Active fluidized bed

CAFB [Chemically active fluidized-bed] A coal-gasification process intended for producing gas for power generation. Coal particles are injected into a shallow bed of lime particles that trap the sulfur dioxide. The bed particles are regenerated in a second fluidized bed, releasing the sulfur dioxide. Developed in the 1970s by the Esso Petroleum Company, UK, but not commercialized. 

In the present paper our previous analysis of fluidized bed filtration efficiencies has been extended by considering more realistic methods for estimating the single collector efficiencies as well as more recently reported experimental results. In general the predicted values of the fluidized bed filtration efficiencies compare favorably to the experimental values. For electrically active fluidized beds, direct measurements of the particle and collector charges would be necessary to substantiate the results given here. 

FIGURE 21.2 Contact-sorption dryer with active fluidized bed (a) batch and (b) continuous. 

There may be a signifleant (Aqrcuit tf op within the electrode itself, particularly if it is fabricated from a relatively poor conductor (e.g. titaniumX if it is very thin or porous (e.g. packed-bed electrodes) or if the electrode particles are in poor, intermittent contact, as in active fluidized bed electrodes. 

Dynamic Moving sheet or wire -reciprocating plate Active fluidized beds... 

The commercialization by Kureha Chemical Co. of Japan of a new, highly attrition-resistant, activated-carbon adsorbent as Beaded Activated Carbon (BAC) allowed development of a process employing fluidized-bed adsorption and moving-bed desorption for removal of volatile organic carbon compounds from air. The process has been marketed as GASTAK in Japan and as PURASIV HR (91) in the United States, and is now marketed as SOLD ACS by Daikin Industries, Ltd. 

Fluidized-bed reaction systems are not normally shut down for changing catalyst. Fresh catalyst is periodically added to manage catalyst activity and particle size distribution. The ALMA process includes faciUties for adding back both catalyst fines and fresh catalyst to the reactor. 

Thus operating cells need aluminum fluoride [7784-18-17, AIF., rather than cryoHte. Much aluminum fluoride is produced in a fluidized bed by the reaction of hydrofluoric acid gas and activated alumina made by partially calcining the alumina hydrate from the Bayer process... 

Fluidized-Bed Vinegar Reactors. Intimate contact of air A.cetohacter is achieved in fluidized-bed or tower-type systems. Air introduced through perforations in the bottom of each unit suspends the mixture of Hquid and microorganisms within the unit. Air bubbles penetrating the bottom plate keep Jicetobacter m. suspension and active for the ethanol oxidation in the Hquid phase. Addition of a carrier for the bacterial ceUs to the Hquid suspension is reported to improve the performance (58—60). 

Process water streams from vinyl chloride manufacture are typically steam-stripped to remove volatile organics, neutralized, and then treated in an activated sludge system to remove any nonvolatile organics. If fluidized-bed oxychlorination is used, the process wastewater may also contain suspended catalyst fines and dissolved metals. The former can easily be removed by sedimentation, and the latter by precipitation. Depending on the specific catalyst formulation and outfall limitations, tertiary treatment may be needed to reduce dissolved metals to acceptable levels. 

The Snamprogetti fluidized-bed process uses a chromium catalyst in equipment that is similar to a refinery catalytic cracker (1960s cat cracker technology). The dehydrogenation reaction takes place in one vessel with active catalyst deactivated catalyst flows to a second vessel, which is used for regeneration. This process has been commercialized in Russia for over 25 years in the production of butenes, isobutylene, and isopentenes. 

Activated alumina and phosphoric acid on a suitable support have become the choices for an iadustrial process. Ziac oxide with alumina has also been claimed to be a good catalyst. The actual mechanism of dehydration is not known. In iadustrial production, the ethylene yield is 94 to 99% of the theoretical value depending on the processiag scheme. Traces of aldehyde, acids, higher hydrocarbons, and carbon oxides, as well as water, have to be removed. Fixed-bed processes developed at the beginning of this century have been commercialized in many countries, and small-scale industries are still in operation in Brazil and India. New fluid-bed processes have been developed to reduce the plant investment and operating costs (102,103). Commercially available processes include the Lummus processes (fixed and fluidized-bed processes), Halcon/Scientific Design process, NIKK/JGC process, and the Petrobras process. In all these processes, typical ethylene yield is between 94 and 99%. 

As mentioned in Section 2.2 (Fixed-Bed Reactors) and in the Micro activity test example, even fluid-bed catalysts are tested in fixed-bed reactors when working on a small scale. The reason is that the experimental conditions in laboratory fluidized-bed reactors can not even approach that in production units. Even catalyst particle size must be much smaller to get proper fluidization. The reactors of ARCO (Wachtel, et al, 1972) and that of Kraemer and deLasa (1988) are such attempts. 

Fluidized-bed powdered activated carbon systems represent another important process. The use of activated carbon for the tertiary treatment of secondary sewage effluents has been used extensively. Powdered carbon is as effective as granular activated carbon for removing the organic impurities from the wastewater. 

Since the catalyst is so important to the cracking operation, its activity, selectivity, and other important properties should be measured. A variety of fixed or fluidized bed tests have been used, in which standard feedstocks are cracked over plant catalysts and the results compared with those for standard samples. Activity is expressed as conversion, yield of gasoline, or as relative activity. Selectivity is expressed in terms of carbon producing factor (CPF) and gas producing factor (GPF). These may be related to catalyst addition rates, surface area, and metals contamination from feedstocks. 

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