Carbon dioxide slurry absorption

Carbonate is measured by evolution of carbon dioxide on treating the sample with sulfuric acid. The gas train should iaclude a silver acetate absorber to remove hydrogen sulfide, a magnesium perchlorate drying unit, and a CO2-absorption bulb. Sulfide is determined by distilling hydrogen sulfide from an acidified slurry of the sample iato an ammoniacal cadmium chloride solution, and titrating the precipitated cadmium sulfide iodimetrically. 

The CNG process removes sulfurous compounds, trace contaminants, and carbon dioxide from medium to high pressure gas streams containing substantial amounts of carbon dioxide. Process features include 1) absorption of sulfurous compounds and trace contaminants with pure liquid carbon dioxide, 2) regeneration of pure carbon dioxide with simultaneous concentration of hydrogen sulfide and trace contaminants by triple-point crystallization, and 3) absorption of carbon dioxide with a slurry of organic liquid containing solid carbon dioxide. These process features utilize unique properties of carbon dioxide, and enable small driving forces for heat and mass transfer, small absorbent flows, and relatively small process equipment. 

The CNG acid gas removal process is distinguished from existing AGR processes by three features. The first feature is the use of pure liquid carbon dioxide as absorbent for sulfurous compounds the second feature is the use of triple-point crystallization to separate pure carbon dioxide from sulfurous compounds the third feature is the use of a liquid-solid slurry to absorb carbon dioxide below the triple point temperature of carbon dioxide. Pure liquid carbon dioxide is a uniquely effective absorbent for sulfurous compounds and trace contaminants triple-point crystallization economically produces pure carbon dioxide and concentrated hydrogen sulfide for bulk carbon dioxide absorption the slurry absorbent diminishes absorbent flow and limits the carbon dioxide absorber temperature rise to an acceptable low value. The sequence of gas treatment is shown in Figure 1, an overview of the CNG acid gas removal process. 

The absorption of carbon dioxide with slurry and the regeneration of slurry by flashing carbon dioxide require small temperature and pressure driving forces. The small driving forces derive from the huge surface area of the solid carbon dioxide particles and the low viscosity of the slurry. Compared with other sub-ambient temperature carbon dioxide removal processes, the CNG process requires less refrigeration even though process temperatures are often lower. 

Carbon dioxide removal by slurry absorption is attractive down to about -75°C, a temperature easily achieved by slurry regeneration to slightly above one atmosphere carbon dioxide pressure. For example, with a -75°C exit gas temperature, slurry absorption reduces the carbon dioxide content of a 1000 psia synthesis gas from about 13 to about 4 mole percent, a 70% reduction in carbon dioxide content. The exact level to which carbon dioxide can be removed from a treated gas by slurry absorption also depends on the solubility of solid carbon dioxide in the treated gas the solubility of solid carbon dioxide in synthesis gas (3H2 CO) is illustrated in Figure 10 for several synthesis gas pressures. Fine removal of carbon dioxide to lower levels is accomplished by conventional absorption into a slip stream of the slurry solvent which is regenerated to meet particular product gas carbon dioxide specifications. 

The process features of carbon dioxide triple-point crystallization and slurry absorption of carbon dioxide have been demonstrated with the first generation bench-scale apparatus. Current efforts are focused on the design and construction of an improved version of the carbon dioxide triple-point crystallizer in cooperation with the U S Department of Energy. Future efforts are planned to design and construct absorption units to study multi-stage slurry absorption of carbon dioxide, and the more conventional gas-liquid absorption of sulfuruous compounds with liquid carbon dioxide. 

Absorption of C02 in aqueous slurry of lime for the manufacture of precipitated calcium carbonate (which is reused in large quantities as a rubber filler, a pigment, etc.). Here lime is sparingly soluble in water and the reaction occurs between the dissolved carbon dioxide and OH" ions. 

Lime scrubbing is quite similar to limestone scrubbing except that the pH in the delay tank is higher, about 8-10 as compared with 5.8-6.0 in limestone scrubbing. The pH apparently drops quickly when the slurry returns to the scrubber, caused by absorption of carbon dioxide and sulfur dioxide, so that the scrubber exit pH is about 5.4-5.8 no matter which absorbent is used. 

Cheng L, li T, Keener TC, Lee JY. A mass transfer model of absorption of carbon dioxide in abubblecolumnreactorbyusingmag-nesium hydroxide slurry. InL J. Greenh. Gas Control 2013 17 240-249. 

The pH of the solution is maintained low enough to avoid carbon dioxide absorption, but high enough to minimize vessel corrosion. Additives buffer the slurry pH above 6.0 (Schaack and Chan, 1989). The inlet gas must be saturated with water and free of liquid contaminants. An efficient inlet separator is recommended (Manning, 1979). 

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