Bunch

Karataev V I, Mamyrin B A and Shmikk D V 1972 New method for focusing ion bunches in time-of-flight mass spectrometers Sov. Phys.-Tech. Phys. 16 1177... 

Finally, tlie ability to optically address single molecules is enabling some beautiful experiments in quantum optics. The non-Poissonian photon arrival time distributions expected tlieoretically for single molecules have been observed directly, botli antibunching at short times [112] and bunching on longer time scales [6, 112 and 113]. The fluorescence excitation spectra of single molecules bound to spherical microcavities have been examined as a probe... 

Figure C 1.5.10. Nonnalized fluorescence intensity correlation function for a single terrylene molecule in p-terjDhenyl at 2 K. The solid line is tire tlieoretical curve. Regions of deviation from tire long-time value of unity due to photon antibunching (the finite lifetime of tire excited singlet state), Rabi oscillations (absorjDtion-stimulated emission cycles driven by tire laser field) and photon bunching (dark periods caused by intersystem crossing to tire triplet state) are indicated. Reproduced witli pennission from Plakhotnik et al [66], adapted from [118].

Bernard J, Fleury L, Talon FI and Orrit M 1993 Photon bunching in the fluorescence from single molecules a probe for intersystem crossing J. Phys. Chem 98 850-9... 

This paper is meant as a contribution to systematize the quantum-classical modeling of molecular dynamics. Hence, we are interested in an extended theoretical understanding of the models rather than to further contribute to the bunch of numerical experiments which have been performed on certain models by applying them to particular molecular systems. Thus, we will carefully review the assumptions under which our models are known to approximate the full quantum dynamical (QD) evolution of the system. This knowledge... 

M. Hochbruck and Ch. Lubich A bunch of time integrators for quan-... 

A Bunch of Time Integrators for Quantum/Classical Molecular Dynamics... 

If the chemist wants to know whether her final product is bromo-safrole and not just a bunch of unreacted safrole there is a simple little test she can do. Safrole is soluble (will dissolve in) cold concentrated sulfuric acid. But bromosafrole is insoluble in it. So the chemist can take a shot glass full of straight-from-the-bottle 96% H2SO4 and place it in the freezer until it s ice cold. Then she takes it out and drops a few drops of mystery product into it. If the oil dissolves then the stuff is unreacted safrole. If the oil drops to the bottom and does not dissolve it s the goods. 

Although Pasteur was unable to provide a structural explanation—that had to wait for van t Hoff and Le Bel a quarter of a century later—he correctly deduced that the enantiomeric quality of the crystals was the result of enantiomeric molecules The rare form of tartanc acid was optically inactive because it contained equal amounts of (+) tartaric acid and (—) tartaric acid It had earlier been called racemic acid (from Latin racemus meaning a bunch of grapes ) a name that subsequently gave rise to our pres ent term for an equal mixture of enantiomers... 

Diagram showing a flow of ions of m/z a, b, c, etc. traveling in bunches toward the front face of a microchannel array. After each ion strikes the inside of any one microchannel, a cascade of electrons is produced and moves toward the back end of the microchannel, where they are collected on a metal plate. This flow of electrons from the microchannel plate constitutes the current produced by the incoming ions (often called the ion current but actually a flow of electrons). The ion.s of m/z a, b, c, etc. are separated in time and reach the front of the microchannel collector array one set after another. The time at which the resulting electron current flows is proportional to V m/z). 

There is no theoretical upper limit on m/z that can be examined, and TOF mass spectrometry is useful for substances having very high molecular mass. In practice, the current upper limit is about 350,000. Unfortunately, ions even of the same m/z value do have a spread of velocities after acceleration, so the resolution achievable with TOF is not very high because bunches of ions of one m/z value overlap those at the next m/z value. 

The polyethylene crystals shown in Fig. 4.11 exist as hollow pyramids made up of planar sections. Since the solvent must be evaporated away prior to electron microscopic observation, the pyramids become buckled, torn, and/ or pleated during the course of sample preparation. While the pyramidal morphology is clearly evident in Fig. 4.1 la, there is also evidence of collapse and pleating. Likewise, the ridges on the apparently planar crystals in Fig. 4.1 lb are pleats of excess material that bunches up when the pyramids collapse. 

B. H. Bunch and A. HeUemans, The Timetables of Technology, Simon and Schuster, New York, 1993. 

Because of the unique features of the x-ray radiation available at synchrotrons, many novel experiments ate being conducted at these sources. Some of these unique features are the very high intensity and the brightness (number of photons per unit area per second), the neatly parallel incident beam, the abihty to choose a narrow band of wavelengths from a broad spectmm, the pulsed nature of the radiation (the electrons or positrons travel in bunches), and the coherence of the beam (the x-ray photons in a pulse are in phase with one another). The appHcations are much more diverse than the appHcations described in this article. The reader may wish to read the articles in the Proceedings of the Materials Research Society Hsted in the bibhography. 

Dongarra, J. J., J. R. Bunch, C. B. Moler, and G. W. Stewart. LINFACK Users Guide, Society for Industrial and Apphed Mathematics, Philadelphia (1979). 

Consider an average derating of 0.8 for a number of power cables bunched together, generally not more than six at a lime. 

Control wiring Wiring from supervisory or annunciator devices to the terminal blocks may be carried out with smaller wires, as may be recommended for such devices. However, they should run through separate wire bunches, and not through the bunches of control wires for easy identification and to remain unaffected by heat of control wires. 

For easy identification and prompt maintenance it is mandatory to segregate all control wires when they are carrying more than one control supply (e.g. at different voltages and both a.c. and d.c.), and run them in separate bunches. The control wires must also be of different colours for different control supplies. The colour codes have been standardized for different control supplies (refer to lEC 60445). 

All ion gun optical columns are provided with deflection plates for scanning the ion beam over areas adjustable from a few square micrometers to many square millimeters. They have been adapted for pulsing by the introduction of additional deflection plates which rapidly sweep the beam across an aperture. By applying an ion beam bunching technique, ion pulses less than 1 ns wide can be produced. 

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