Chemical reaction cracking

Chemical reaction cracking is caused by deleterious chemical reactions. These reactions may be attributed to materials used to make the concrete or materials that come into contact with the concrete after it has hardened (sulfates, de-icing salts, etc.) (ACI2007). 

Concrete may crack with time as a result of slowly developing expansive reactions between aggregates containing active silica and alkalis derived from cement hydration, admixtures or external sources (such as curing water, groundwater, de-icing chemicals and alkaline solutions stored or used in the finished structure) (Brooks and Neville 1992). 

Certain carbonated rocks participate in reactions with alkalis that, in some instances, produce detrimental expansion and cracking. These detrimental alkali-carbonate reactions are usually associated with argillaceous dolomitic limestones that have a very fine-grained structure (ACI 2007). 

Chemical reaction cracking due to alkali-aggregate reaction typically appears after more than 5 years. 

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Procedures, General Design Concept, Choice of Solvent, Selection of Column Diameter, Physical Absorption, Solvent Absorption, Natural Gas Dehydration, Gas Drying, Sulfuric Acid Manufacture, Formaldehyde Absorption, Absorption with Chemical Reaction, Cracked Gas Scrubbing, Amine Systems, Hot Carbonate Systems, Multicomponent Absorption, Reboiled Absorbers, Example Problem, Notation, References... 

Each isomer has its individual set of physical and chemical properties however, these properties are similar (Table 6). The fundamental chemical reactions for pentanes are sulfonation to form sulfonic acids, chlorination to form chlorides, nitration to form nitropentanes, oxidation to form various compounds, and cracking to form free radicals. Many of these reactions are used to produce intermediates for the manufacture of industrial chemicals. Generally the reactivity increases from a primary to a secondary to a tertiary hydrogen (37). Other properties available but not Hsted are given in equations for heat capacity and viscosity (34), and saturated Hquid density (36). 

Dente and Ranzi (in Albright et al., eds.. Pyrolysis Theory and Industrial Practice, Academic Press, 1983, pp. 133-175) Mathematical modehng of hydrocarbon pyrolysis reactions Shah and Sharma (in Carberry and Varma, eds.. Chemical Reaction and Reaction Engineering Handbook, Dekker, 1987, pp. 713-721) Hydroxylamine phosphate manufacture in a slurry reactor Some aspects of a kinetic model of methanol synthesis are described in the first example, which is followed by a second example that describes coping with the multiphcity of reactants and reactions of some petroleum conversion processes. Then two somewhat simph-fied industrial examples are worked out in detail mild thermal cracking and production of styrene. Even these calculations are impractical without a computer. The basic data and mathematics and some of the results are presented. 

All refining operations may be classed as either conversion processes or separation processes. In the former, the feed undergoes a chemical reaction such as cracking, polymerization, or desulfurization. Separation processes take advantage of differences in physical properties to split the feed into two or more different products. Distillation, the most common of all refinery separation processes, uses differences in boiling points to separate hydrocarbon mixtures. 

The nucleus of an atom consists of protons and neutrons that are bound together by a nuclear force. Neutrons and protons are rearranged in a nuclear reaction in a manner somewhat akin to rearrang ing atoms in a chemical reaction. The nuclear reaction liberating energy in a nuclear power plant is called nuclear fission. The word fission is derived from fissure, which means a crack or a separation. A nucleus is separated (fissioned) into two major parts by bombardment with a neutron. 

Certain internal chemical treatments employed also need strict control to avoid risks of adverse chemical reaction and resultant corrosion. In particular, nitrogen-containing chemicals such as hydrazine and amines require effective monitoring to limit the concentration of ammonia release into steam because the presence of ammonia may, under certain conditions, cause stress corrosion cracking of copper and brasses. 

Examples Continuous or batch chemical reactions Catalytic cracking Electrochemistry Examples Paint formulating Powder mixing Diluting with solvent Warehousing... 

More recent tests have shown that much of the cracking takes place in the transfer line in which the regenerated catalyst is conveyed into the reactor in the stream of oil vapour. The chemical reaction involved is very fast, and the performance of the reactor is not sensitive to the hydrodynamic conditions. 

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