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Amino conjugates

K.R.J. Thomas, J.T. Lin, M. Velusamy, Y. Tao, and C. Chuen, Color tuning in benzo[l,2,5]thia-diazole-based small molecules by amino conjugation/deconjugation bright red light emitting diodes, Adv. Func. Mater., 14 83-90 (2004). [Pg.405]

QDs have been linked to phthalocyanines for Forster resonance energy transfer (FRET) [119-123] and for switch on sensing studies [124—126]. Figure 32 shows a linked nickel tetra amino conjugate (CdTe-QDs-(5-NiTAPc) conjugate for electrochemical studies. [Pg.259]

Typical auxochromes are hydroxyl, alkoxyl and aroxyl, amino, alkyl-amino and arylamino, all of which promote conjugation with lone pairs on oxygen or nitrogen atoms. [Pg.1146]

Alkylation of 2-methylaminothiazole (204) with ROH in 85% sulfuric acid gives 2-methylimino-3-alkyl-4-thiazoIine (54). 2-Amino-4-rnethyl-thiazoie alkylated with an excess of isopropanol, however, gives 95% of 2-isopropylamino-4-methyl-5-isopropylthiazole (56). The same result is obtained with cyclohexanol (242). These results and those reported in Sections III.l.C and IV.l.E offer interesting new synthetic possibilities in thiazole chemistry. The reactive species in these alkylations is the conjugate acid of 2-aminothiazole. and the diversity of the products obtained suggests that three nucleophilic centers may be operative in this species. [Pg.47]

A more challenging problem is to find the pH of a solution prepared from a polyprotic acid or one of its conjugate species. As an example, we will use the amino acid alanine whose structure and acid dissociation constants are shown in Figure 6.11. [Pg.163]

The most used EIA reagents conjugate a fluotophote such as fluorescein-isothiocyanate (EITC) or thodarnine—isothiocyanate to antibody (or antigen) free amino groups. Examples of other commonly used fluotophotes for EIA and their spectral characteristics ate presented in Table 3. EIA assays ate available in sandwich and competitive formats similar to EIAs. Unlike EIA kits which can be used directly with visual color deterrnination, EIAs require a fluorometer, and thus ate primarily laboratory-based. [Pg.26]

Rifamycin S also undergoes conjugate addition reactions to the quinone ring by a variety of nucleophiles including ammonia, primary and secondary amines, mercaptans, carbanions, and enamines giving the C-3 substituted derivatives (38) of rifamycin SV (117,120,121). Many of the derivatives show excellent antibacterial properties (109,118,122,123). The 3-cycHc amino derivatives of rifamycin SV also inhibit the polymerase of RNA tumor vimses (123,124). [Pg.498]

Oxidative Couplings of Heterocyclic Hydrazones. This method has opened the way to the preparation of azo derivatives of diazo compounds unobtainable by other means, ie, heterocycHc compounds ia which the diazotizable amino group is conjugated with the heterocycHc nitrogen atom as ia 2- and 4-amiQopyridine, compounds which do not normally yield stable diazonium salts (38). The reaction occurs as illustrated by equation 7 for the iateraction of (A/-methylcarbostyryl)hydrazone [28219-37-6] and dimethyl aniline the overall process is oxidation. [Pg.430]

Proteins may consist exclusively of a polymeric chain of amino acids these are the simple proteins. Quite often some other chemical component is covalendy bonded to the amino acid chain. Glycoproteins and Hpoproteins contain sugar and Hpid components, respectively. Porphyrins are frequently associated with proteins, eg, in hemoglobin. Proteins bound to other chemical components are called conjugated proteins. Most enzymes are conjugated proteins. [Pg.94]

A mechanism has been proposed to rationalize the results shown in Figure 23. The relative proportion of the A -pyrazolines obtained by the reduction of pyrazolium salts depends on steric and electronic effects. When all the substituents are alkyl groups, the hydride ion attacks the less hindered carbon atom for example when = Bu only C-5 is attacked. The smaller deuterohydride ion is less sensitive to steric effects and consequently the reaction is less selective (73BSF288). Phenyl substituents, both on the nitrogen atom and on the carbon atoms, direct the hydride attack selectively to one carbon atom and the isolated A -pyrazoline has the C—C double bond conjugated with the phenyl (328 R or R = Ph). Open-chain compounds are always formed during the reduction of pyrazolium salts, becoming predominant in the reduction of amino substituted pyrazoliums. [Pg.243]

The pAT values of the conjugate acids of several enamines derived from 2-methyl-propanal have been reported. Rationalize the observed variation with the structure of the amino constituent. [Pg.444]

A partial explanation of the above findings must lie in the known ease of addition of nucleophilic reagents to the conjugated double bond of pregn-16-en-20-ones. The amide ion that is a by-product of the reduction probably adds to a portion of the unreduced pregn-16-en-20-one giving the lithium enolate of amino ketone (74). This enolate may well be relatively stable at — 33° and would be protonated to the free 16-amino-20-one during work-up... [Pg.40]

Conjugation of the amino group of an aiylfflnine with a second aiomatic ring, then a thud, reduces its basicity even further. Diphenylamine is 6300 times less basic than aniline, whereas triphenylamine is scarcely a base at all, being estimated as 10 ° times less basic than aniline and 10 " times less basic than ammonia. [Pg.921]

The isoelectric points of the amino acids in Table 27.3 are midway between the pK values of the zwitterion and its conjugate acid. Take two exanples aspartic acid and lysine. Aspartic acid has an acidic side chain and a pi of 2.77. Lysine has a basic side chain and a pi of 9.74. [Pg.1118]

While the usual eonsequence of hydration of enamines is eleavage to a secondary amine and an aldehyde or ketone, numerous cases of stable carbinolamines are known (102), particularly in examples derived from cyclic enamines. The selective terminal hydration (505) of a cross-conjugated dienamine-vinylogous amide is an interesting example which gives an indication of the increased stabilization of the vinylogous amide as compared to simple enamines, which is also seen in the decreased nucleophilicity of the conjugated amino olefin-carbonyl system. [Pg.418]


See other pages where Amino conjugates is mentioned: [Pg.358]    [Pg.358]    [Pg.118]    [Pg.358]    [Pg.358]    [Pg.118]    [Pg.191]    [Pg.67]    [Pg.310]    [Pg.20]    [Pg.51]    [Pg.295]    [Pg.296]    [Pg.379]    [Pg.468]    [Pg.475]    [Pg.308]    [Pg.64]    [Pg.309]    [Pg.131]    [Pg.36]    [Pg.50]    [Pg.146]    [Pg.268]    [Pg.41]    [Pg.1245]    [Pg.271]    [Pg.276]    [Pg.126]    [Pg.200]    [Pg.407]    [Pg.226]    [Pg.292]    [Pg.334]   
See also in sourсe #XX -- [ Pg.280 ]




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Acylation reactions amino acid conjugation

Amino acid conjugates animals

Amino acid conjugates formation

Amino acid conjugates synthesis

Amino acid conjugation

Amino acid conjugation animals

Amino acid conjugation plants

Amino acid conjugation, xenobiotics

Amino acid glyceride conjugates

Amino acids conjugate addition

Amino acids conjugation with

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Amino group conjugated

Bile acids amino acid conjugates

Birds, amino acid conjugation

Conjugation of amino acids with other compounds

Conjugation reactions with amino acids

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Mammals amino acid conjugations

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Urea-amino acid conjugates

Xenobiotic metabolism amino acids, conjugation with

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