Bimetallic cases

Bimetallic Cases. In addition, we have discovered that a result, perhaps related to this differential charging effect, may, in some cases, be chemically induced. In this regard, we have examined a series of Pd doped-alumina systems that are also infused with different alkali cations. Even without physical abuses, these systems produce the aforementioned negative shift (with respect to "normal" Pd°), and one also finds that the size of the shift seems to depend, in a regular fashion, on which alkali cation is employed (i.e., the relative ionicity of the latter ), see Figure 4. This result seems to suggest two possible explanations. Either the... 

A non-disjoint mechanism, which at least in principle allows simultaneous linear-bilinear kinetics, is shown in Fig. 9. This arises exclusively in the bimetallic case (M) [M l when the core CBER structure is shared with a unicycUc mechanism. In this case, there are two pathways for product formation, and this arises from three interconnected cycles. There is one set of all important steps a and p, and there are four sequences of intermediates. Three of these sequences are mcmonuclear and one is dinuclear. 

Surface heterogeneity may merely be a reflection of different types of chemisorption and chemisorption sites, as in the examples of Figs. XVIII-9 and XVIII-10. The presence of various crystal planes, as in powders, leads to heterogeneous adsorption behavior the effect may vary with particle size, as in the case of O2 on Pd [107]. Heterogeneity may be deliberate many catalysts consist of combinations of active surfaces, such as bimetallic alloys. In this last case, the surface properties may be intermediate between those of the pure metals (but one component may be in surface excess as with any solution) or they may be distinctly different. In this last case, one speaks of various effects ensemble, dilution, ligand, and kinetic (see Ref. 108 for details). 

Coatings of more noble metals than the substrate metal (e.g., Cu on Fe) are only protective when there are no pores. In other cases severe local corrosion occurs due to cell formation (bimetallic corrosion). Cathodic protection is theoretically possible. This protection combination is not very efficient since the coating usually consumes more protection current than the uncoated steel. 

Consider the two cases of (1) two unbonded metal strips of different coefficients of thermal expansion placed side by side but not bonded and (2) the same two strips bonded together. For case (1), at room temperature, the two strips are the same length. When they are heated, both strips elongate (their primary observable change, but they do also get wider and thicker). For case (2) at room temperature, the strips are also of the same length but bonded together. When the bonded bimetallic... 

Most cases of practical bimetallic corrosion in solutions occur under conditions when the solution contains dissolved oxygen. Accordingly, the primary cathodic reaction is the reduction of dissolved oxygen... 

Contact with steel, though less harmful, may accelerate attack on aluminium, but in some natural waters and other special cases aluminium can be protected at the expense of ferrous materials. Stainless steels may increase attack on aluminium, notably in sea-water or marine atmospheres, but the high electrical resistance of the two surface oxide films minimises bimetallic effects in less aggressive environments. Titanium appears to behave in a similar manner to steel. Aluminium-zinc alloys are used as sacrificial anodes for steel structures, usually with trace additions of tin, indium or mercury to enhance dissolution characteristics and render the operating potential more electronegative. 

Disadvantages Possible interaction effects on other buried structures (Section 10.6) subject to the availability of a suitable a.c. supply source or other source of d.c. regular electrical maintenance checks and inspection required running costs for electrical supply (usually not very high except in the case of bare marine structures and in power stations where structures are often bare and include bimetallic couples) subject to power shutdowns and failures. 

Cadmium also provides a sacrificial coating to steel which gives better protection than zinc in applications where strong acids and alkalis may be encountered and those involving immersion in stagnant or soft neutral waters. It should be used in applications involving bimetallic contact with aluminium and in electrical applications where ease of solderability is important. Cadmium has a low torque resistance and should be used as a coating material in cases where bolted assemblies have to be frequently... 

It is evident from previous considerations (see Section 1.4) that the corrosion potential provides no information on the corrosion rate, and it is also evident that in the case of a corroding metal in which the anodic and cathodic sites are inseparable (c.f. bimetallic corrosion) it is not possible to determine by means of an ammeter. The conventional method of determining corrosion rates by mass-loss determinations is tedious and over the years attention has been directed to the possibility of using instantaneous electrochemical methods. Thus based on the Pearson derivation Schwerdtfeger, era/. have examined the logarithmic polarisation curves for potential breaks that can be used to evaluate the corrosion rate however, the method has not found general acceptance. 

