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Carbonyl Compounds reaction

Tetrazole, l-(p-substituted phenyl)-antimicrobial activity, 5, 835 Tetrazole, 5-thio-rearrangements, 5, 823 Tetrazole, 2-thioacyl-reactions, 5, 109 Tetrazole, 5-(o-tolyl)-tautomerism, 5, 804 Tetrazole, 5-(p-tolyl)-dipole moments, 5, 795 tautomerism, 5, 804 Tetrazole, 5-(trimethylsilylamino)-synthesis, 5, 832 Tefrazolecarbaldehydes reactions, 5, 820 Tetrazole-5-carbaldehydes reactions, 5, 820 Tetrazolecarbonitriles reactions, 5, 820 Tetrazole carbonyl compounds reactions, 5, 820 Tetrazolecarboxylic acid, 5-aryl-acidity, 5, 816... [Pg.854]

The mechanistic pattern established by study of hydration and alcohol addition reactions of ketones and aldehydes is followed in a number of other reactions of carbonyl compounds. Reactions at carbonyl centers usually involve a series of addition and elimination steps proceeding through tetrahedral intermediates. These steps can be either acid-catalyzed or base-catalyzed. The rate and products of the reaction are determined by the reactivity of these tetrahedral intermediates. [Pg.456]

The enantioselective addition of a nucleophile to a carbonyl group is one of the most versatile methods for C C bond formation, and this reaction is discussed in Chapter 2. Trifluoromethylation of aldehyde or achiral ketone via addition of fluorinated reagents is another means of access to fluorinated compounds. Trifluoromethyl trimethylsilane [(CF SiCFs] has been used by Pra-kash et al.87 as an efficient reagent for the trifluoromethylation of carbonyl compounds. Reaction of aldehydes or ketones with trifluoromethyltrime-thylsilane can be facilitated by tetrabutyl ammonium fluoride (TBAF). In 1994, Iseki et al.88 found that chiral quaternary ammonium fluoride 117a or 117b facilitated the above reaction in an asymmetric manner (Scheme 8-42). [Pg.484]

Tertiary amines are oxidized to the corresponding nitrogen oxides. Tosyl hydrazones of ketones and aldehydes and imines are oxidized to the corresponding carbonyl compounds. Reactions have been carried out with small molecules and also with molecules that would not diffuse into the pore structure of the titanium silicates. As in the case of C—C bond cleavage, it is possible that these reactions take place on the outer surface of the catalyst crystals. [Pg.316]

Iodosylbenzene Reactions with Unsaturated Compounds. Reactions with Alcohols and Carbonyl Compounds. Reactions with NitrogenCompounds. Reactions with Sulfur and Other Compounds. [Pg.225]

CARBONYL ADDITIONS, CERIUM(III) CHLORIDE-PROMOTED, 76, 237 Carbonyl compounds, reactions with organolithiums or Grignard reagents, 76, 228 Carboxylic acid amides, 77, 27 Cells, storage of, 76, 80 Centrifugation, 76, 78... [Pg.155]

As discussed in section 4, reaction of the peroxy radicals with N02 gives thermally unstable peroxy nitrates. Reaction with H02 gives hydroperoxides and possibly carbonyl compounds. Reaction with other peroxy radicals (R 02) gives alkoxy radicals, carbonyls, and alcohols. The alkoxy radicals will then either isomerize, react with 02, or decompose (see Sect. 3). Thus, the NO3 radical-initiated atmospheric degradation of alkenes leads to oxiranes (generally in small yield), nitrooxy hydroperoxides, nitrooxy carbonyls, and nitrooxyalcohols. For a detailed listing of products from individual alkenes the reader should consult Calvert et al. [55]. [Pg.140]

The p-hydroxy carbonyl compound formed from the crossed aldol reaction can be reduced with NaBH4, CH3OH (Section 20.4A) to form a 1,3-diol (Reaction [1]) or dehydrated to form an a,p-unsaturated carbonyl compound (Reaction [2]). Reduction of the c(,p-unsaturated carbonyl compound forms an allylic alcohol with NaBHi (Reaction [3]), or a ketone with H2 and Pd-C (Reaction [4]) see Section 20.4C. Reaction of the a,p-unsaturated carbonyl compound with an organometalllc reagent forms two different products depending on the choice of RM (Reaction [5]) see Section 20.15. [Pg.924]

