Acrylated soybean oil

Acrylated oil epoxy acrylates These epoxy acrylates are essentially epoxidized soybean oil acrylate. These resins have low viscosity, low cost, and good pigment wetting properties. They produce relatively flexible coatings. Acrylated oil epoxy acrylates are used mainly in pigmented coatings or to reduce cost. 

Scheme 2, The modification of acrylated epoxidized soybean oil (AESO) shown using cyclohexane dicarboxylic anhydrade or maleic anhydride. These AESOs were cured with styrene or other comonomers (20).

Tetrachloroethane (1,1,2,2-) Acetylene Tetrachloride Tetrachloroethane Chlorotrifluoroethylene Trifluorochloroethylene Trifluorovinylch bride Methacrylic Acid Methyl Acrylic Acid Dichloroacetic Acid Nitropropane (2-) Cam phene Hexene Noryl GFN3 Cumene Hydroperoxide Bromobutyric Acid (2-) Methyl Methacrylate Cedar Wood Oil Lavender Oil Terpineol Eucalyptus Oil Tung Oil Sunflower Oil Soybean Oil Linseed Oil Cottonseed Oil Corn Oil Coconut Oil Benzalkonium Chloride Zephiran Chloride Creosote Cod Liver Oil Ceresin Castor Oil Bone Oil Pine Oil Rapeseed Oil Spermaceti Sperm Oil Tall Oil Cocoa Butter Red Oil Turkey Red Oil Neats Foot Oil Johnsons V fex 111 Palm Oil Vidden D Dowtherm Dowtherm A Lanolin Sassafras Oil Sandalwood Oil Santal Oil Rose Oil Nutmeg Butter Nutmeg Oil Cedar Leaf Oil Terpinyl Acetate Coal Tar Tar... 

Epoxy resin adhesives for aluminum, glass, and steel have been prepared by converting octaallyl or octacrotyl-sucrose to the corresponding epoxides which were cured with diethylenetriamine.157 Several plastics, resins, and adhesives have been based on soybean oil.158 Vinyl esters of the fatty acids can be used as monomers. The oil can be epoxidized, then hydrolyzed to glycols, which can be converted to acrylates or maleates for polymerization. Natural fibers, such as hemp, can be used with such materials to form inexpensive composites. 

Fig. 17.6. Epoxidation of soybean oil (a), followed by hydrolysis to form polyols (b). Modification of polyols to form polyesters (c), soybean oil based acrylates (d), and epichlorohydrin modified soybean oil (e).

Lu, Y., Xia, Y, Larock, R. C. (2011). Surfactant-free core-shell hybrid latexes from soybean oil-based waterborne polyurethanes and poly(styrene-butyl acrylate). Proa. Ora. Coat. 71, 336-342. 

Chem. Descrip. Epoxidized soybean oil acrylate, with 3740 ppm MEHQ Uses Otters flexibility, pigment wetting, high adhesion tor paper coatings, wood coatings, metal coatings, concrete polymers, inks Properties Gardner 4 It. yel. liq. sp.gr. 1.040 vise. 23,000 cps 99% reactive esters... 

Uses Flexibilizer, pigment wetting agent in lithographic inks, pigmented coatings, varnishes, esp. on paper and board substrates Trade Names Actilane 300 Actilane 300HV See also Epoxidized soybean oil acrylate... 

Trade Names Containing PDI Type 47 Epoxidized soybean oil acrylate... 

Isooctyl alcohol Isophthalic acid, Isopropanolamine, Isostearic acid, Itaconic acid, Jayflex DHP Jayflex DINA Jayflex DIOP Jonrez IC-2805 Kenplast G Lanolin alcohol Maleic acid Maleic anhydride, Mekon White 2-Mercaptoethanol 3-Methoxybutanol Methoxyethanol Methoxyethyl acrylate. Methyl acetyl ricinoleate Methyl caprate. Methyl laurate. Methyl linoleate Methyl oleate Methylpropanediol Neopentyl glycol Nonanolc acid, Nopalcol 4-0 Nomlacresin, Octoxynol 2-Octyi-l-decanol Octyl palmitate. Oleic acid. Oxidized soybean oil Paroll 142 ... 

In the same fashion, methacrylate groups have also been incorporated in soybean oils to generate similar polymer architectures. Acrylated epoxidized soybean oil and maleinated acrylated epoxidized soybean oil were reacted with methacrylated lauric acid as a method of reducing styrene input [41]. This increased both the visocosity and the glass transition temperature when compared with the styrene analogue as well as having the benefits of improving the environmental properties of the polymer even further. Acrylated, epoxidized soybean oil was copolymerized with methyl methacrylate in a polymerization initiated by benzoyl peroxide to produce a clear bioplastic [42]. 

Also similar to styrene and methyacrylates is the use of divinylbenzene as a comonomer. Acrylated, epoxidized soybean oil was polymerized with divinylbenzene or modified with phthalic anhydride before polymerization to give materials with increased glass transition temperatures [43]. Modification of the soybean oil with cinnamate esters and subsequent... 

Sen, S. and CayU, G. (2010) Synthesis of bio-based polymeric nanocomposites from acrylated epoxidized soybean oil and montmorillonite clay in the presence of a bio-based intercalant. Polymer International, 59(8), 1122-1129. 

S-Flakes. See Hydrogenated soybean oil SFR 100. See Silicone SFS. See Sodium formaldehyde sulfoxylate SG-741, SG-841. See Silicone SGP 502S Absorbent Polymer. See Corn starch/acrylamide/sodium acrylate copolymer Shaddock extract. See Grapefruit (Citrus grandis) extract... 

Stabilizer C. See N,N -Diphenylthiourea Stabilizer l-FF. See 2-Phenyl indole Stabioi CA 580 i. See Calcium stearate Stabioi CA 1362. See Calcium behenate Stabioi CA 1733. See Calcium stearate Stabioi ZN 592 i. See Zinc stearate Stabioi ZN 1500. See Zinc 2-ethylhexanoate Stabiand . See Hydrogenated soybean oil Stabiec iDC 52, Stabiec iDC 85. See Lecithin Stabrom 909. See Bromine Stabyien 30. See Acrylates/vinyl isodecanoate crosspolymer... 

Epoxidized soybean oil, butyl esten Epoxidized soybean oil, methyl ester Isobomyl acrylate Isopropyl titanium triisostearate Neopentyl glycol diacrylate... 

Dimethiconol stearate Dimethyl adipate Dioctyl adipate Dioctyl sebacate Distearyidimonium chloride Ditridecyl sodium sulfosuccinate Epoxidized soybean oil Ethylene/acrylic acid copolymer Ethyl hydroxymethyl oleyl oxazoline Glycereth-7... 

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