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Benzidine treatment with

The conversion of a hydrazobenzene into a diaminodiphenyl upon treatment with acid is termed the benzidine rearrangement. The following mechanism for the formation of benzidine from hydrazobenzene appears reasonable ... [Pg.629]

Benzidine chemistry involves reduction. The nitro precursor is reduced either by zinc and alkali or electrolyticaUy to the hydrazo intermediate, which is then transformed to the benzidine by treatment with acid. [Pg.289]

It is known that not all reactions proceed in the same manner on all adsorbent layers because the material in the layer may promote or retard the reaction. Thus, Ganshirt [209] was able to show that caffeine and codeine phosphate could be detected on aluminium oxide by chlorination and treatment with benzidine, but that there was no reaction with the same reagent on silica gel. Again the detection of amino acids and peptides by ninhydrin is more sensitive on pure cellulose than it is on layers containing fluorescence indicators [210]. The NBP reagent (. v.) cannot be employed on Nano-Sil-Ci8-100-UV2S4 plates because the whole of the plate background becomes colored. [Pg.90]

Reduction of the nitroaromatic with NaBH4 in DMSO or Zn in NaOH/EtOH leads to the hydrazo derivative and treatment with aqueous HC1 gives benzidine rearrangement.115... [Pg.295]

In addition the role played by the sorbent on which the chromatography is carried out must not be neglected. For instance, it is only on aliuninium oxide layers and not on silica gel that it is possible to detect caffeine and codeine by exposure to chlorine gas and treatment with potassium iodide — benzidine [37]. The detection limits can also depend on the sorbent used. The detection limit is also a fimction of the h/ f value. The concentration of substance per chromatogram zone is greater when the migration distance is short than it is for components with high h/ f values. Hence, compounds with low h/ f values are more sensitively detected. [Pg.274]

One of the major uses of 1,2-diphenylhydrazine is as a starting material in the production of benzidine however, it is no longer produced in the United States. 1,2-Diphenylhydrazine rearranges to benzidine upon treatment with strong acid benzidine is used by the dye industry for the production of benzidine-based dyes including many of the Direct dyes (e.g.. Direct Red 28, Direct Black 4, Direct Blue 2) (Ferber 1978 Lurie 1964). Fabricolor, the last producer of benzidine based dyes, discontinued production in 1988 (Personal communication, Alvarez 1989). [Pg.48]

Benzidine-2,2 -disulfonic acid (61) affords the diamine 62 (Scheme 13) on treatment with aqueous sodium hydroxide. " ... [Pg.23]

VI. Treatment with Diphenylbenzidine Reagent. Place a few small crystsof unknown in an indenture of a white porcelain spot test, add 2 drops of diphenyl-benzidine reagent(a satd soln of C Hg.NH.CgH. C5H. NH.CgHj in glac AcOH), and then 1 drop of coned H SO. Observe the color after 1 min. A blue color indicates one of the following expls TNT, TNAns or HNDPhA yel color or no color -PA, AmmPic or DNPh (See also Chart B)... [Pg.194]

In addition to the iodometiic determination, direct precipitation as barium sulfate before and after treatment with bromine was suggested for both quantitative and qualitative test for sulfur dioxide in wine (see Monier-Williams, 1927). Precipitation of SO2 after oxidation with H2O1 as the benzidine sulfate was proposed by Rothen-fusser (1929) reduction of the molybdenum in phosphomolybdic acid by the sulfite ion present in an aqueous solution of the food was proposed by Sasaki (1928) as a colorimetric method formation of a blue color from a solution of 1% methylene blue and 5% iodine in potassium iodide was proposed by Svershkov (1939). Mathers (1949) proposed a turbidimetric method based on the distillation of wine into a dilute solution of lead acetate to form a colloidal suspension of lead sulfite whose spectral transmittance in the range of 400 to 700 mn could be used as a measure of sulfur dioxide. This is similar to turbidimetric methods based on turbidity produced by adding BaCfii to a... [Pg.115]