Carbethoxycyclopropyltriphenylphosphonium fluoroborate (475) proves to be an excellent reagent for cycloalkenylation of carbonyl compounds. Reaction of p-kcio esters (as their sodium enolates) smoothly produces cyctopentene diesters (602) (equation 213). The mechanism can be most simply viewed as a nucleophilic attack of the enolate on the cyclopropane ring to produce a stabilized ylide, which rapidly cyclizes to the... [Pg.539]

Hoppe has investigated the regioselectivity of the reaction of oxaallylic anions generated from the N,N-diisopropyl carbamates of a variety of allylic alcohols. With carbonyl compounds reaction was found to take place predominantly at the y-carbon. The directing influence of the carbamoyloxy group was unfortunately diminished in alkylation reactions. [Pg.196]

Reactions of chiral allylic boranes with carbonyl compounds Reactions of chiral allyl boranes with imines Asymmetric Addition of Carbon Nucleophiles to Ketones Addition of alkyl lithiums to ketones Asymmetric epoxidation with chiral sulfur ylids Asymmetric Nucleophilic Attack by Chiral Alcohols Deracemisation of arylpropionic acids Deracemisation of a-halo acids Asymmetric Conjugate Addition of Nitrogen Nucleophiles An asymmetric synthesis of thienamycin Asymmetric Protonation... [Pg.505]

Under Lewis add catalysis, the reaction of allylsilanes takes place easily with a-enones but not with a,P-unsaturated esters [162]. Because disappointing results were obtained in reactions of allylmetals with a,P-unsaturated carbonyl compounds, reactions of allylsilanes with electrophiles bearing chiral auxiliaries have been examined. Schultz and Lee [1435] performed the T1CI4 catalyzed addition of trimethylallylsilane to compound 7.67 at -78°C. After treatment with methylhy-droxylamine in acidic media, the 1,4-adduct 7.80 was obtained with high ee (Figure 7.56). Under similar conditions, N-enoyloxazolidinone 7.68 (R = Ph) or sultam... [Pg.449]

Carbonyl Compound Reaction Partner Solvent./Temp (nC) Products Ratio Yield (%) Ref... [Pg.956]

One of the earliest descriptions of an asymmetric lithiating reagent was reported by Nozaki and co-workers in 1968 (35). (—)-Sparteine was used to coordinate n-butyllithium, and this complex stereoselectively added to several carbonyl compounds (Reaction 32). Moreover, the Skattebol-Moore method (which consists of dehalogenating gem-dihalo-cyclopropanes with an alkyllithium complex) by Nozaki to synthesize allenes gave optically active products when the n-butyllithium/ ( —)-sparteine complex was used (36). [Pg.243]

Ph2MeSBF4 or Ph2MeSC104. These form oxiranes 11 on treatment with carbonyl compounds. Reaction of the oxiranes with LiNEt2 gives quinoxalinyl ketones (12) of the type shown. [Pg.115]

Association between RMgX and Carbonyl Compounds Reactions of Benzophenone(s) with Grignard Reagents... [Pg.216]


See other pages where Carbonyl Compounds reaction is mentioned: [Pg.126]    [Pg.22]    [Pg.133]    [Pg.71]    [Pg.72]    [Pg.25]   


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1,3-Pentadiene reactions with carbonyl compounds

1.3- Butadiene reactions with carbonyl compounds

2-Azapentadienyl anion reaction with carbonyl compounds

Acetylide ions carbonyl compound reactions

Acetylides reactions with carbonyl compounds

Addition reactions to carbonyl compounds

Addition, Condensation and Substitution Reactions of Carbonyl Compounds

Alcohols from Carbonyl Compounds Grignard Reaction

Alcohols from Reaction of Carbonyl Compounds with Grignard Reagents

Alcohols reaction with carbonyl compound

Aldol Reactions of Other Carbonyl Compounds

Alkyl metals, a-selenocarbonyl compound homologation reactions with carbonyl compounds

