma (21). Figure 3 shows the mechanism for the formation of this compound as proposed by Shu et... 

Chang et al. (42). They Isolated and identified 2,4,5-triinethyl-3-oxazoline in boiled beef. This compound was described as having a "characteristic boiled beef aroma". Mussinan et al. (35) identified oxazolines and no oxazoles in their beef system. Peterson et al. (43) reported on the volatiles of canned beef stew. Both 2,4,5-trimethyloxazole and 2,4,5-trimethyl-3-oxazoline were present. The relative concentration of 2,4,5-trimethyloxazole was medium while for 2,4,5-trlmethyl-3-oxazoline was extra high. Lee et al. (44) identified 2-methyl-3-oxazoline, 2,4-dimethyl-3-oxazoline and 2,4,5-trimethyl-3-oxazoline in the volatiles of roasted peanuts. The latter two 3-oxazollnes were also identified in the volatiles of fried chicken (19). 

In our opinion, the predominant contribution to flavor seems to come from sulfurous and carbonyl-containing volatiles. While many of the sulfur-containing volatiles are known to have meaty aromas, volatile carbonyl compounds generally are formed by lipid autoxidation/degradation and do not possess meaty flavor notes. However, it has been indicated that the carbonyl compounds are responsible for the "chickeny" aroma of cooked chicken (17). Thus, lipid autoxldatlon appears to yield the character impact compounds for chicken (18). 

The Top Notes are compositions of natural or synthetic flavouring ingredients to impart a very specific desired aroma profile spicy, peppery, rosemary, lime, buttery, roasted garlic notes for a clear variation. Or specific fatty notes like 2,4-decadienal, 2-nonenal to adjust the chicken flavour to a more natural impression. Top notes are very flexible in production and can be adjusted to customer needs. 

Kerscher, R., Grosch, W. (2000) Comparison of the aromas of cooked beef, pork and chicken. In Schieberle, P., Engel, K.-H. (eds.) Frontiers of Flavor Sicence. Deutsche Forschungsanstalt flir Lebensmittelchemie, Garching, pp. 17-20... 

That many chemical substances are not soluble in sc carbon dioxide permits selective extraction.100 It is often used with foods, for which it eliminates the possibility of leaving toxic residues of solvents such as methylene chloride. It also avoids the hydrolysis that might occur when esters (for flavors or fragrances) are recovered by steam distillation. It has been used to extract the flavor from hops, the caffeine from coffee, fat and cholesterol from foods,101 pecan oil,102 lavender oil (for which hydrolysis of linalyl acetate could occur in steam distillation), 103 ginseng (from which it does not extract pesticide residues),104 ginger,105 microalgae,106 cooked chicken,107 ethanol from cider,108 and many others. One method used with aromas and con-... 

Ingredients and heating condition are important factors influencing the flavor of moist pet foods. The main ingredient affecting the flavor of moist pet foods is fat, because crude fat acts as an oil-soluble flavor carrier. Bacon and chicken fats, for example, have strong aroma characteristics and tastes (Hanna, 1976). The fat flavor is influenced by relative protein tissues and the nature of the fat itself. A suitable amount of fats in moist pet foods is around 3%-6% of a final product. Excess fats in moist pet foods may lead to a problem of nutrition balance and inversely affect the... 

Occurrence E)-2-A. Cg-C,3 in citrus oils, especially bitter orange, Cg also in guava and ginger aromas, C, in bread, cucumber, carrot (see vegetable flavors) and rice flavor, c,o in coriander oil, butter, chicken and guava aroma, C,2 in coriander oil, peanut and meat flavor. (Z)-4-Heptenal is found, among others, in "butter, seafood and tea flavor, (Z)-3- and (Z)-6-nonenal in cucumber, melon and fish aroma, and (Z)-4-decenal in calamus oil and Citrus junos oil. ... 

The structure of the food matrix is also known to affect the release of volatile compounds having an impact on flavors and aroma. Changes in flavor result from the interactions of lipid-derived carbonyl compounds by aldolization with the amino groups of proteins. Undesirable flavors are produced when beef or chicken are fried in oxidized fats by the interaction of secondary lipid oxidation... 

---