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4-Amino-2-chlor

Die Synthese von Phosphorsaure-(amino-chlor-methylenamid)-dichloriden [s. Bd. XII/2 (4. Aufl.), S. 513] aus phosphorylierten Harnstoffen und Phosphor(V)-chlorid liefert gute Ausbeuten, wenn die Umsetzung ausgehend vom Harnstoff bei 13—26 kPa in-nerhalb 30—80 Min. durchgefiihrt wird (rasche Entfernung von Chlorwasserstoff)26 J 270 ... [Pg.532]

Phosphor(V)-chlorid reagiert mit subst. Harnstoffen bei 70—80° zu 2,4-Bis-[di-chlorphosphorylimino]-l, 3-dialkyl(diaryl)- 1,3-diazetidinen275, die auch aus Phosphorsaure-(amino-chlor-methylenamid)-dichloriden und Triethylamin entste-... [Pg.533]

Bei der Einwirkung von Amino-chlor-sulfanen auf Phosphorigsaure-dialkylester (s. Bd. XII/2, S. 949) erhalt man Thiophosphorsaure-S-anhydrid-tetraalkylester in guten Ausbeuten, wenn man die Reaktionsprodukte nicht destilliert442 ... [Pg.566]

Durch Umsetzung von Thiophosphorigsaure-0,0-diestern mit Amino-chlor-sulfanen in Gegenwart von Pyridin325,326 z.B. ... [Pg.726]

Phosphor(III)-fluorid und -chlorid-difluorid addieren bei 20° Bis-[trifluormethyl]-chlor-amin zu (Bis- tri-fluormethyl]-amino)-chlor-trifluor- bzw. (Bis-[trifluormethyl]-amino)-dichlor-difluor-phosphoran ... [Pg.838]

Amino-chlor-methylen)-amino]-1 -chlor-3,4-dioxo- E15/2, 1499 (Cl - N-)... [Pg.26]

Malousaure (Amino-chlor-meth-ylen)- -dinitril E15/2, 1652... [Pg.138]

Malonskure (Amino-chlor-methy-len)- -methylester-nitril E15a/2, 1653 [ROOC-CH(CN)2 + HC1] Pyridin 6-Chlor-2-hydroxamino- ... [Pg.196]

Sulfoninm Bis-[(chlor-diethylamino-methylen)-amino]-chlor- (chlorid) Ell, 345 (R2N-CN + SOCl2)... [Pg.818]

Carbamidsanre N-[(Benzyl-methyl-amino)-chlor-methylen]- -2,2,2-trichlor-ethylester E4, 1182 (R2N-CN + Cl-COOR)... [Pg.993]

Boran (tert.-Butyl-trimethylsilyl-amino)-chlor-phenyl- XIII/3b,... [Pg.1190]

Step 2 On reaction with hydrogen chlor ide in an anhydrous solvent, the thiocar bonyl sulfur of the PTC der ivative attacks the car bonyl car bon of the N-terminal amino acid. The N-terminal anino acid is cleaved as a thiazolone derivative from the remainder of the peptide. [Pg.1134]

Reaction of 2 equiv of 2-aminopyridines with 2-hydropolyfluoroalk-2-anoates 351 in MeCN in the presence of NEts at 90 °C for 50 h afforded a mixture of the isomeric 2-oxo-2H- and 4-oxo-4//-pyrido[l,2-n]pyrimidines 110 and 111. Reaction of 3 equiv of 2-amino-pyridines and 2-hydropoly-fluoroalk-2-enoates 351 in MeCN in the presence K2CO3 could be accelerated by ultrasonic irradiation (125W). 2-Amino-6-methylpyridine yielded only 2-substituted 6-methyl-4//-pyrido[l,2-n]pyrimidin-4-ones 111 (R = 6-Me), whereas 2-amino-5-bromopyridine gave a mixture of 7-bromo-4//-pyrido[l,2-n]pyrimidin-4-one (111, R = 7-Br, R = CF2C1) and 2-(chlor-o,difluoromethyl)-6-bromoimidazo[l, 2-n]pyrimidine-3-carboxylate in 44 and 8% yields, respectively (97JCS(P 1)981). Reactions in the presence of K2CO3 in MeCN at 90°C for 60h afforded only imidazo[l,2-n]pyrimidine-3-carboxylates. [Pg.243]

