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Anionics and cationics, analysis

From 1993 to the present, several publications have described anion and cation analysis for determination of pharmaceutical counterions (Pigure 16). and impurity profiling. For these applications, several buffers were used on different CE instruments. In most cases, detection was indirect or direct UV detection for analytes such as bromide that do absorb at 200 nm. Two papers describe use of a conductivity detector. [Pg.338]

Ion chromatography, suppressed and nonsuppressed, can be applied both to anion and cation analysis. The... [Pg.861]

Common ions can be determined at ppb levels, e.g. fluoride, chloride, nitrate, sulfate, sodium, ammonium, and potassium. This is especially important in environmental and industrial applications. Anion and cation analysis can be performed in many types of samples, e.g. groundwater samples, power plant waters, coastal and sea water samples, on air filters, solid waste samples, blood and food and digested rock samples. [Pg.92]

CE has been applied to anion and cation analysis during the last 15 years. This technique constitutes a viable alternative to ion chromatography. The United States Environmental Protection Agency (US EPA) has already approved a CE method for determining hexavalent chromium (in Region VII) and is currently... [Pg.376]

Ion chromatography (IC) has become a useful tool for the analytical chemist especially in the area of inorganic and organic anions and cations analysis. [Pg.909]

Middle shelf Syringe pumps for collecting sample solutions, ion chromatographs for anion and cation analysis and human interface. [Pg.1062]

Figure 10.77 Anion and cation analysis of aerosol particles (PM 2.5) In an outside air sample, (a) Anion analysis - separator column Metrosep A Supp 5 column dimensions ... Figure 10.77 Anion and cation analysis of aerosol particles (PM 2.5) In an outside air sample, (a) Anion analysis - separator column Metrosep A Supp 5 column dimensions ...
Figure 14-9 also shows a flowchart for analysis of wet and dry precipitation. The process involves weight determinations, followed by pH and conductivity measurements, and finally chemical analysis for anions and cations. The pH measurements are made with a well-calibrated pH meter, with extreme care taken to avoid contaminating the sample. The metal ions Ca, Mg, Na, and are determined by flame photometry, which involves absorption of radiation by metal ions in a hot flame. Ammorda and the anions Cl, S04 , NO3 , and P04 are measured by automated colorimetric techniques. [Pg.213]

The method developed by Epton [212,213] became the universally accepted method for the analysis of active matter of anionic and cationic surfactants. Epton s method, also known as the two-phase titration, is based on the titration of the anionic surfactant with cetylpyridinium bromide, a cationic surfactant, in the presence of methylene blue as indicator. A solution of the anionic surfactant is mixed with the indicator dissolved in dilute sulfuric acid, followed by further addition of chloroform, and then it is titrated with the cationic surfactant. Methylene blue forms a complex with the anionic salt that is soluble in chloroform, giving the layer a blue color. As the titration proceeds there is a slow transference of color to the water layer until the equivalence point. At the equivalence point colors of the chloroform and water layers are visually the same. On successive additions of titrant the chloroform layer lightens in shade and finally becomes colorless. [Pg.279]

Sevilla et The analysis of the hyperfine spectra of these radicals has revealed that the cation radical should have D2H symmetry, whereas the molecular symmetry of the anion radical should be lower than the apparently-full molecular symmetry, i. e., We now examine the molecular symmetries of the anion and cation radicals of heptafulvalene, together with those of its 5-membered analogue, fulvalene PCXI) using the symmetry rule. [Pg.19]

Karmarkar, S.V., Analysis of wastewater for anionic and cationic nutrients by ion chromatography in a single run with sequential flow injection analysis, /. Chromatogr. A, 850, 303, 1999. [Pg.301]

Applications Applications of IC extend beyond the measurement of anions and cations that initially contributed to the success of the technique. Polar organic and inorganic species can also be measured. Ion chromatography can profitably be used for the analysis of ionic degradation products. For example, IC permits determination of the elemental composition of additives in polymers from the products of pyrolysis or oxidative thermal degradation. The lower detection limit for additives in polymers are 0.1% by PyGC... [Pg.272]

Molecular Probe Analysis. In an effort to understand how a molecule is seen by either another molecule or by a surface, molecular probes can be moved around a chemical to map out its surface. These probes include anions and cations (point charges) and hard spheres or can be constructed as a combination of these. The empirical potential energy is computed at a variety of points around the test molecule and an energy surface is thus generated. This can be examined graphically and compared as changes are made to the molecule. [Pg.33]