Laboratory tests used in the development of inhibitors can be of various types and are often associated with a particular laboratory. Thus, in one case simple test specimens, either alone or as bimetallic couples, are immersed in inhibited solutions in a relatively simple apparatus, as illustrated in Fig. 19.34. Sometimes the test may involve heat transfer, and a simple test arrangement is shown in Fig. 19.35. Tests of these types have been described in the literatureHowever, national standards also exist for this type of test approach. BSl and ASTM documents describe laboratory test procedures and in some cases provide recommended pass or fail criteria (BS 5117 Part 2 Section 2.2 1985 BS 6580 1985 ASTM 01384 1987). Laboratory testing may involve a recirculating rig test in which the intention is to assess the performance of an inhibited coolant in the simulated flow conditions of an engine cooling system. Although test procedures have been developed (BS 5177 Part 2 Section 2.3 1985 ASTM 02570 1985), problems of reproducibility and repeatability exist, and it is difficult to quote numerical pass or fail criteria. 

The somewhat different bis(diboratetrasiloxane) derivatives 94 and 95 have been prepared from bimetallic salen B(OEt)2 2 derivatives and diphenylsi-lanediol [131, 138]. In this case the four boron atoms of two diboratetrasilox-ane rings 86 are chelated by salen-type ligands in order to produce cages of cylindrical geometry (Fig. 25). 

The effect of precursor-support interactions on the surface composition of supported bimetallic clusters has been studied. In contrast to Pt-Ru bimetallic clusters, silica-supported Ru-Rh and Ru-Ir bimetallic clusters showed no surface enrichment in either metal. Metal particle nucleation in the case of the Pt-Ru bimetallic clusters is suggested to occtir by a mechanism in which the relatively mobile Pt phase is deposited atop a Ru core during reduction. On the other hand, Ru and Rh, which exhibit rather similar precursor support interactions, have similar surface mobilities and do not, therefore, nucleate preferentially in a cherry model configuration. The existence of true bimetallic clusters having mixed metal surface sites is verified using the formation of methane as a catalytic probe. An ensemble requirement of four adjacent Ru surface sites is suggested. 

It has generally been assumed that the most important consideration in the surface enrichment of one metal in preference to another in a supported bimetallic cluster is based on differences in the enthalpies of sublimation of the metals which comprise the cluster. In most cases, the surface composition is enriched in the metal having the lower enthalpy of sublimation (1 ). 

As was the case for the silica-supported Ru-Rh bimetallic catalysts, there was no significant surface enrichment in either metal over the entire range of bimetallic catalyst compositions. 

Metal dispersions were observed to decrease as the concentration of Ru was Increased. This same trend was observed for the Ru-Rh catalysts and was in marked contrast to observations on silica-supported Ft-Ru catalysts W. In this case a large Increase in dispersion was obtained as a result of bimetallic clustering in the cherry model configuration. 

The surface-catalyst composition data for the silica-supported Ru-Rh cuid Ru-Ir catalyst are shown in Figure 1. A similcir plot for the series of silica-supported Pt-Ru bimetallic catalysts taken from ref. P) is included for comparison purposes. Enthalpies of sublimation for Pt, Ru, Rh and Ir are 552, 627, 543, and 648 KJ/mole. Differences in enthalpies of sublimation (a<75 KJ/mole) between Pt and Ru cind between Rh and Ru are virtually identical, with Pt euid Rh having the lower enthalpies of sublimation. For this reason surface enrichment in Pt for the case of the Pt-Ru/Si02 bimetallic clusters cannot be attributed solely to the lower heat of sublimation of Pt. Other possibilities must also be considered. 

A comment regarding the dispersion of the Ru-Rh/Si02 and the Ru-Ir/Si02 is in order. For the case of the supported Pt-Ru catalysts. Increases in dispersion as a result of clustering were very large ( ). This effect was particularly noticeable for bimetallic particles which conform to the cherry model. Evidently, the formation of an inner core enriched in one of the two metals, followed by an outer layer enriched in the other metal, inhibits further crystal growth. For the alumina-supported Pt-Ru bimetallic clusters, the effect, although present, is considerably smaller. 

M1M2 - All kinds of bimetallic nanoparticles including random alloy nanoparticles. In this case Mi and M2 should be arranged in an alphabetical order. 

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