Alkylation with Carbonyl Compounds The Prins Reaction

Allene, reaction with carbonyl compounds

Allyl acetates reactions with carbonyl compounds

Allyl reaction with carbonyl compounds

Allylation reaction of carbonyl compounds

Allylation reactions with carbonyl compounds

Allylic acetates reactions with carbonyl compounds

Allylsilanes reactions with carbonyl compounds

Allylstannanes reactions with carbonyl compounds

Allylthiol reactions with carbonyl compounds

Aluminum, alkyladdition reactions masked carbonyl compounds

Amination reactions carbonyl compounds

Amines reaction with carbonyl compounds

Amino reaction with carbonyl compound

Arsonium ylides reaction with carbonyl compounds

Benzothiazole, 2-alkylmetallated reactions with carbonyl compounds

Biphilic Reactions with Carbonyl Compounds

Borane, dialkylcrotylisomerization reactions with carbonyl compounds

Boranes reaction with halo carbonyl compounds

Borohydride reaction with carbonyl compounds

Carbanions addition reactions with carbonyl compounds

Carbanions carbonyl compound addition reactions

Carbene complexes carbonyl compound addition reactions

Carbene complexes reactions with carbonyl compounds

Carbene complexes, alkyl pentacarbonylalkylation reaction with carbonyl compounds

Carbonyl complexes, reaction with organomagnesium compound

Carbonyl compound intramolecular reactions

Carbonyl compound, acidity general reactions

Carbonyl compound-nucleophile reaction

Carbonyl compound-nucleophile reaction mechanism

Carbonyl compounds 1,4-addition reactions with

Carbonyl compounds 1,4-addition reactions with cyanohydrin ethers

Carbonyl compounds 1,4-addition reactions with cyanohydrins

Carbonyl compounds Knoevenagel reaction

Carbonyl compounds Mannich reaction

Carbonyl compounds Mukaiyama aldol reaction

Carbonyl compounds Norrish type I reaction

Carbonyl compounds Paterno-Biichi reaction

Carbonyl compounds Sakurai allylation reaction

Carbonyl compounds Shapiro reaction

Carbonyl compounds Simmons-Smith reaction

Carbonyl compounds Wittig reaction

Carbonyl compounds acid derivatives reactions with organometallic reagents

Carbonyl compounds acyclic, diastereoselective reactions

Carbonyl compounds addition reactions

Carbonyl compounds addition reactions with alcohols

Carbonyl compounds addition-elimination reactions

Carbonyl compounds aldol reactions

Carbonyl compounds alkynylation reactions

Carbonyl compounds asymmetric reactions

Carbonyl compounds atom-transfer reaction

Carbonyl compounds catalytic asymmetric reactions

Carbonyl compounds chloroform/base reactions

Carbonyl compounds condensation reactions

Carbonyl compounds cycloaddition reactions

Carbonyl compounds diazoalkane cycloaddition reactions

Carbonyl compounds enantiomers, Michael reaction

Carbonyl compounds haloform reaction

Carbonyl compounds intermolecular pinacol coupling reactions

Carbonyl compounds nucleophilic addition reactions

Carbonyl compounds nucleophilic reactions

Carbonyl compounds oxetane formation (Paterno Biichi reaction)