In the present review, first we will describe how to fabricate artificial photosynthetic reaction center in nanometer scales by making use of phase separation in mixed monolayers of hydrocarbon (HC) and fluorocarbon (FC) amphiphiles [2,5,20-26] as shown in Fig. 2b [3]. The phase separated structures were studied by SPMs such as AFM, SSPM, and scanning near-field optical/atomic force microscopy (SNOAM) [27-33] as well as a conventional local surface analysis by SIMS [3,5], The model anionic and cationic HC amphiphilic... [Pg.194]

The simplest electrodimerization mechanism occurs when the species formed as the result of a first electron transfer reaction reacts with itself to form a dimer (Scheme 2.7). This mechanism is usually termed radical-radical dimerization (RRD) because the most extensive studies where it occurs have dealt with the dimerization of anion and cation radicals formed upon a first electron transfer step as opposed to the case of radical-substrate dimerizations, which will be discussed subsequently. It is a bimolecular version of the EC mechanism. The bimolecular character of the follow-up reaction leads to nonlinear algebra and thus complicates slightly the analysis and numerical computation of the system. The main features of the cyclic voltammetric responses remain qualitatively similar, however. Unlike the EC case, however, the dimensionless parameter,... [Pg.103]

These observations obtained from the application of different API techniques are determinative for qualitative and quantitative FIA results in the analysis of non-ionic and ionic surfactants. Therefore, both ionic surfactant types, anionic and cationic surfactant blends, besides a non-ionic AE surfactant blend were examined, recording their FIA-MS and MS-MS spectra from the blends before the spectra were generated from the mixture of all blends. The results, which show considerable variation, will be presented and discussed as follows. [Pg.163]

Ion chromatography (IC) is used increasingly in the food industry and a useful reference book was written by Weiss (1995). Henshall (1997) reviewed applications for food and beverage analysis. Recent reviews have been published for anions and cations (Buldini et al., 1997 Danielson et al., 2000) and carbohydrates (Cataldi et al., 2000). [Pg.121]

The major anions and cations in seawater have a significant influence on most analytical protocols used to determine trace metals at low concentrations, so production of reference materials in seawater is absolutely essential. The major ions interfere strongly with metal analysis using graphite furnace atomic absorption spectroscopy (GFAAS) and inductively coupled plasma mass spectroscopy (ICP-MS) and must be eliminated. Consequently, preconcentration techniques used to lower detection limits must also exclude these elements. Techniques based on solvent extraction of hydrophobic chelates and column preconcentration using Chelex 100 achieve these objectives and have been widely used with GFAAS. [Pg.50]

It is impossible to recommend how far you should pursue the possibilities discussed in this chapter. Essentially, all analytical process developers routinely screen both anion and cation exchangers with salt gradients over a range of fixed pH values. A smaller subset routinely evaluates pH gradients as well. Exploration into more exotic territory is usually undertaken only when conventional approaches fail. This is probably as it should be. As powerful and versatile as IEC is, it is only one of a suite of proven chromatography techniques for protein analysis. If investigating the basics in IEC does not yield the results you seek, it... [Pg.77]

Complementary to IC, the capillary electrophoresis (CE) technique is useful for both anions and cations. The method is significantly faster than IC for screening and is relatively easy to automate which is advantageous when large numbers of samples require analysis. Although CE is currendy similar in terms of sensitivity to IC it is a relatively new technique and significant improvements in both selectivity and sensitivity continue to be made [26]. [Pg.237]

The sample-preparation technique may depend on a number of variables, for example the molecular weight of sample and interferences, the sample volume and analyte concentration, buffer salt (anion and cation) content and metal concentration and type. Other than filtration for particulate removal, most of the approaches are based on the use of chromatographic media for cleaning up samples before analysis. [Pg.118]

Because of its exceptional selectivity, sensitivity and speed, IC is particularly suited to applications involving analysis of anions and cations in wastewater, natural waters, source effluents, workplace environments, ambient air and rain water. The analysis of organic as well as inorganic ions can be performed by 1C. Table I is a growing list of ions which have been successfully separated and detected. The principles of IC and selected applications to environmental pollutants are described in this paper. [Pg.233]


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Anionic cationic

Cation Analysis

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Cationics analysis

Cations and anions

Experiment 14 Qualitative Analysis of Cations and Anions

Qualitative Analysis of Cations and Anions

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