Into a stirred, cooled (10°-15°C) solution of 26.2 grams (0.1 mol) of 2-amino-5-chlorobenzo-phenone (3-oxime in 150 ml of dioxane were introduced in small portions 12.4 grams (0.11 mol) of chloracetyl chloride and an equivalent amount of 3 N sodium hydroxide. The chlor acetyl chloride and sodium hydroxide were introduced alternately at such a rate so as to keep the temperature below 15°C and the mixture neutral or slightly alkaline. The reaction was completed after 30 minutes. The mixture was slightly acidified with hydrochloric acid, diluted with water and extracted with ether. The ether extract was dried and concentrated in vacuo. Upon the addition of ether to the oily residue, the product, 2-chloroacetamido-5-chlorobenzophenone (3-oxime, crystallized in colorless prisms melting at 161°-162°C. [Pg.466]

Amino-l-(3-chlor-5-hydroxy-4-methoxy-phenyl)-athanol-HydrochIorid 69% d.Th. F 195°... [Pg.118]

Chlor-3-amino-2-methyl-4,5-bis-[hydroxymethyl]-pyndin-Hydrochlorid 44% d.Th. F 270°... [Pg.158]

Azido-2-oxo-4-(4-chlor-phenyl) — 3-Amino-2-(4-chlor-phenyl)-azetidin 73% d.Th. [Pg.250]

Die Redukdon von 1 -Chlor-2-nitroso-Verbindungen zu 1 -Chlor-2-amino-Verbm-dungen gelingt mit Zinn(II)-chlorid in Salzsaure (Bd. X/l, S. 990). [Pg.489]

Chlor-anilin 4-Methoxy-unilin 4-Amino-benzvesaure-methy /ester 4-Amino-benzonitril... [Pg.501]

Die Bamberger-Umlagerung zu Amino-phenolen ist oft Ziel der elektrochemischen Reduktion, so z. B. bei der kathodischen Reduktion von 6-Chlor-2-nitro-toluol zu 2-Chlor-4-amino-3-methyl-phenol (an Pt bis 78% d.Th.)2 und von 2-Chlor-l-nitro-benzol zu 3-Chlor-4-amino-phenol (bis 63% d.Th.)3 (die leicht zu 1,4-Benzochinonen oxidiert werden konnen). [Pg.684]

Athylamino-l, 1-diphenyl- 350 2-Athylamino-l-phenyl- 350 Amino- 241, 462, 612 2-Amino-1-(4-chlor-phenyl)- 116... [Pg.885]

Nitro-phenyl)- -athylester 694 4-(2-Oxo-propyl)- -methylester 629 Pcntafluor- 599, 616 Pentafluor-amino- 616 Pentafluor-4-chlor- 616 Pentafluor-methoxy- 616 Pentamethoxy- -aziridid 234 -phenylester 192, 601 -piperidid 240... [Pg.893]

Amino-6-(4-methyl-benzoylamino)- 681 6-Amino- -nitril 579 2-Brom- -athylester 396 2-Chlor- -isopropylester 548 2-Chlor-2-methyl- -isopropylester 548 2,2-Dicblor- -isopropylester 548... [Pg.905]

AthyI-(4-amino-phcnyl)- 684 Athyl-benzyl- 500 Bis-[4-brom-phenyI]- 572 Bis-[4-chlor-phenyl]- 488 Bis-[4-hydroxy-phenyl]- 572 Bis-14-methoxy-phenyl]- 572 Bis-[4-methyl-phenyl]- 572 Bis-[4-nitro-phenyl]- 572 a-Brom- 534f. [Pg.922]

Amino-4-methyl-2-phenyl-2,5-dihydro- 480 5-Chlor-3-methoxy-2-phenyl- 595 5-Chlor-3-methyl-2-phenyl- 595... [Pg.930]


See other pages where 4-Amino-2-chlor is mentioned: [Pg.1195]    [Pg.599]    [Pg.1043]    [Pg.164]    [Pg.698]    [Pg.1193]    [Pg.911]    [Pg.906]    [Pg.55]    [Pg.906]    [Pg.179]    [Pg.470]    [Pg.116]    [Pg.129]    [Pg.377]    [Pg.489]    [Pg.686]    [Pg.886]    [Pg.891]    [Pg.925]    [Pg.937]    [Pg.937]    [Pg.937]    [Pg.937]   
See also in sourсe #XX -- [ Pg.370 ]




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2-Amino-4-chlor- -methylester

2-Amino-6-chlor- -Hydrochlorid

3- Amino-6-chlor-4,5-dimethyl

4 -chlor

4- Amino-3-benzoyl-2-chlor

4- Amino-6-chlor-3-phenyl

4-Amino-2-chlor-3-nitro

5- Amino-2-brom-3-chlor

5- Amino-2-chlor- -ethylester

5- Amino-4-chlor-6-fluor

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