Carbonyl compounds photochemical reactions

Carbonyl compounds photocycloaddition reactions

Carbonyl compounds photocycloaddition reactions with alkenes

Carbonyl compounds pinacol coupling reactions

Carbonyl compounds reaction with alanines

Carbonyl compounds reaction with alcohols to form hemiacetal

Carbonyl compounds reaction with benzylic

Carbonyl compounds reaction with bisulfite

Carbonyl compounds reaction with boron reagents

Carbonyl compounds reaction with cyanide

Carbonyl compounds reaction with diazoalkanes

Carbonyl compounds reaction with enol silanes

Carbonyl compounds reaction with nitriles

Carbonyl compounds reaction with organocuprates

Carbonyl compounds reaction with sodium borohydrid

Carbonyl compounds reaction with sodium borohydride

Carbonyl compounds reaction with trialkylboranes

Carbonyl compounds reaction with water

Carbonyl compounds reactions between

Carbonyl compounds reactions under acid catalysis

Carbonyl compounds reactions under base catalysis

Carbonyl compounds reactions with a-selenoalkylmetals

Carbonyl compounds reactions with allenylsilanes

Carbonyl compounds reactions with allylic sulfinyl carbanions

Carbonyl compounds reactions with crotyl organometallics

Carbonyl compounds reactions with nucleophile

Carbonyl compounds reactions with nucleophiles

Carbonyl compounds reactions with organometallic reagents

Carbonyl compounds reactions with organometallics

Carbonyl compounds reactions with organosamarium ‘ate’ complexes

Carbonyl compounds reactions with selenium-stabilized carbanions

Carbonyl compounds reactions with sulfonimidoyl carbanions

Carbonyl compounds reactions with sulfonyl-stabilized carbanions

Carbonyl compounds rearrangement reactions

Carbonyl compounds redox reactions

Carbonyl compounds reductive coupling reactions

Carbonyl compounds substitution reactions

Carbonyl compounds synthesis, Knoevenagel reaction

Carbonyl compounds three-component reactions

Carbonyl compounds, Diels-Alder reaction

Carbonyl compounds, Diels-Alder reaction NMR spectra

Carbonyl compounds, Diels-Alder reaction mass spectra

Carbonyl compounds, Passerini reaction

Carbonyl compounds, a-benzyloxy nucleophilic addition reactions

Carbonyl compounds, a-oxygenated Wittig reaction

Carbonyl compounds, a-seleno reactions with enals

Carbonyl compounds, addition reactions Wittig reaction

Carbonyl compounds, addition reactions acetal formation

Carbonyl compounds, addition reactions alcohols

Carbonyl compounds, addition reactions cyanohydrin formation

Carbonyl compounds, addition reactions enamine formation

Carbonyl compounds, addition reactions hydration

Carbonyl compounds, addition reactions imine formation

Carbonyl compounds, addition reactions overview

Carbonyl compounds, addition reactions simple reversible additions

Carbonyl compounds, addition reactions substituted imine formation

Carbonyl compounds, condensation reactions Cannizzaro reaction

Carbonyl compounds, condensation reactions Horner-Emmons reaction

Carbonyl compounds, condensation reactions Mannich reaction

Carbonyl compounds, condensation reactions Michael reaction

Carbonyl compounds, condensation reactions aldol dehydration

Carbonyl compounds, condensation reactions amines

Carbonyl compounds, condensation reactions crossed aldol dehydration

Carbonyl compounds, reaction with ammonia

Carbonyl compounds, reaction with hydrazine

Carbonyl compounds, reaction with methylene equivalents

Carbonyl compounds, reaction with phosphines

Carbonyl compounds, reactions at a position

Carbonyl compounds, reactions with organolithiums or Grignard reagents

Carbonyl compounds, reactions with silenes

Carbonyl compounds, simple, enolisation and related reactions

Cobalt, octacarbonylbiscatalyst silane reaction with carbonyl compounds

Condensation of Phosphonium Ylides with Carbonyl Compounds Wittig Reaction

Condensation reactions, carbonyl compounds Michael condensations, acid derivatives

Condensation reactions, carbonyl compounds alkylation, enolate ions

Condensation reactions, carbonyl compounds conjugate addition

Condensation reactions, carbonyl compounds enolization

Cumulative Subject reaction with carbonyl compounds

Cyanohydrin esters reactions with carbonyl compounds

Cyanohydrin ethers reactions with carbonyl compounds

Cycloaddition Reactions of Carbonyl Compounds with Alkenes

Cycloaddition and Rearrangement Reactions of Unsaturated Carbonyl Compounds

Cycloaddition reactions, alkenes carbonyl compounds

Cyclopropanecarboxylic acid, 2-siloxymethyl ester cycloaddition reactions carbonyl compounds, metal catalyzed

Cyclopropanecarboxylic acid, 2-silyloxyhomoenolate equivalents reactions with carbonyl compounds

