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Carbon with nickel complex

Carbon-nitrogen bonds can be made using similar coupling reactions. With nickel complexes of chelating phosphines such as l,l -bis(diphenylphosphino)ferro-cene, even the generally unreactive aryl chlorides can be converted to anilines.94... [Pg.1267]

Dicyclopentadiene has two cyclopentene rings with different reactivities. In the reaction with nickel complexes and carbon dioxide only the more reactive norbornene ring couples with CO2, whereas the unstrained ring proved to be unreactive [14,16]. The last example in Figure 6 is cyclooctatetraene, which stands in a temperature-dependent equilibrium with bicyclo[4.2.0]octatriene. Both isomers undergo an oxidative coupling with nickel and CO2. Decomposition by hydrochloric acid leads to cycloocta-2,4,6-triene-carboxylic acid and bicyclo-[4.2.0]octa-2,4-diene-7-carboxylic acid [14]. [Pg.65]

Stable enolates such as diethyl malonate anions react with allyl sulfones (or acetates) in the presence of nickel complexes to give a mixture of the a- and /-product83. The regioselectivity is generally poor in the nickel-catalyzed reaction, but the molybdenum-catalyzed reaction is selective for alkylation at the more substituted allylic site, thereby creating a quaternary carbon center84. [Pg.878]

In the reaction of Ni(CNBu )4 and methyl iodide oligomerization of the isocyanide was observed the only isolable nickel complex was (I), shown below. This product is believed to arise through sequential insertions of three isocyanides into a nickel-carbon bond. Upon further treatment with additional isocyanide at a temperature greater than 60° C one obtains a polymer (RNC) presumably through multiple isocyanide insertion reactions. The addition of benzoyl chloride to Ni(CNBu )4 gave two isolable compounds Ni(CNBu )3(COPh)Cl (74%) and (II) (8.2%). This latter reaction, and the isolation of (II) in particular, suggests that the proposed mechanism for polymerization of isocyanides is reasonable. [Pg.32]

Pyridine compounds 45 can also be produced by the NHC-Ni catalysed cycloaddition between nitriles 43 and diynes 44 (Scheme 5.13) [16]. The SIPr carbene was found to be the best ligand for the nickel complex in this reaction. The reaction required mild reaction conditions and low catalyst loadings, as in the case of cycloaddition of carbon dioxide. In addition to tethered aUcynes (i.e. diynes), pyridines were prepared from a 3-component coupling reaction with 43 and 3-hexyne 23 (Scheme 5.13). The reaction of diynes 44 and nitriles 43 was also catalysed by a combination of [Ni(COD)J, NHC salts and "BuLi, which generates the NHC-Ni catalyst in situ. The pyridines 45 were obtained with comparable... [Pg.138]

Transition metals 172 a-bonded to cyclopropanes, substituted on the a-carbon with a halogen atom, are interesting intermediates for cyclopropylidene complexes 173 or allene ones 174 [88]. The former complexes are also supposed to be precursors of the above-mentioned nickel enolates. (Scheme 65)... [Pg.134]

Reactions of alcohols, ethers, and aliphatic halides with carbon monoxide were described as far back as 1948-1953 (173, 195). High pressure and temperature were required, however, for these processes. The use of alkaline media allowed carbonylation of alkyl iodides under mild conditions (example 22, Table VII). More recently, carbonylation of alkyl-nickel complexes was reported (example 26, Table VII). [Pg.232]

Oxidation of carbon ligands with concomitant insertion has been observed in the reaction of methallyl nickel complexes with norbornene or strained olefins in general and oxygen (example 3, Table IX). [Pg.239]

Insertion of carbon dioxide into olefin oxides gives olefin carbonates, and is an example of basic catalysis with nickel(O) complexes (example 14, Table XI). [Pg.243]

As seen from Scheme 7.2, the epoxy-ring cleavage and nickel oxidation proceed simultaneously. The nickel-oxygen bond is formed. This results in the formation of the carbon-nickel biradical in which Ph-CH fragment can rotate freely. The cleavage of the (NiO)-C bond leads to the formation of a mixture of styrenes. At early reaction stages (30 min), cis and trans olefins are formed in 50 50 ratio. After a prolonged contact (30 h), when all possible transformations should be completed, the trans isomer becomes the main product and cis trans ratio becomes 5 95. Such enrichment of the mixture with the trans isomer follows from the formation of the di-P-(trimethylsilyl)styrene anion-radical and its isomerization. The styrene formed interacts with an excess of the nickel complex. [Pg.350]

The number of theoretical investigations of transition metal complexes with carbodiphosphoranes and related divalent carbon(O) ligands is rather small. Quantum chemical calculations of the nickel complexes (CO) Ni-C(PPh3)2 with n = 2, 3 have been pubhshed together with experimental work which describes the S3mthesis and X-ray structure analyses of the compounds [107]. The first systematic... [Pg.66]

It is usual for a coordination compound to write the formula of a ligand with the donor atom first. The nickel complex represented above has both S and P bonded to the metal (as well as all the carbon atoms of the C5H5). The ring structure for chlorocyclohexane should be obvious. [Pg.16]

Nickel tetracarbonyl may be prepared in the laboratory by the Hieber process, a disproportion reaction of several nickel compounds of organic thio acids, such as nickel(II) phenyldithiocarbamate, (CeHs— NH—C(=S)—S)2Ni, with carbon monoxide under controlled conditions. In such disproportionation reactions, the divalent nickel ion converts to a tetravalent nickel complex (Hieber. H. 1952. Z.anorg.Chem., 269, pp. 28). The overall reaction is ... [Pg.625]

In the case of phosphine, especially tri-n-butyl and triphenyl phosphines, an active phosphine complex is formed in the reaction medium via reaction with nickel carbonyl. This complex is a very active species provided that the optimum concentration of phosphine is used. Low phosphine concentration results in a loss of the effective nickel concentration through the formation of nickel tetra-carbonyl, nickel metal or nickel iodide. The absolute concentration of phosphine is less important than the P/Ni ratio. In addition to form the stable Ni-P catalyst, the phosphine has to compete with other ligands in the reaction mixture for nickel. With high carbon monoxide partial pressure, there is more CO in solution to compete with phosphine favoring the formation of the carbonyl, which is inactive under the reaction conditions. Hence with high carbon mon-... [Pg.63]

The four-coordinate alkyl complex, LNiI(C0)CH3, may coordinate with carbon monoxide to regenerate the five coordinate alkyl species, and this leads to insertion to form Ni-acyl complex. This complex, LNil (CO)(COCH3), can be cleaved either by water yielding acetic acid or by methanol to give methyl acetate. However, in the presence of high iodide concentration formation of acetyl iodide may predominate (29). This step is reversible and can lead to decarbonylation under low carbon monoxide partial pressure. Similar decarbonylations of acyl halides by nickel complexes are known (34). [Pg.74]


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Carbon complex

Carbon-nickel

Carbonate complexation

Carbonate) complexes

Nickel carbonate

Nickel complexes reactions with carbon dioxide

Nickel complexes, with

With nickel

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