Secondary aerosol

A few years ago the World Health Organization came to much less uncertainty when stating the toxicity of the most important air pollutants in more general terms and proposing the corresponding noxious concentrations and subsequent air quality standards (WHO, 1972). The way followed in this case has been much less mathematic and more length,y but the consensus arrived at by various sets of experts on SO2 effects can be considered unanimous, even if did not consider in detail sulfate deposition and sulfate aerosol secondary toxicity generated by the primary pollutant sulfur dioxide. 

The United States weaponized VEE before the offensive program was terminated. Other countries are also thought to have developed weaponized VEE. The virus could be produced in a wet or dry form and delivered by aerosol. Secondary spread from human to human is possible but rare. It would require mosquito transmission or exposure to blood or body fluids. 

The ablated vapors constitute an aerosol that can be examined using a secondary ionization source. Thus, passing the aerosol into a plasma torch provides an excellent means of ionization, and by such methods isotope patterns or ratios are readily measurable from otherwise intractable materials such as bone or ceramics. If the sample examined is dissolved as a solid solution in a matrix, the rapid expansion of the matrix, often an organic acid, covolatilizes the entrained sample. Proton transfer from the matrix occurs to give protonated molecular ions of the sample. Normally thermally unstable, polar biomolecules such as proteins give good yields of protonated ions. This is the basis of matrix-assisted laser desorption ionization (MALDI). 

Environmental Aspects. Airborne particulate matter (187) and aerosol (188) samples from around the world have been found to contain a variety of organic monocarboxyhc and dicarboxyhc acids, including adipic acid. Traces of the acid found ia southern California air were related both to automobile exhaust emission (189) and, iadirecfly, to cyclohexene as a secondary aerosol precursor (via ozonolysis) (190). Dibasic acids (eg, succinic acid) have been found even ia such unlikely sources as the Murchison meteorite (191). PubHc health standards for adipic acid contamination of reservoir waters were evaluated with respect to toxicity, odor, taste, transparency, foam, and other criteria (192). BiodegradabiUty of adipic acid solutions was also evaluated with respect to BOD/theoretical oxygen demand ratio, rate, lag time, and other factors (193). 

Air-poUutant effects on neural and sensory functions in humans vary widely. Odorous pollutants cause only minor annoyance yet, if persistent, they can lead to irritation, emotional upset, anorexia, and mental depression. Carbon monoxide can cause death secondary to the depression of the respiratory centers of the central nervous system. Short of death, repeated and prolonged exposure to carbon monoxide can alter sensory protection, temporal perception, and higher mental functions. Lipid-soluble aerosols can enter the body and be absorbed in the lipids of the central nervous system. Once there, their effects may persist long after the initial contact has been removed. Examples of agents of long-term chronic effects are organic phosphate pesticides and aerosols carrying the metals lead, mercury, and cadmium. 

The secondary source of fine particles in the atmosphere is gas-to-particle conversion processes, considered to be the more important source of particles contributing to atmospheric haze. In gas-to-particle conversion, gaseous molecules become transformed to liquid or solid particles. This phase transformation can occur by three processes absortion, nucleation, and condensation. Absorption is the process by which a gas goes into solution in a liquid phase. Absorption of a specific gas is dependent on the solubility of the gas in a particular liquid, e.g., SO2 in liquid H2O droplets. Nucleation and condensation are terms associated with aerosol dynamics. 

Finally, atmospheric chemical transformations are classified in terms of whether they occur as a gas (homogeneous), on a surface, or in a liquid droplet (heterogeneous). An example of the last is the oxidation of dissolved sulfur dioxide in a liquid droplet. Thus, chemical transformations can occur in the gas phase, forming secondary products such as NO2 and O3 in the liquid phase, such as SO2 oxidation in liquid droplets or water films and as gas-to-particle conversion, in which the oxidized product condenses to form an aerosol. 

Secondary Aerosols aerosol formed by the interaction of two or more gas molecules and/or primary aerosols. 

Primary alkyl chlorides are fairly stable to fluorine displacement. When fluorinated, 1-chloropropane is converted to 1-chloroheptafluoropropane and 1-chloto-2-methylbutane produces 39% l-chlorononafluoro-2-methylbutane and 19% perfluoro-2-methylbutane. Secondary and tertiary alkyl chlorides can undergo 1,2-chlorine shifts to afford perfluonnated primary alkyl chlorides 2-Chloro-2-methylpropane gives l-chlorononafluoro-2-methylpropane, and three products are obtained by the fluorination of 3-chloropentane [7] (equation 1). Aerosol fluorina-tion of dichloromethane produces dichlorodifluoromethane which is isolated in 98% purity [4 (equation 2). If the molecule contains only carbon and halogens, the picture is different. Molecular beam analysis has shown that the reaction of fluorine with carbon tetrachlonde, lodotrichloromethane, or bromotrichloromethane proceeds first by abstraction of halogen to form a trichloromethyl radical [5]... 

