Chemical functionalities

Simple functionalities have also been used to perform catalytic transformations. Triazine networks have been used to perform cycloadditions to epoxides either using just the basic triazine units or via the incorporation of pyridines.  

The post-synthetic methodology has also been used to incorporate catalytic centres. The incorporation of chiral l,l -bi-2-naphthols (BINOLs) into CMPs has been used to perform catalytic reactions using the alcohol groups to bind to catalytically active centres such as phosphoric acids for asymmetric transfer hydrogenations or titanium for diethyl-zinc additions. Other metal-containing functionalities have also been incorporated into CMP networks. The coordination of metals to pyridine or phenylpyridine via Sonogashira reactions has also been reported for catal5Aic transformations such as reductive amination or aza-Henry reactions, a-atylations and oxyaminations.  

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In oil bearing formations, the presence of polar chemical functions of asphaltenes probably makes the rock wettable to hydrocarbons and limits their production. It also happens that during production, asphaltenes precipitate, blocking the tubing. The asphaltenes are partly responsible for the high viscosity and specific gravity of heavy crudes, leading to transport problems. 

D substructure search is usually known as pharmacophore searching in QSAR. Generally speaking, there are two major approaches to it topological and chemical function queries. These two techniques are based on a slighfly different philosophy and usually provide different results [31]. 

S Kahn, H Savoj, P Sprague and S Teig 1994, Chemical Function Queries for 3D Database ch. Journal of Chemical Information and Computer Science 34 1297-1308. 

Copolymers can be used to introduce a mixture of chemical functionalities into a polymer. Acidic and basic substituents can be introduced, for example, through comonomers like acrylic acid and vinyl pyridine. The resulting copolymers show interesting amphoteric behavior, reversing their charge in solution with changes of pH. 

The solubHity properties of the PAG itself can play an important role in the overaH resist performance as weU (50). SolubHity differences between the neutral onium salt and the acidic photoproducts can be quite high and wHl affect the resist contrast. In fact onium salts can serve as dissolution inhibitors in novolac polymers, analogous to diazonaphthoquinones, even in the absence of any acid-sensitive chemical function (51). 

Chemically Functional. Refractory coatings are used for corrosion-resistant high temperature service in gas turbine and diesel engines, components such as cmcibles, thermocouple protection tubing, valve parts, etc. 

Treatments with Chemicals or Resins. Resin treatments are divided into topical or chemical modifications of the fiber itself. Most chemical treatments of synthetic fibers are topical because of the inert character of the fiber itself and the general resistance of the fiber to penetration by reagents. By contrast, ceUulosics and wool possess chemical functionality that makes them reactive with reagents containing groups designed for such purchases. Natural fibers also provide a better substrate for nonreactive topical treatments because they permit better penetration of the reagents. 

Infrared Spectroscopy (ir). Infrared curves are used to identify the chemical functionality of waxes. Petroleum waxes with only hydrocarbon functionality show slight differences based on crystallinity, while vegetable and insect waxes contain hydrocarbons, carboxyflc acids, alcohols, and esters. The ir curves are typically used in combination with other analytical methods such as dsc or gc/gpc to characterize waxes. 

In addition to data obtained using the spectral mode of analysis, it is often important to know the location of a particular chemical group or compound on the sample surface. Such information is achieved by static SIMS chemical mapping—a procedure in which a specific chemical functionality on the material is imaged, providing information as to its lateral distribution on the surface. 

Examples of chemical functional groups used in UNIFAC... 

Chemical covalent bonding. The formation of covalent chemical bonds between elements at an interface may be an important factor. Such direct chemical bonding would greatly enhance interfacial adhesion, but specific chemical functional groups are required for the reactions to occur. 

Just like the physical and microchemical methods of detection, the indirect, biological-physiological detection procedures are very selective when apphed to thin-layer chromatography. Here it is not chemical functional groups or particular physical properties that are selectively detected but effects on highly sensitive biodetectors . The following detection techniques have been employed ... 

Characteristics due to chemical functionalities (e.g., carboxyl groups) of sample components that control solubility of the sample in aqueous media, viscosity of carbohydrate/polysaccharide solutions, and stability of obtained solutions. 

Proteins are the indispensable agents of biological function, and amino acids are the building blocks of proteins. The stunning diversity of the thousands of proteins found in nature arises from the intrinsic properties of only 20 commonly occurring amino acids. These features include (1) the capacity to polymerize, (2) novel acid-base properties, (3) varied structure and chemical functionality in the amino acid side chains, and (4) chirality. This chapter describes each of these properties, laying a foundation for discussions of protein structure (Chapters 5 and 6), enzyme function (Chapters 14-16), and many other subjects in later chapters. 

Catalytic processes frequently require more than a single chemical function, and these bifunctional or polyfunctional materials innst be prepared in away to assure effective communication among the various constitnents. For example, naphtha reforming requires both an acidic function for isomerization and alkylation and a hydrogenation function for aromati-zation and saturation. The acidic function is often a promoted porous metal oxide (e.g., alumina) with a noble metal (e.g., platinum) deposited on its surface to provide the hydrogenation sites. To avoid separation problems, it is not unusual to attach homogeneous catalysts and even enzymes to solid surfaces for use in flow reactors. Although this technique works well in some environmental catalytic systems, such attachment sometimes modifies the catalytic specifici-... 

A large part of organic and macromolecular chemistry starts with the chemical functionalization of benzene, and benzene units serve us building blocks for important polymers. Naturally, benzene-based aromatic materials also represent an important subclass of jt-conjugaled architectures. Despite some synthetic difficulties related to the generation of structurally well-defined oligo- and poly(phenyl-... 

Since multiple electrical and optical functionality must be combined in the fabrication of an OLED, many workers have turned to the techniques of molecular self-assembly in order to optimize the microstructure of the materials used. In turn, such approaches necessitate the incorporation of additional chemical functionality into the molecules. For example, the successive dipping of a substrate into solutions of polyanion and polycation leads to the deposition of poly-ionic bilayers [59, 60]. Since the precursor form of PPV is cationic, this is a very appealing way to tailor its properties. Anionic polymers that have been studied include sulfonatcd polystyrene [59] and sulfonatcd polyanilinc 159, 60]. Thermal conversion of the precursor PPV then results in an electroluminescent blended polymer film. 

Experiments on absorption and permeation of flavorants have been carried out in high nitrile barrier containers with a number of organic compounds which represent a variety of chemical functionalities. Table... 

Test Compound (0.1% Concentration) Chemical Functionality Poly- ethylene PVC Lopac... 

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