Butyl Sheets

This gives plants and wildlife time to settle in before the following winter. This pond is lined with a flexible butyl sheet liner. PVC is not recommended for use in the organic garden it contains potentially carcinogenic plasticizers and also poses a threat of chlorine pollution on disposal. 

For zinc oxide at, for example, levels of 15 to 45 phr, good filler dispersion is essential for better dimensional stability in calendered sheets. Butyl sheets are used in storage tanks, digesters and other large equipment handling phosphoric acid, hydrochloric acid and sulfuric acid very effectively in fertiliser and chlor-alkali plants. When high temperatures are encountered, carbon bricks or acid resistant bricks are lined over the rubber lining. 

Acrylic Acid Recovery. The process flow sheet (Fig. 3) shows equipment and conditions for the separations step. The acryUc acid is extracted from the absorber effluent with a solvent, such as butyl acetate, xylene, diisobutyl ketone, or mixtures, chosen for high selectivity for acryUc acid and low solubihty for water and by-products. The extraction is performed using 5—10 theoretical stages in a tower or centrifiigal extractor (46,61—65). 

Esterifica.tlon. The process flow sheet (Fig. 4) outlines the process and equipment of the esterification step in the manufacture of the lower acryflc esters (methyl, ethyl, or butyl). For typical art, see References 69—74. The part of the flow sheet containing the dotted lines is appropriate only for butyl acrylate, since the lower alcohols, methanol and ethanol, are removed in the wash column. Since the butanol is not removed by a water or dilute caustic wash, it is removed in the a2eotrope column as the butyl acrylate a2eotrope this material is recycled to the reactor. 

The dehydrogenation of 2-butanol is conducted in a multitube vapor-phase reactor over a zinc oxide (20—23), copper (24—27), or brass (28) catalyst, at temperatures of 250—400°C, and pressures slightly above atmospheric. The reaction is endothermic and heat is suppHed from a heat-transfer fluid on the shell side of the reactor. A typical process flow sheet is shown in Figure 1 (29). Catalyst life is three to five years operating in three to six month cycles between oxidative reactivations (30). Catalyst life is impaired by exposure to water, butene oligomers, and di-j -butyl ether (27). 

The first use for butyl mbber was ia inner tubes, the air-retention characteristics of which contributed significantly to the safety and convenience of tires. Good weathefing, ozone resistance, and oxidative stabiUty have led to appHcations ia mechanical goods and elastomeric sheeting. Automobile tires were manufactured for a brief period from butyl mbber, but poor abrasion resistance restricted this development at the time. 

Copolymers of methyl methacrylate and butyl acrylate gave polymers that were somewhat tougher and slightly softer than the homopolymers. Materials believed to be of this type were marketed in sheet form by ICI as Asterite for a short while in the 1960s (the name having been recently revived for another product as described in Section 15.2.6). 

Two possible forms of membrane are hot applied mastic asphalt or bitumen/butyl rubber sheeting with welded or glued joints. The membrane under the floor slabs has to be lapped with that around the walls. It is essential that the membrane is protected during construction, and a typical arrangement is as shown in Figure 6.15. 

Laminated tapes In more general use now than pressure sensitive tapes are tapes consisting of polyvinyl chloride or polyethylene films in conjunction with butyl rubber. These tapes are applied with an adhesive butyl rubber primer. Thicknesses of up to 0-75 mm are in use and loose protective outer wraps of p.v.c. or polyethylene sheet are commonly applied. Tape quality control is exercised with reference to ASTM standard test methods and may include water vapour transmission rate and elongation. 

Lithium dispersion can be safely destroyed by carefully adding it in small portions to a large excess of technical tert-butyl alcohol in a metal pan. If too much lithium is added at one time, the reaction with the ferf-butyl alcohol can become very vigorous. Under these circumstances, a fire can be avoided by covering the pan with a second, larger metal pan or with an asbestos sheet. 

In an acetone extract from a neoprene/SBR hose compound, Lattimer et al. [92] distinguished dioctylph-thalate (m/z 390), di(r-octyl)diphenylamine (m/z 393), 1,3,5-tris(3,5-di-f-butyl-4-hydroxybenzyl)-isocyanurate m/z 783), hydrocarbon oil and a paraffin wax (numerous molecular ions in the m/z range of 200-500) by means of FD-MS. Since cross-linked rubbers are insoluble, more complex extraction procedures must be carried out (Chapter 2). The method of Dinsmore and Smith [257], or a modification thereof, is normally used. Mass spectrometry (and other analytical techniques) is then used to characterise the various rubber fractions. The mass-spectral identification of numerous antioxidants (hindered phenols and aromatic amines, e.g. phenyl-/ -naphthyl-amine, 6-dodecyl-2,2,4-trimethyl-l,2-dihydroquinoline, butylated bisphenol-A, HPPD, poly-TMDQ, di-(t-octyl)diphenylamine) in rubber extracts by means of direct probe EI-MS with programmed heating, has been reported [252]. The main problem reported consisted of the numerous ions arising from hydrocarbon oil in the recipe. In older work, mass spectrometry has been used to qualitatively identify volatile AOs in sheet samples of SBR and rubber-type vulcanisates after extraction of the polymer with acetone [51,246]. 

Figure III.1 Product sheet of the phenolic antioxidant 2,2 -methylene-bis-(6-tert-butyl-4-methylphenol). After Gijsman [1], Reproduced by permission of P. Gijsman...

The materials selected for evaluation included three materials currently being used in these applications Biomer (Thoratec Laboratories Corporation, Emeryville, CA), representative of segmented ether-type polyurethanes Avcothane-51 (Avco Everett Research Laboratory, Inc., Everett, MA), a block copolymer of 10% silicone rubber and 90% polyurethane and Hexsyn (Goodyear Tire and Rubber Company, Akron, OH), a sulfur vulcanized hydrocarbon rubber that is essentially a polyhexene. Also selected, because of their easy availability, were Pellethane (Upjohn Company, North Haven, CT), an ether-type of polyurethane capable of being extruded in sheet form, and a butyl rubber formulation, compounded and molded at the National Bureau of Standards. The material thickness varied, but the sheets were generally about 1 mm thick. 

Rohm and Haas, "BUTYL ACRYLATE", Material Safety Data Sheet, Philadelphia (Oct., 1978). 

Petro-Tex Chemical Corp., "METHYL TERT-BUTYL ETHER , Material Safety Data Sheet, Houston, TX (1979). 

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