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Bucherer

Bucherer reaction Bucherer discovered that the interconversion of 2-naphthol and 2-naphthylamine through the action of alkali and ammonia could be facilitated if the reaction was carried out in the presence of (HSO3]" at about 150 C. This reaction is exceptional for the ease with which an aromatic C —OH bond is broken. It is not of general application, it is probable that the reaction depends upon the addition of [HSO3]" to the normally unstable keto-form of 2-naphthol, and subsequent displacement of —OH by —NH2. [Pg.69]

Bucher J P, Douglass D C and Bloomfield L A 1991 Magnetic properties of free cobalt clusters Phys. Rev. Lett. 66 3052... [Pg.2405]

Bucher P N and Cotter D 1990 The Eiements of Noniinear Optics (New York Cambridge University Press)... [Pg.2875]

The reversibility of the Bucherer reaction is utilised in the preparation of 2-p-tolylamino-5-hydroxynaphthalene-T-3ulphonic acid (II) from 2-amino-... [Pg.561]

The above reaction is an example of Bucherer s hydantoin synthesis. The following mecJiavism has been proposed ... [Pg.843]

Benzilic acid rearrangement Benzoin reaction (condensation) Blanc chloromethylation reaction Bouveault-Blanc reduction Bucherer hydantoin synthesis Bucherer reaction Cannizzaro reaction Claisen aldoi condensation Claisen condensation Claisen-Schmidt reaction. Clemmensen reduction Darzens glycidic ester condensation Diazoamino-aminoazo rearrangement Dieckmann reaction Diels-Alder reaction Doebner reaction Erlenmeyer azlactone synthesis Fischer indole synthesis Fischer-Speior esterification Friedel-Crafts reaction... [Pg.1210]

B. typhosus Bubble Breaker Bubble jet technology Bubble memory devices Bubble packs Bubble-point test Bubble shapes Bubbling-bed design Buccal tablets Bucherer-Bergs reaction Bucherer reaction Bucherer synthesis Bucidovir [86304-28-1]... [Pg.135]

The Bucher-Guyer horizontal rotary press is a highly automated batch process machine that requires no press aid. The press consists of a horizontal hydrauhc ram inside a rotating cylinder containing many flexible rods covered with a knitted synthetic fabric. The rods have serrated surfaces to allow juice which passes through the fabric to flow to the discharge ends. Hydrauhc pressure is apphed for a preset time, the ram is retracted, and the cylinder is rotated to break up the press cake. This cycle is repeated several times before the press cake is removed from the cylinder and the press is cleaned (16). Juice yield for this horizontal rotary press is 84% with secondary water addition it is increased to 92% (15). [Pg.572]

Synthesis from Aldehydes and Ketones. Treatment of aldehydes and ketones with potassium cyanide and ammonium carbonate gives hydantoias ia a oae-pot procedure (Bucherer-Bergs reactioa) that proceeds through a complex mechanism (69). Some derivatives, like oximes, semicarbazones, thiosemicarbazones, and others, are also suitable startiag materials. The Bucherer-Bergs and Read hydantoia syntheses give epimeric products when appHed to cycloalkanones, which is of importance ia the stereoselective syathesis of amino acids (69,70). [Pg.254]

Synthesis from Thiohydantoins. A modification (71) of the Bucherer-Bergs reaction consisting of treatment of an aldehyde or ketone with carbon disulfide, ammonium chloride, and sodium cyanide affords 2,4-dithiohydantoias (19). 4-Thiohydantoias (20) are available from reaction of amino nitriles with carbon disulfide (72). Compounds (19) and (20) can be transformed iato hydantoias. [Pg.254]

Nitration. Naphthalene is easily nitrated with mixed acids, eg, nitric and sulfuric, at moderate temperatures to give mostly 1-nitronaphthalene and small quantities, 3—5%, of 2-nitronaphthalene. 2-Nitronaphthalene [581-89-5] is not made in substantial amounts by direct nitration and must be produced by indirect methods, eg, the Bucherer reaction starting with 2-naphthalenol (2-naphthol [135-19-3]). However, the 2-naphthylamine [91-59-8] made using this route is a carcinogen thus the Bucherer method is seldom used in the United States. [Pg.482]

Many aminonaphthalenesulfonic acids are important in the manufacture of azo dyes (qv) or are used to make intermediates for azo acid dyes, direct, and fiber-reactive dyes (see Dyes, reactive). Usually, the aminonaphthalenesulfonic acids are made by either the sulfonation of naphthalenamines, the nitration—reduction of naphthalenesulfonic acids, the Bucherer-type amination of naphtholsulfonic acids, or the desulfonation of an aminonaphthalenedi-or ttisulfonic acid. Most of these processes produce by-products or mixtures which often are separated in subsequent purification steps. A summary of commercially important aminonaphthalenesulfonic acids is given in Table 4. [Pg.494]

By the Bucherer reaction (with sulfite) of the appropriate arninonaphthalenesulfonic acid. [Pg.501]

