CAAs

The two levels of NAAQS, primary and secondary, are Hsted in Table 3. Primary standards were set to protect pubHc health within an adequate margin of safety secondary standards, where appHcable, were chosen to protect pubHc welfare, including vegetation. According to the CAA, the scientific bases for the NAAQS are to be reviewed every 5 years so that the NAAQS levels reflect current knowledge. In practice, however, the review cycle takes considerably longer. 

The Resource Conservation and Recovery Act (RCRA) controls the disposal of ha2ardous waste. SARA Tide III governs the toxic iaventory and emission reporting the Clean Water Act (CWA) sets the limits for metals that can be present ia water discharge and the Clear Air Act (CAA)... 

Various laws have been passed in the United States to control air pollution. The first law that had any real effect was the Clean Air Act of 1970 (CAA), which was followed by the Clean Air Act Amendments of 1977. Most recentiy, the Clean Air Act Amendments (CAAA) of 1990 (5) further changed and updated the requirements. 

Clean Air Act (CAA) Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)... 

Production. MTBE production capacity has grown steadily, usually at an annual rate of 10 to 20% per year. In 1980, world capacity was 30 thousand barrels per day (1.5 X 10 t/yr). By 1990, capacity was up to 180 thousand barrels per day (7 x 10 t/yr). Because of the requirements of the U.S. CAA, production capacity is expected to more than double from 1990 to 1995 (25). By 2000, MTBE may be the second largest organic chemical produced in the United States, second only to ethylene (26). 

Because there does not appear to be sufficient MTBE capacity to satisfy the oxygen requirements for the 1990 CAA revision, there has been a general upward movement ia MTBE market prices that should provide the iacentive for additional capacity to be built (27). 

CAA Clean Air Act PIES Pollution prevention information exchange systems... 

Sources Subject to Prevention of Significant Deterioration (PSD) Sources subject to PSD regulations (40 CFR, Sec. 52.21, Aug. 7, 1980) are major stationary sources and major modifications located in attainment areas and unclassified areas. A major stationaiy source was defined as any source hsted in Table 25-4 with the potential to emit 100 tons per year or more of any pollutant regulated under the Clean Air Act (CAA) or any other source with the potential to emit 250 tons per year or more of any CAA pollutant. The potential to emit is defined as the maximum capacity to emit the pollutant under apphcable emission standards and permit conditions (after apphcation of any air pollution control equipment) excluding secondaiy emissions. A major modification is defined as any physical or operational change of a major stationaiy source producing a significant net emissions increase of any CAA pollutant (see Table 25-5). 

Ambient monitoring is required of all CAA pollutants with emissions greater than or equal to Table 25-5 values for which there are... 

NAAQS. Continuous monitoring is also required for other CAA pollutants for which the EPA or the state determines that monitoring is necessary. The EPA or the state may exempt any CAA pollutant from these monitoring requirements if the maximum air-quahty impact of the emissions increase is less than the values in Table 25-6 or if present concentrations of the pollutant in the area that the new source would affect are less than the Table 25-6 values. The EPA or the state... 

New Source Performance Standards (NSPS) were promulgated under Sections 111(b) and 129 of the CAA Amendments of 1990. The NSPS apphes to new municipal sohd-waste combustors (MWCs) with... 

In addition, restrictions on industrial air emissions under the Clean Air Act (CAA) as amended in 1977, the Clean Air Act Amendments (CAAA) of 1990, and other state and local statutes and regulations have universal impact on the storage of toxic materials, with direct and significant effects on the design and operation of toxic material storage facilities. Whereas the primary factors which once determined how air emissions from storage tanks were handled were fire protection and loss prevention, in recent years environmental protection concerns nearly always determine the extent and nature of the air emission controls required to be installed. 

The Clean Air Act Amendments of 1990 put a heavy burden on the Environmental Protection Agency (EPA) and state agencies to permit and oversee compliance with the Clean Air Act (CAA). Table 24-1 lists the major deadlines affecting industry under the 1990 amendments. Some of the deadlines have already passed without any action" being promulgated and finalized. The other deadlines may also slip to a later date. Almost no statutorv "hammers" have been included in CAAA90. 

Toxic air pollutants are pollutants which are hazardous to human health or the environment but which are not specifically regulated by the CAA. These pollutants are typically carcinogens, mutagens, and teratogens. The CAAA of 1977 failed to result in substantial reductions in the emissions of these harmful substances. 

Onboard Refueling Vapor Recovery (OR ) regulations were fust proposed m 1987 but were met with a litany of technical and safety issues that delayed the requirement. The 1990 CAA amendments required the implementation of ORVR and the EPA regulation requires passenger cars to first have the systems starting in 1998. The ORVR test will be performed in a SHED and will require that not more than 0.2 grams of hydrocarbon vapor per gallon of dispensed fuel be released from the vehicle. 

At elevated temperatures where titanium alloys could be the adherend of choice, a different failure mechanism becomes important. The solubility of oxygen is very high in titanium at high temperatures (up to 25 at.%), so the oxygen in a CAA or other surface oxide can and does dissolve into the metal (Fig. 12). This diffusion leaves voids or microcracks at the metal-oxide interface and embrittles the surface region of the metal (Fig. 13). Consequently, bondline stresses are concentrated at small areas at the interface and the joint fails at low stress levels [51,52]. Such phenomena have been observed for adherends exposed to 600°C for as little as 1 h or 300°C for 710 h prior to bonding [52] and for bonds using... 

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