Diazo compounds, reactions with metal carbonyls

Diazo reaction with carbonyl compounds

Diels-Alder reactions of carbonyl compounds

Diols reaction with carbonyl compounds

Electron-transfer Reactions of Carbonyl Compounds

Elimination reactions 0-unsaturated carbonyl compounds

Enol esters reaction with carbonyl compounds

Enol ethers reaction with carbonyl compounds

Enol sulfonates reaction with carbonyl compounds

Enolates reaction with carbonyl compounds

Enolisation of simple carbonyl compounds and related reactions

Enolizable Carbonyl Compounds the Haloform Reaction

Ether, benzyl chloromethyl reaction with carbonyl compounds

Friedel-Crafts alkylation reactions carbonyl compounds

Friedel-Crafts reaction carbonyl compounds

Furan, 2,5-bis reaction with carbonyl compounds

Furan, 2,5-bis reaction with carbonyl compounds from succinic anhydrides

Furan, 2,5-bis reaction with carbonyl compounds synthesis

Furan, 2,5-bis reaction with carbonyl compounds titanium tetrachloride catalyst

Furan, 2-trimethylsiloxyaldol condensation reaction with carbonyl compounds

General Reactions of Carbonyl Compounds

Grignard reaction: alkylation with carbonyl compounds

Grignard reagents carbonyl compound reactions

Grignard reagents reaction with carbonyl compounds

Henry reaction a,p-unsaturated carbonyl compounds

Heterocyclic methylene-active carbonyl compounds, reaction

Homoenolates reaction with carbonyl compounds

Hydration carbonyl compounds, reaction mechanisms

Hydrazones reaction with carbonyl compounds

Hydride shifts reactions with carbonyl compounds

Hydroxylamine, reaction with carbonyl compounds

Iodides reactions with carbonyl compounds

Iron, carbonyl compounds reaction with base

Iron-catalyzed reactions carbonyl compounds

Isoprene reactions with carbonyl compounds

Isoquinoline reactions with carbonyl compounds

Ketenes carbonyl compound reaction

Ketenes reaction with carbonyl compounds

Lanthanide homoenolates reactions with carbonyl compounds

Lewis acid carbonyl compound reactions

Lithium dialkylcuprates reactions with carbonyl compounds

Lithium, 1-phenylseleno-l-thioalkylreactivity reactions with carbonyl compounds

Lithium, 1-seleno-1-silylalkylreactivity reactions with carbonyl compounds

Lithium, a-selenoalkylacyl anion equivalents reactions with carbonyl compounds

Lithium, a-selenoalkylnucleophilicity reactions with carbonyl compounds

Lithium, a-selenoallylambident reactivity reactions with carbonyl compounds

Lithium, a-selenocyclopropylreactivity reactions with carbonyl compounds

Magnesium bromide allylstannane reaction with carbonyl compounds

Methanesulfonic acid reactions with carbonyl compounds

Methanethiol, phenyldianions reactions with carbonyl compounds

Modified Julia reaction, carbonyl compounds

Mori 2 Palladium-Catalyzed Hydrocarboxylation and Related Carbonylation Reactions of 7r-Bonded Compounds

