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Carbonyl compounds, reactions with organolithiums or Grignard reagents

CARBONYL ADDITIONS, CERIUM(III) CHLORIDE-PROMOTED, 76, 237 Carbonyl compounds, reactions with organolithiums or Grignard reagents, 76, 228 Carboxylic acid amides, 77, 27 Cells, storage of, 76, 80 Centrifugation, 76, 78... [Pg.155]

USE OF CERIUM(III) CHLORIDE IN THE REACTIONS OF CARBONYL COMPOUNDS WITH ORGANOLITHIUMS OR GRIGNARD REAGENTS FOR THE SUPPRESSION OF ABNORMAL REACTIONS ... [Pg.228]

The competition between insertion and hydrogen transfer is also crucial to the selectivity of the reaction of aluminium alkyls with carbonyl compounds. Aluminium alkyls, like organolithium compounds and Grignard reagents, can add to aldehydes and ketones to form secondary or tertiary alcohols, respectively. If the aluminium alkyl has a j -hydrogen, however, reduction of the carbonyl compound is a common side reaction, and can even become the main reaction [16]. Most authors seem to accept that reduction involves direct j5-hydrogen transfer to ketone. [Pg.143]


See other pages where Carbonyl compounds, reactions with organolithiums or Grignard reagents is mentioned: [Pg.274]    [Pg.902]    [Pg.103]    [Pg.233]    [Pg.238]    [Pg.354]    [Pg.233]    [Pg.354]    [Pg.120]    [Pg.362]    [Pg.790]    [Pg.298]    [Pg.231]    [Pg.310]    [Pg.231]    [Pg.142]    [Pg.67]    [Pg.78]    [Pg.35]    [Pg.157]    [Pg.426]    [Pg.279]    [Pg.231]    [Pg.279]    [Pg.286]    [Pg.279]    [Pg.279]    [Pg.247]    [Pg.193]    [Pg.32]    [Pg.33]    [Pg.712]    [Pg.471]    [Pg.14]    [Pg.164]    [Pg.213]    [Pg.754]    [Pg.215]    [Pg.719]    [Pg.685]    [Pg.323]   
See also in sourсe #XX -- [ Pg.76 , Pg.228 ]

See also in sourсe #XX -- [ Pg.76 , Pg.228 ]




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Carbonyl compounds Grignard reagent

Carbonyl compounds organolithiums

Carbonyl compounds reagents

Carbonyl compounds, reactions

Carbonyl reagent

Grignard compounds

Grignard reagent carbonyl

Grignard reagents reaction with carbonyl compounds

Grignard reagents reactions

Organolithium compounds

Organolithium compounds carbonylation

Organolithium compounds, reactions

Organolithium reaction

Organolithium reagents

Organolithium reagents carbonyl compounds

Organolithium reagents compounds

Organolithium reagents reaction

Organolithium reagents reactions with carbonyl compounds

Organolithium with carbonyl compounds

Organolithiums reaction with carbonyl compounds

Organolithiums reagents

Reaction with Grignard reagents

Reaction with carbonyl compounds

Reaction with organolithium

Reaction with organolithium compounds

Reaction with organolithium reagents

With Carbonyl Compounds

With Grignard Reagents

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