Most of the non-gaseous impurities in ice were once atmospheric aerosols. Atmospheric aerosols raining onto an ice sheet are of two types primary aerosols, which are incorporated directly into the atmosphere as aerosols (these include continental dust and sea spray), and secondary aerosols which form in the atmosphere from gases. In addition to aerosol-derived impurities, some soluble gases in the atmosphere (HNO3 HCl, H2O2, and NH3) adsorb directly onto ice, and so are measured in a core... 

Irregular respiration was observed in both male and female rats after a 4-hour nose-only inhalation exposure to aerosolized endosulfan (Hoechst 1983a). In both male and female rats, dyspnea was observed at the lowest concentrations tested (12.3 and 3.6 mg/m for males and females, respectively). Autopsies of the rats that died revealed dark-red, pinhead-sized foci on the lungs. It is unclear whether these effects represent direct effects of inhaled endosulfan on respiratory tissues or whether they are secondary to central nervous system effects on respiratory function. No treatment-related effects were... 

The transformation of arenes in the troposphere has been discussed in detail (Arey 1998). Their destruction can be mediated by reaction with hydroxyl radicals, and from naphthalene a wide range of compounds is produced, including 1- and 2-naphthols, 2-formylcinnamaldehyde, phthalic anhydride, and with less certainty 1,4-naphthoquinone and 2,3-epoxynaphthoquinone. Both 1- and 2-nitronaphthalene were formed through the intervention of NO2 (Bunce et al. 1997). Attention has also been directed to the composition of secondary organic aerosols from the photooxidation of monocyclic aromatic hydrocarbons in the presence of NO (Eorstner et al. 1997) the main products from a range of alkylated aromatics were 2,5-furandione and the 3-methyl and 3-ethyl congeners. 

Forstner HJL, RC Flagan, JH Seinfeld (1997) Secondary organic aerosol from the photoxodation of aromatic hydrocarbons molecular composition. Environ Sci Technol 31 1345-1358. 

BZ is usually disseminated as an aerosol with the primary route of entry into the body through the respiratory system the secondary route is through the digestive tract. BZ blocks the action of acetylcholine in both the peripheral and central nervous systems. As such, it lessens the degree and extent of the transmission of impulses from one nerve fiber to another through their connecting synaptic junctions. It stimulates the action of noradrenaline (norepinephrine) in the brain, much as do amphetamines and cocaine. Thus, it may induce vivid hallucinations as it sedates the victim. Toxic delirium is very common. 

The cosmogenic radionuclides, particularly Be-7, are associated with slightly smaller aerosols than sulfate, both in winter and summer. The reasons for this difference may be either (1) faster growth rates of secondary aerosols in plumes... 

McMurray, P. H. and J. C. Wilson, Droplet Phase (Heterogeneous) and Gas Phase (Homogeneous) Contributions to Secondary Ambient Aerosol Formation As Functions of Relative Humidity, Atmos. Environ.. 

Diffusion is the dominant mechanism of lung deposition for radon daughter aerosols. It is generally assumed that airflow is laminar in the smaller airways and that deposition in each airway generation can be calculated adequately (Chamberlain and Dyson, 1936 Ingham, 1975). However, there is no such consensus on the treatment of deposition in the upper bronchi. Some authors (Jacobi and Eisfeld, 1980 NCRP, 1984) have considered deposition to be enhanced by secondary flow, on the basis of experimental results (Martin and Jacobi, 1972). It has been shown that this assumption reduces the calculated dose from unattached radon daughters by a factor of two (James, 1985). 

Secondary Hazards Aerosols (cough, sneeze) Blood and body fluids Fecal (from birds) Fomites (from birds). 

Secondary Hazards Aerosols Body fluids Fecal matter Fomites. 

Secondary Hazards Aerosols (contaminated dust coughs, sneezes from individuals with pneumonia) Milk and urine (from ruminants) Fecal (from ruminants). 

Secondary Hazards Aerosols (possibly) Fecal matter Vectors (mechanical). 

Secondary Hazards Aerosols (cough, sneeze) Contact Body fluids Fomites. 

Secondary Hazards Aerosols (body fluids) Blood and body fluids Body tissue Vectors (mechanical—rodents). 

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