Multicomponent reactions carbonyl compounds

Nickel sulfide silane reaction with carbonyl compounds

Nitrogen stabilization carbonyl compound addition reactions

Norrish Type I Cleavage Reaction of Carbonyl Compounds

Norrish Type II Reaction of Carbonyl Compounds

Organocadmium reagents reactions with carbonyl compounds

Organochromium reagents reactions with carbonyl compounds

Organolithium compounds carbonyl compound reactions

Organolithium reagents reactions with carbonyl compounds

Organolithiums reaction with carbonyl compounds

Organomagnesium reagents reactions with carbonyl compounds

Organometallic compounds, reactions with carbonyls

Organosilanes reactions with carbonyl compounds

Organostannanes reactions with carbonyl compounds

Organotin compounds reactions with carbonyls

Organotitanium reagents reactions with carbonyl compounds

Organozinc reagents reactions with carbonyl compounds

Other Reactions of Nucleophiles and Carbonyl Compounds

Oxazoline, 2-alkylmetallated achiral reactions with carbonyl compounds

Oxidation-reduction reactions, carbonyl compounds

Phenylhydrazine reaction with carbonyl compounds

Phosphonates, a-silyladdition reactions carbonyl compounds

Phosphonium ylides carbonyl compound reactions

Photochemical Reactions of Carbonyl Compounds

Photochemical cycloaddition reactions of carbonyl compounds with alkenes

Photocycloaddition reactions of carbonyl compounds

Pinacol coupling reactions with carbonyl compounds

Propargylic acetates reactions with carbonyl compounds

Propionic acid reactions with carbonyl compounds

Propionic acid, 3- dianions reactions with carbonyl compounds

Propyne, l,3-bis dilithium anion reaction with aliphatic carbonyl compounds

Pyrrole, 2,5-bis reaction with carbonyl compounds

Reaction of carbonyl compounds with sulfur tetrafluoride

Reaction of stabilized carbanions with carbonyl compounds

Reaction with Carbonyl Compounds 2 Imines

Reaction with carbonyl compounds

Reactions at the a Carbon of Carbonyl Compounds Enols and Enolates

Reactions of Carbonyl Compounds

Reactions of Carbonyl Compounds Simple Reversible Additions

Reactions of Carbonyl Compounds with Heteroatom Nucleophiles

Reactions of Carbonyl Compounds with Other Carbon Nucleophiles

Reactions of Carbonyl Compounds with a-Trimethylsilylcarbanions

Reactions of Co-ordinated Carbonyl Compounds with Nucleophiles

Reactions of Organolithiums with Carbonyl Compounds

Reactions with Chiral Non-Racemic Carbonyl Compounds

Reactions with Prochiral Carbonyl Compounds

Reactions with a, 3-Unsaturated Carbonyl Compounds

Reactions with carbonyl compounds aromatic aldehydes

Reactions with carbonyl compounds ketones

Reactions with carbonyl compounds mechanism

Reactions with carbonyl compounds olefin yields

Reactions with carbonyl compounds product isomerization

Recent Michael-Type Reactions Using Chirally Modified ,-Substituted Carbonyl Compounds

Reduction reactions carbonyl compounds

Rhodium, chlorotris catalyst silane reaction with carbonyl compounds

Schmidt reactions with carbonyl compounds

Selenides, p-hydroxyalkyl reactions with carbonyl compounds

Selenones, a-metalloalkyl reactions with carbonyl compounds

Selenonium ylides reactions with carbonyl compounds

Selenoxides, a-metalloalkyl reactions with carbonyl compounds

Selenoxides, a-metallovinyl reactions with carbonyl compounds

Silane, vinylepoxidation reaction with carbonyl compounds

Silanes reaction with carbonyl compounds

Silanes, allenyl annulations reactions with a,p-unsaturated carbonyl compounds

Silanones reactions with carbonyl compounds

Silyl enol ethers reactions with carbonyl compounds

Sodium bisulfite, reaction with carbonyl compounds

Stannanes reactions with carbonyl compounds

Stereoelectronics reactions of chiral carbonyl compounds with

Subject reactions with carbonyl compounds

Substitution Reactions of Carbonyl Compounds at the a Carbon

Sulfoxide, benzyl f-butyl reactions with carbonyl compounds

Sulfoxide, methyl p-tolyl reactions with carbonyl compounds

Sulfoxides, a-halo reactions with carbonyl compounds

Sulfoxides, alkyl aryl reactions with carbonyl compounds

Sulfoxides, allyl p-tolyl reactions with carbonyl compounds

Sulfur ylides reactions with carbonyl compounds

Syntheses of Carbonyl Compounds by Ring-Enlargement Reactions

The Reactions of Carbonyl Compounds with Hydride Ion

Thermo- and Photochemical Reactions of Carbonyl Compounds in the Solid State

Thioanisole reaction with carbonyl compounds

Titanium complexes reactions with carbonyl compounds

Titanium tetrachloride allylstannane reactions with carbonyl compounds

Titanium tetrachloride reactions with carbonyl compounds

Titanium, ally 1heterosubstituted reactions with carbonyl compounds

Titanium, allylheterosubstituted reactions with carbonyl compounds

Titanium, methyl reactions with carbonyl compounds

Titanium, trichloromethylproperties reaction with carbonyl compounds

Titanium, tris methylproperties reaction with carbonyl compounds

Tosylates reactions with carbonyl compounds

Two Useful Reactions of Nonenolizable Carbonyl Compounds

Unsaturated carbonyl compounds photochemical reactions

Unsaturated carbonyl compounds reaction with organocopper reagents

Unsaturated carbonyl compounds) reactions

Ylides reactions with carbonyl compounds

Ynamines reactions with carbonyl compounds

Zirconium reagents, allylic reaction with carbonyl compounds

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