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Aromatic heterocyclic nitrogen compounds

Aromatic heterocyclic nitrogen compounds likewise reacted with Grignard reagents in the conjugate manner. An example is the condensation of the phenyl reagent with benzalquinaldine. The product, a-benzohydryl-quinaldine, was obtained in a yield of 70% 45). [Pg.233]

Sims, V.A. 1962. Vinylation of aromatic heterocyclic nitrogen compounds. US Patent... [Pg.343]

Examples The various compounds that may be detected conveniently are, namely aromatic amines, phenols, ketones, and aldehydes and heterocyclic nitrogen compounds. [Pg.465]

The reactive species that initiate free-radical oxidation are present in trace amounts. Extensive studies (11) of the autoxidation mechanism have clearly established that the most reactive materials are thiols and disulfides, heterocyclic nitrogen compounds, diolefins, furans, and certain aromatic-olefin compounds. Because free-radical formation is accelerated by metal ions of copper, cobalt, and even iron (12), the presence of metals further complicates the control of oxidation. It is difficult to avoid some metals, particularly iron, in fuel systems. [Pg.414]

The nitrogenous bases are planar aromatic heterocyclic ring compounds which absorb ultraviolet light. They are of two different types, derived from pyrimidine and purine respectively. [Pg.109]

An example of processing contaminants arising at higher temperatures, which decades ago were considered risky in terms of health effects, are primary aromatic amines (aminoimidazoazaarenes), whose precursor is the amino acid creatinine, Strecker aldehydes and heterocyclic nitrogen compounds arising in the Maillard reaction. Some other amino acids and proteins may also be precursors of aminoimidazoazaarenes. [Pg.907]

As an illustration, crude benzene extracts of test materials (e.g., carbonaceous shale samples) can be preseparated by TLC into neutral polynuclear aromatic hydrocarbons (PAHs) and polar compounds (e.g., heterocyclic nitrogen compounds, aza-arenes, phenols) and other nonpolar hydrocarbons. This type of separation can be accomplished with a silica-gel plate in a onedimensional run with, for example, benzene-cyclohexane. Plates are air-dried and observed under UV light. Saturated hydrocarbons run with the solvent to... [Pg.244]

In addition, liver preparations from rats induced with Aroclor 1254 (Monsanto) showed the best general applicability for activation. However, individual differences in effectiveness do occure.g., in the results given in Table 5, variously induced preparations show obvious differences between fraction 9 (the basic fraction. Be) and fraction 14 (the neutral/methanol fraction). The Aroclor-induced preparation works best with the neutral fraction (PAHs ), whereas the phenobarbital-induced preparations work more efficiently with the basic fraction (heterocyclic nitrogen compounds, aromatic amines, aza-arenes ). [Pg.248]

The aromatic extracts are black materials, composed essentially of condensed polynuclear aromatics and of heterocyclic nitrogen and/or sulfur compounds. Because of this highly aromatic structure, the extracts have good solvent power. [Pg.291]

Indole is classified as a 7c-excessive aromatic compound. It is isoelectronic with naphthalene, with the heterocyclic nitrogen atom donating twm of the ten 7t-electrons. [Pg.2]

Methods of Introduction of Ruonne into Aromatic and Nitrogen-Contaimng Heterocyclic Compounds (Czech ) Hradil, P, Radi, S Chem Listy S4, 952-969 113 ... [Pg.21]

The reaction of A-acyliminium ions with nucleophilic carbon atoms (also called cationic x-amidoalkylation) is a highly useful method for the synthesis of both nitrogen heterocycles and open-chain nitrogen compounds. A variety of carbon nucleophiles can be used, such as aromatic compounds, alkcncs, alkyncs, carbcnoids, and carbanions derived from active methylene compounds and organometallics. [Pg.803]

In the scientific sector, the understanding of the generally higher reactivity of heteroaromatic diazo components relative to that of aromatic diazonium salts has increased. The number of heterocyclic nitrogen atoms in azolediazonium ions has a marked influence on the N-H acidity of these ions. The pvalues of a series of such ions in aqueous solution at 0 °C (Scheme 12-4) indicate that the electrophilicity of the diazonio group in these compounds increases with the number of nitrogen atoms in the ring. ... [Pg.309]

In certain cases, the SrnI mechanism has been found (p. 856). When the substrate is a heterocyclic aromatic nitrogen compound, still a different mechanism [the Sn(ANRORC) mechanism], involving opening and reclosing of the aromatic ring, has been shown to take place. [Pg.865]

D. S. Treybig and R. G. Martinez. Compositions prepared from hydrocarbyl substituted nitrogen-containing aromatic heterocyclic compounds, an aldehyde and/or ketone and an amine. Patent US 4871848, 1989. [Pg.470]

Kaiser et al. reviewed the microbial metabolism of different nitrogen compounds [320], There is agreement among the authors in suggesting an initial step in the transformation of quinoline (by whole cells) that consists of a hydroxylation at position 2 of the heterocyclic aromatic ring, leading to 2-hydroxyquinoline (see Fig. 21 [321]). [Pg.156]

Generalized valence bond interaction energies were computed for mono/poly-nitrogenous five- and six-membered heterocycles.203 Results that diverged from those obtained by other methods were obtained only for poly-nitrogenous systems such as pyridazine, benzotriazole, and tetrazole, which may confirm Bird s earlier finding123 204 that electron delocalization is not a stand-alone and direct measure of aromaticity for nitrogenous heterocyclic compounds. [Pg.25]

Actinomycetes can metabolize a wide variety of organic substrates, including organic compounds that are generally not metabolized, such as phenols and steroids. They are also important in the metabolism of heterocyclic compounds such as complex nitrogen compounds and pyrimidines [42,49]. The breakdown products of their metabolites are frequently aromatic, and these metabolites are important in the formation of humic substances and soil humus [42,49]. [Pg.324]

In any event, 02SbFg and 02AsFg act as very effective one-electron oxidants with regard to aromatic amines, nitrogen- and sulfur-containing heterocyclic compounds (Dinnocenzo and Banach 1986, 1988,1989) as well as to perfluorobenzene, benzotrifiuoride, and perfluoronaphthalene (Richardson et al. 1986). The oxidation proceeds in Freon (CHCIF2) at temperatures from -115 to -145°C, and the formation of the organic cation-radicals has been firmly established. [Pg.59]


See other pages where Aromatic heterocyclic nitrogen compounds is mentioned: [Pg.227]    [Pg.261]    [Pg.56]    [Pg.188]    [Pg.85]    [Pg.93]    [Pg.810]    [Pg.106]    [Pg.30]    [Pg.438]    [Pg.302]    [Pg.413]    [Pg.53]    [Pg.323]    [Pg.59]    [Pg.60]    [Pg.77]    [Pg.316]    [Pg.151]    [Pg.291]    [Pg.105]    [Pg.2]    [Pg.178]    [Pg.209]    [Pg.998]    [Pg.185]    [Pg.120]    [Pg.164]    [Pg.526]   


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Aromatic compound nitrogen

Aromatic compounds heterocycles

Aromatic nitrogen heterocycles

Aromaticity aromatic heterocycles

Aromaticity heterocyclic aromatic compounds

Aromaticity heterocyclics

Aromaticity nitrogen heterocycles

Heterocycles aromatic

Heterocycles aromatization

Heterocyclic aromatic nitrogen

Heterocyclic aromatics

Heterocyclic compounds Nitrogen heterocycles)

Heterocyclic compounds aromatic

Heterocyclic compounds aromatic heterocycles

Heterocyclic nitrogen

Heterocyclic nitrogen compounds

Nitrogen aromatic

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