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Charge adsorption

The FAS SAMs on the magnetic heads lead to a considerable improvement on tribological and corrosion-resistant properties, a high water contact angle, and electron charge adsorption-resistant property of the magnetic head. [Pg.3]

Regarding the charging of a semiconductor film surface in the act of forming a charged adsorption, in this particular case it is just an accompanying effect which does not impose any limits on the whole chemi-sorbtion process. [Pg.208]

The sensor detection of EEPs is methodically more complicated than the detection of atoms and radicals. With atoms and radicals being adsorbed on the surface of semiconductor oxide films, their electrical conductivity varies merely due to the adsorption in the charged form. If the case is that EEPs interact with an oxide surface, at least two mechanisms of sensor electrical conductivity changes can take place. One mechanism is associated with the effects of charged adsorption and the other is connected with the excitation energy transfer to the electron... [Pg.296]

At equilibrium surfactant concentrations of less than 0.0003 M SDS where the hematite surface is still positively charged, adsorption of surfactant follows its normal pattern due to the electrostatic forces which provide the driving force for adsorption. Sufficient effective surface area must be available for this level of SDS adsorption density. As surfactant adsorption... [Pg.302]

Some very important surface properties of solids can be properly characterized only by certain wet chemical techniques, some of which are currently under rapid improvement. Studies of adsorption from solution allow determination of the surface density of adsorbing sites, and the characterization of the surface forces involved (the energy of dispersion forces, the strength of acidic or basic sites and the surface density of coul-ombic charge). Adsorption studies can now be extended with some newer spectroscopic tools (Fourier-transform infra-red spectroscopy, laser Raman spectroscopy, and solid NMR spectroscopy), as well as convenient modern versions of older techniques (Doppler electrophoresis, flow microcalorimetry, and automated ellipsometry). [Pg.69]

Point-o f-zero-charge Adsorption of potential-determining ions, many indirect methods based on a characteristic response to mineral processing operation... [Pg.288]

The currently most relevant separation and purification techniques for processing biomolecules from animal cell cultures are discussed in the sections that follow. They are classified according to the protein characteristic on which the separation is based, such as solubility, molar mass, electrical charge, adsorption properties, and biological affinity for ligands. [Pg.301]

CEC packed unmodified Silica gel Size, charge, adsorption "reverse phase", ion-exchange... [Pg.102]

The characteristic effect of surfactants is their ability to adsorb onto surfaces and to modify the surface properties. Both at gas/liquid and at liquid/liquid interfaces, this leads to a reduction of the surface tension and the interfacial tension, respectively. Generally, nonionic surfactants have a lower surface tension than ionic surfactants for the same alkyl chain length and concentration. The reason for this is the repulsive interaction of ionic surfactants within the charged adsorption layer which leads to a lower surface coverage than for the non-ionic surfactants. In detergent formulations, this repulsive interaction can be reduced by the presence of electrolytes which compress the electrical double layer and therefore increase the adsorption density of the anionic surfactants. Beyond a certain concentration, termed the critical micelle concentration (cmc), the formation of thermodynamically stable micellar aggregates can be observed in the bulk phase. These micelles are thermodynamically stable and in equilibrium with the monomers in the solution. They are characteristic of the ability of surfactants to solubilise hydrophobic substances. [Pg.54]

Polysaccharide type CSPs as well as most synthetic polymeric type CSPs have no ionic interaction sites and thus are primarily operated in the normal-phase mode. Proteins, in contrast, have several (positively and negatively) charged adsorption sites for strong ionic interactions, which have to be balanced by buffered mobile phases. The system must take into account that denaturation of the proteins must not occur, which limits the amounts of organic mridifiers that can be used as part of the aqueous mobile phase. [Pg.360]

Graphitized carbon black (GCB) materials are frequently used for off-line SPE as well. GCB behaves as a nonspecific sorbent, but because positively-charged adsorption sites are present, it also acts as an anion exchanger, which is useful for the enrichment of acidic compounds [75]. Examples involve the enrichment of chlorinated phenoxy acids [42], aryloxyphenoxypropionic herbicides [45], sulfonylurea herbicides [50], and imidazolinone herbicides [65]. [Pg.193]

The most common alloy used for hydrogen storage experiments is AB iron/titanium. This combination has the capacity to hold about 1.95% of its weight in hydrogen. Iron/titanium permits charging (adsorption) and de-charging (desorption) hydrogen at ambient temperatures and relatively low pressures. [Pg.321]

If mass transport occurs by surface diffusion (3b) a solute molecule is adsorbed and transported deeper into the pore system by movement along the pore surface. During the whole transport process, molecules are within the attraction forces of the adsorbent surface. Notably, the attractive forces between the surface and absorbed molecules are so strong (Zhang et al, 2003) that, for many common adsorpt— adsorbent systems encountered in preparative chromatography, surface diffusion is physically implausible (especially in charged adsorpt - charged surface interactions). [Pg.24]

Higa et al. (1998) measured the Donnan potential at a membrane interface. They found that the effective charge density was the same for all ions tested. The potential in the system was determined by the counter-ion with the highest valence. Takagi et al (1996) determined Donnan potential from zeta potential. Donnan potential was vety large compared to zeta potential, due to the low pore volume of RO membranes. The effective charge was due to chloride adsorption, as the CA membrane possessed no fixed charge. Adsorption on the surface and in pores was identical. [Pg.76]

Calvo J.I., Hernandez A., Pradanos P., Tejerina F. (1996), Charge adsorption and zeta potential in cyclopore... [Pg.377]

In addition to iodine speciation, the input concentration and contact time have an effect on iodine sorption and transport behavior. Because the sorption of both I (especially) and IO3 are related to the presence and magnitude of soil components that possess positively charged surfaces, and since positively charged surface sites are fim-ited, the extent of sorption will probably be affected by the input concentration. Positively charged adsorption sites may exist on the edges of 2 1 clays (such as smectite and iUite), on Al- and Fe-oxide surfaces, and on 1 1 clays (such as kaolinite). The number of sorption sites in variable-charge minerals is influenced by ionic strength, solution... [Pg.102]

Adsorption is dne to snrface phenomena that do not necessarily involve electrical charges. Adsorption is limited and reaches a balance. It is proportionally more efficient if there is a low concentration of the snbstance adsorbed in the solution. High adsorption may be observed when only traces of dissolved matter are present. One example of this effect is the use of charcoal to remove discoloration from white wines. [Pg.295]

The main objective of this work was to study and to compare the electric surface properties (electrokinetic potential and charge adsorption of ions T surface con-... [Pg.462]


See other pages where Charge adsorption is mentioned: [Pg.405]    [Pg.75]    [Pg.224]    [Pg.225]    [Pg.125]    [Pg.310]    [Pg.270]    [Pg.321]    [Pg.476]    [Pg.275]    [Pg.644]    [Pg.232]    [Pg.288]    [Pg.295]    [Pg.100]    [Pg.314]    [Pg.405]    [Pg.54]    [Pg.134]    [Pg.238]    [Pg.231]    [Pg.272]    [Pg.336]    [Pg.387]    [Pg.533]    [Pg.248]    [Pg.475]    [Pg.56]    [Pg.127]    [Pg.125]    [Pg.42]    [Pg.285]    [Pg.286]   
See also in sourсe #XX -- [ Pg.11 ]

See also in sourсe #XX -- [ Pg.151 ]




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