In some cases, Bucherer s process is employed also, but strict control of reaction conditions is needed because the reactivity of formaldehyde is different from other aldehydes. DL-Alanine (212) is produced by either Strecker s or Bucherer s process from acetaldehyde. [Pg.291]

Hydroxyisoquinolines. Hydroxy groups in the 5-, 6-, 7-, and 8-position show phenoHc reactions for example, the Bucherer reaction leads to the corresponding anainoisoquinolines. Other typical reactions include the Mannich condensation, azo-coupling reactions, and nitrosation. Both 0-methyl and /V-methyl derivatives are obtained from the methylation of 1-hydroxyisoquinoline, indicating that both tautomeric forms are present. Distillation of various hydroxy compounds, eg, 1- and 4-hydroxyisoquinoline, with zinc dust removes the oxygen. Treatment of 1-isoquinolinol with phosphoms tribromide yields 1-bromoisoquinoline [1532-71 -4] (178). [Pg.398]

Amination of phenoHc derivatives is limited to specially developed catalytic processes for aniline and y -toluidine (3). More general conditions apply to amination of naphthols by the Bucherer reaction. Important intermediates made by a Bucherer reaction include Tobias acid and gamma acid. [Pg.292]

V-Alkyl and A/-aryl substituted naphthyl amines are also important, eg, letter acid derivatives, but are usually manufactured by the Bucherer reaction. [Pg.292]

BUCHERER LE PETIT Naphthol (Naphihylamine) Synthesis Synthesis of naphihylamines tram naphthols and naphihols from naphthylamines... [Pg.54]

Efforts are still being made to estimate that elusive notion quality in smoking tobacco by chemical analysis it does at least seem to be clearly established that a low content of protein and of nicotine is desirable, and in that connection the isolation by Bucherer of several species of... [Pg.48]

Among other formulae which must be mentioned are those of Vis, which represents morphine as a benzyh soquinoline, Vongerichten, Bucherer, Gadamer and Klee, devised to account for the possible natural formation in P. orientate of isothebaine from thebaine, and the vinyl formula of Wieland and Kappelmeier. ... [Pg.240]

The Bucherer carbazole synthesis " involves the treatment of a naphthyl alcohol (1 or 4) or a naphthyl amine (2 or 5) with a phenylhydrazine 3 in the presence of aqueous sodium bisulfite to afford, after acidic work-up, either a benzo[a]carbazole 4 or benzo[c]carbazole 6. [Pg.110]

The Bucherer carbazole synthesis was first demonstrated when 7 was heated in the presence of phenylhydrazines 8, sodium hydroxide and sodium bisulfite after acidic work-up, the benzocarbazole product 9 was isolated (-70% yield). When 2-naphthol was used the reaction was significantly slower with the yield of benzocarbazole being only 46% after several days at 130 °C Bucherer and co-workers investigated this reaction extensively concluding, incorrectly, that intermediate products were probably carbazole-Al-sulfonic acids due to the ease with which they lost the sulfonic acid residues to yield benzocarbazoles. [Pg.110]

Whereas the similarity between the Bucherer carbazole synthesis and the Fischer indolisation was noted by Bucherer and Seyde in their pioneering work, it was only later... [Pg.111]


See other pages where Bucherer is mentioned: [Pg.270]    [Pg.561]    [Pg.604]    [Pg.355]    [Pg.254]    [Pg.167]    [Pg.277]    [Pg.277]    [Pg.496]    [Pg.462]    [Pg.383]    [Pg.276]    [Pg.160]    [Pg.546]    [Pg.549]    [Pg.339]    [Pg.172]    [Pg.287]    [Pg.54]    [Pg.467]    [Pg.143]    [Pg.461]    [Pg.472]    [Pg.99]    [Pg.110]    [Pg.112]   
See also in sourсe #XX -- [ Pg.157 , Pg.301 ]

See also in sourсe #XX -- [ Pg.96 ]

See also in sourсe #XX -- [ Pg.47 ]




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2- Naphthol Bucherer reaction with

Aldehydes Bucherer-Bergs reaction

And the Bucherer reaction

BUCHERER - LE PETIT Naphthol

Bucher

Bucher

Bucher studies

Bucherer carbazole synthesis

Bucherer hydantoin synthesis

Bucherer modification

Bucherer reaction

Bucherer reaction, aminonaphthalene

Bucherer reaction, application

Bucherer substitution

Bucherer synthesis

Bucherer, Hans

Bucherer-Berg multicomponent reactions

Bucherer-Bergs

Bucherer-Bergs 4-component reaction

Bucherer-Bergs And Strecker Multicomponent Reactions

Bucherer-Bergs condensation

Bucherer-Bergs hydantoin synthesis

Bucherer-Bergs modified

Bucherer-Bergs reaction

Bucherer-Bergs reaction Mechanism

Bucherer-Bergs reaction, Strecker amino acid

Bucherer-Bergs synthesis, amino acids

Bucherer-Le Petit

Bucherer-Lieb variation

Hydantoins Bucherer-Bergs reaction

Mechanism Bucherer reaction

Modified Bucherer-Bergs Reaction

Presses Bucher

Retro-Bucherer reaction

Synthesis Bucherer-Bergs

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