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Catalysis olefin

Oxidation Catalysis Olefinic alcohol epoxidation with t-BuOOH VO(OiPr)3... [Pg.22]

Compounds Ni(olefin)2 have significant application in catalysis. Olefin-carbonyl complexes of the type [Ni(CO)j, (olefin) ] are not known. Their existence as unstable intermediate compounds in many reactions results from catalytic properties of tetracarbonylnickel in olefin oligomerization processes, oxo synthesis, olefin isomerization, etc. [Pg.373]

The utility of the Heck reaction in its many forms has been extensively studied for the construction of useful synthons and complex molecules. Advances in C—H functionalization have enabled the synthesis of Heck products directly from unactivated arenes via Pd(II) catalysis. Olefination of electron-rich and -deficient arenes has been reported. Approaches to olefination of arenes have included directed olefination with haloolefins. ... [Pg.65]

Alkylation. Alkylation of the 2-position of quinoline is possible via C-H activation. Using rhodium catalysis, olefins can... [Pg.578]

Addition of HCN to unsaturated compounds is often the easiest and most economical method of making organonitnles. An early synthesis of acrylonitrile involved the addition of HCN to acetylene. The addition of HCN to aldehydes and ketones is readily accompHshed with simple base catalysis, as is the addition of HCN to activated olefins (Michael addition). However, the addition of HCN to unactivated olefins and the regioselective addition to dienes is best accompHshed with a transition-metal catalyst, as illustrated by DuPont s adiponitrile process (6—9). [Pg.217]

The conversion of aromatic monomers relative to C-5—C-6 linear diolefins and olefins in cationic polymerizations may not be proportional to the feedblend composition, resulting in higher resin aromaticity as determined by nmr and ir measurements (43). This can be attributed to the differing reactivity ratios of aromatic and aHphatic monomers under specific Lewis acid catalysis. Intentional blocking of hydrocarbon resins into aromatic and aHphatic regions may be accomplished by sequential cationic polymerization employing multiple reactors and standard polymerization conditions (45). [Pg.354]

Reaction conditions depend on the reactants and usually involve acid or base catalysis. Examples of X include sulfate, acid sulfate, alkane- or arenesulfonate, chloride, bromide, hydroxyl, alkoxide, perchlorate, etc. RX can also be an alkyl orthoformate or alkyl carboxylate. The reaction of cycHc alkylating agents, eg, epoxides and a2iridines, with sodium or potassium salts of alkyl hydroperoxides also promotes formation of dialkyl peroxides (44,66). Olefinic alkylating agents include acycHc and cycHc olefinic hydrocarbons, vinyl and isopropenyl ethers, enamines, A[-vinylamides, vinyl sulfonates, divinyl sulfone, and a, P-unsaturated compounds, eg, methyl acrylate, mesityl oxide, acrylamide, and acrylonitrile (44,66). [Pg.109]

Substituted Phenols. Phenol itself is used in the largest volume, but substituted phenols are used for specialty resins (Table 2). Substituted phenols are typically alkylated phenols made from phenol and a corresponding a-olefin with acid catalysts (13). Acidic catalysis is frequendy in the form of an ion-exchange resin (lER) and the reaction proceeds preferentially in the para position. For example, in the production of /-butylphenol using isobutylene, the product is >95% para-substituted. The incorporation of alkyl phenols into the resin reduces reactivity, hardness, cross-link density, and color formation, but increases solubiHty in nonpolar solvents, dexibiHty, and compatibiHty with natural oils. [Pg.292]

Dicumjlphenol (2,4-DCP) or 2,4-bis(l-methyl-l-phenylethyl)phenol is produced by the alkylation of phenol with a-methylstyrene under acidic catalysis. The cmde alkylation product contains 4-cumylphenol, 2,4-dicumylphenol, and 2,4,6-tricumylphenol along with some olefin oligomers. Pure... [Pg.69]

Organic titanates perform three important functions for a variety of iadustrial appHcations. These are (/) catalysis, especially polyesterification and olefin polymerization (2) polymer cross-linking to enhance performance properties and (J) Surface modification for adhesion, lubricity, or pigment dispersion. [Pg.161]

The Wilkinson hydrogenation cycle shown in Figure 3 (16) was worked out in experiments that included isolation and identification of individual rhodium complexes, measurements of equiUbria of individual steps, deterrnination of rates of individual steps under conditions of stoichiometric reaction with certain reactants missing so that the catalytic cycle could not occur, and deterrnination of rates of the overall catalytic reaction. The cycle demonstrates some generally important points about catalysis the predominant species present in the reacting solution and the only ones that are easily observable by spectroscopic methods, eg, RhCl[P(CgH 2]3> 6 5)312 (olefin), and RhCl2[P(CgH )2]4, are outside the cycle, possibly in virtual equiUbrium with... [Pg.164]

Olefin Hydroformylation (The Oxo Process). One of the most important iadustrial applications of transition-metal complex catalysis is the hydroformylation of olefins (23), ihusttated for propjdene ... [Pg.167]

Polymer-supported catalysts incorporating organometaUic complexes also behave in much the same way as their soluble analogues (28). Extensive research has been done in attempts to develop supported rhodium complex catalysts for olefin hydroformylation and methanol carbonylation, but the effort has not been commercially successful. The difficulty is that the polymer-supported catalysts are not sufftciendy stable the valuable metal is continuously leached into the product stream (28). Consequendy, the soHd catalysts fail to eliminate the problems of corrosion and catalyst recovery and recycle that are characteristic of solution catalysis. [Pg.175]