When solutions of lead or bismuth salts are treated with alkali hypo-bromite, lead peroxide and higher oxides of bismuth are formed. These products react with benzidine acetate to give benzidine blue (seepage 282). However, if bismuth salts are heated alone with alkali hydroxides, a yellow precipitate forms, [probably BiO(OH)] and, when once formed, is not converted into higher bismuth oxides on treatment with h3q)obromite. This resistance is applied in the detection of lead in bismuth salts. The following procedure is recommended in the examination of pharmaceutical bismuth preparations (e.g., bismuth sub-gallate, -tannate, -salicylate). [Pg.568]

According to the Toxics Release Inventory (TRI), in 1996, a total of 2 pounds (1 kg) of 3,3 -dichloro-benzidine was released to the environment from one processing facility (TRI96 1998). Table 5-1 lists amounts released from this facility. In addition, an estimated 250 pounds (118 kg) were released by manufacturing and processing facilities to publicly owned treatment works (POTWs), and an estimated 51,550 pounds (23,432 kg) were transferred offsite (TRI96 1998). The TRI data should be used with caution because only certain types of facilities are required to report. Therefore, this is not an exhaustive list. [Pg.112]

Benzidine Rearrangement. Treatment of hydrazobcnzcnc with strong acids. [Pg.1424]

Although several peroxidase enzymes obtained from plant, animal, and microbial sources have been investigated for their ability to catalyze the removal of aromatic compounds from wastewaters, the majority of studies have focused on using HRP. In particular, it has been shown HRP can transform phenol, chlorophenols, methoxyphenols, methylphenols, amino-phenols, resorcinols, and various binuclear phenols [7], HRP was also used for the treatment of contaminants including anilines, hydroxyquinoline, and arylamine carcinogens such as benzidines and naphthylamines [7,8]. In addition, it has been shown that HRP has the ability to induce the formation of mixed polymers resulting in the removal of some compounds that are either poorly acted upon or not directly acted upon by peroxidase [7], This phenomenon, termed coprecipitation or copolymerization, has important practical implications for wastewaters that usually contain many different pollutants. This principle was demonstrated when it was observed that polychlorinated biphenyls (PCBs) could be removed from solution through coprecipitation with phenols [20]. However, this particular application of HRP does not appear to have been pursued in any subsequent research. [Pg.455]

Derivatives of Nitrogen.— The preparation of amino-derivatives of perfluoromesityl-ene froth the parent compound and ammonia in ether has been claimed, and treatment of hexafluorobenzene with A -Iithium iV-ethylpentafluoroanilide gives the iV-ethy immoperfluoro-l,4-phenylenes (197 n = 1,2, and 3). 3,3 -Diamino-4,4, 6,6 -tetrafluoro-, 3,3 -diamino-2,2, 6,6 -tetrafluoro-, and 3,3 -diamino-2,2 -4,4, 6,6 -hexafluorobiphenyl have been synthesized by conventional nitration-reduction routes from the appropriate tetrafluoro- and hexafluoro-biphenyls, and treatment of the azo-compounds 098 X = Y = F, Z = H X = Z = F, Y = H X = OEt, Y =5 H, Z = F) with tin(ii) chloride and hydrochloric acid yields the conesponding benzidines (199). >... [Pg.410]


See other pages where Benzidine treatment with is mentioned: [Pg.194]    [Pg.263]    [Pg.302]    [Pg.193]    [Pg.296]    [Pg.137]    [Pg.669]    [Pg.53]    [Pg.119]    [Pg.195]    [Pg.210]    [Pg.28]    [Pg.518]    [Pg.227]    [Pg.17]    [Pg.137]    [Pg.290]    [Pg.75]    [Pg.467]    [Pg.11]    [Pg.537]    [Pg.301]    [Pg.151]    [Pg.328]    [Pg.301]    [Pg.856]    [Pg.548]    [Pg.553]    [Pg.49]    [Pg.460]   
See also in sourсe #XX -- [ Pg.90 ]

See also in sourсe #XX -- [ Pg.90 ]




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Benzidine treatment

Treatment with

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