These siUca-supported catalysts demonstrate the close connections between catalysis in solutions and catalysis on surfaces, but they are not industrial catalysts. However, siUca is used as a support for chromium complexes, formed either from chromocene or chromium salts, that are industrial catalysts for polymerization of a-olefins (64,65). Supported chromium complex catalysts are used on an enormous scale in the manufacture of linear polyethylene in the Unipol and Phillips processes (see Olefin polymers). The exact stmctures of the surface species are still not known, but it is evident that there is a close analogy linking soluble and supported metal complex catalysts for olefin polymerization. [Pg.175]

In dihalocarbene generation by phase-transfer catalysis the following steps seem to be involved (15) formation of CX anions dynamically anchored at the boundary reversible detachment with the help of the catalyst reversible carbene formation [Q+ CX3 ] [Q + X ] + CX2 addition to olefin. [Pg.189]

When heated in the presence of a carboxyHc acid, cinnamyl alcohol is converted to the corresponding ester. Oxidation to cinnamaldehyde is readily accompHshed under Oppenauer conditions with furfural as a hydrogen acceptor in the presence of aluminum isopropoxide (44). Cinnamic acid is produced directly with strong oxidants such as chromic acid and nickel peroxide. The use of t-butyl hydroperoxide with vanadium pentoxide catalysis offers a selective method for epoxidation of the olefinic double bond of cinnamyl alcohol (45). [Pg.175]

Hydrogen cyanide adds to an olefinic double bond most readily when an adjacent activating group is present in the molecule, eg, carbonyl or cyano groups. In these cases, a Michael addition proceeds readily under basic catalysis, as with acrylonitrile (qv) to yield succinonitnle [110-61-2], C4H4N2, iu high yield (13). Formation of acrylonitrile by addition across the acetylenic bond can be accompHshed under catalytic conditions (see Acetylene-DERIVED chemicals). [Pg.376]

Alkyl tertiary alkyl ethers can be prepared by the addition of an alcohol or phenol to a tertiary olefin under acid catalysis (Reycler reaction) sulfuric acid, phosphoric acid, hydrochloric acid, and boron trifluoride have all been used as catalysts ... [Pg.426]

Base catalysis is most effective with alkali metals dispersed on solid supports or, in the homogeneous form, as aldoxides, amides, and so on. Small amounts of promoters form organoalkali comnpounds that really contribute the catalytic power. Basic ion exchange resins also are usebil. Base-catalyzed processes include isomerization and oligomerization of olefins, reactions of olefins with aromatics, and hydrogenation of polynuclear aromatics. [Pg.2094]

To date a number of reactions have been carried out in ionic liquids [for examples, see Dell Anna et al. J Chem Soc, Chem Commun 434 2002 Nara, Harjani and Salunkhe Tetrahedron Lett 43 1127 2002 Semeril et al. J Chem Soc Chem Commun 146 2002 Buijsman, van Vuuren and Sterrenburg Org Lett 3 3785 2007]. These include Diels-Alder reactions, transition-metal mediated catalysis, e.g. Heck and Suzuki coupling reactions, and olefin metathesis reactions. An example of ionic liquid acceleration of reactions carried out on solid phase is given by Revell and Ganesan [Org Lett 4 3071 2002]. [Pg.77]

Metallocene catalysis can also make possible the production of copolymers of propylenes with monomers such as long-chain olefins, cyclic olefins and styrene which is not possible with more conventional Ziegler-Natta catalysts. [Pg.251]


See other pages where Catalysis olefin is mentioned: [Pg.396]    [Pg.396]    [Pg.147]    [Pg.10]    [Pg.396]    [Pg.396]    [Pg.147]    [Pg.10]    [Pg.24]    [Pg.205]    [Pg.295]    [Pg.1083]    [Pg.458]    [Pg.357]    [Pg.416]    [Pg.385]    [Pg.387]    [Pg.449]    [Pg.477]    [Pg.465]    [Pg.506]    [Pg.66]    [Pg.67]    [Pg.82]    [Pg.41]    [Pg.332]    [Pg.70]    [Pg.164]    [Pg.181]    [Pg.171]    [Pg.2092]    [Pg.563]    [Pg.290]   


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Asymmetric catalysis olefin hydrogenation

Catalysis of olefin and diene polymerization

Catalysis of olefin metathesis

Catalysis olefin cracking

Catalysis olefin metathesis

Catalysis olefin oligomerization

Catalysis olefin polymerization

Catalysis/catalysts olefin polymerization

Electron-deficient olefins phase-transfer catalysis

Heterogeneous catalysis olefins

High-Throughput Approaches in Olefin Polymerization Catalysis

Homogeneous catalysis alkene (olefin) and alkyne metathesis

Homogeneous catalysis alkene (olefin) metathesis

Ketones olefination, catalysis

Methanol to olefin catalysis

Olefin block copolymers chain shuttling catalysis

Olefin epoxidation, asymmetric catalysis

Olefin hydrogenation, catalysis

Olefin isomerization, catalysis

Olefin metathesis molybdenum catalysis

Olefin metathesis ruthenium catalysis

Olefin polymerization, catalysis Ziegler-Natta

Olefins Fischer-Tropsch catalysis

Olefins amine catalysis

Olefins asymmetric catalysis

Olefins cyclic, catalysis

Olefins epoxidation catalysis

Olefins homogeneous catalysis

Olefins osmium catalysis

Olefins phase-transfer catalysis

Organolithium Catalysis of Olefin and Diene Polymerization

Palladium catalysis olefination, oxygen oxidant

Palladium catalysis olefinations

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