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Acrolein 2-ethyl

Flammable gases and vapors include acetylene, hydrogen, butadiene, ethylene oxide, propylene oxide, acrolein, ethyl ether, ethylene, acetone, ammonia, benzene, butane, cyclopropane, ethanol, gasoline, hexane, methanol, methane, natural gas, naphtha, and propane. [Pg.431]

Ethylene unreactive Propenal (Acrolein) Ethyl propenoate (Ethyl acrylate) ... [Pg.558]

Equilibrium in the System—Acrolein-Ethyl Alcohol-Allyl Alcohol-Acetaldehyde... [Pg.757]

This evidence of reversibility in the acrolein-ethyl alcohol reaction at a temperature (396°, 1 atm.) where both allyl alcohol and ethyl alcohol are thermodynamically unstable with respect to the aldehydes and hydrogen indicated that the hydrogen transfer reaction was catalyzed by surfaces which were inactive for hydrogenation-dehydrogenation reactions. In order to explore the activity of magnesia and zinc oxide for hydrogenation, a number of these catalysts were tested for the direct hydrogenation of acrolein. [Pg.757]

Mixed vapors of acrolein and ethyl alcohol were passed over the catalyst in a heated stainless steel tube at atmospheric pressure. Products were condensed and fractionated in a 20-plate bubble tray column. Fractions taken were acetaldehyde, 20-36°, and acrolein-ethyl alcohol, 36-78.4°. At this point water was added to the distillation kettle and an ethyl alcohol-aUyl alcohol-water fraction, 78-95°, was taken overhead. Fractions were analyzed for aldehydes by the hydroxylamine hydrochloride method, for im-saturation by reaction with bromine in aqueous potassium bromide, for alcohol by the nitrite ester method, and for water with Fischer reagent. Propyl alcohol in the water-free allyl alcohol recovered from the azeotrope was calculated by difference from the total alcohol determined by reaction with acetyl chloride and the unsaturated alcohol determined by reaction with aqueous bromine solution. Fresh catalyst was used for each experiment. [Pg.763]

Cycloaddition (Diels-Alder) reactions have been reported for [6]radia-lene (5) and its hexaalkyl derivatives 113 and 115, but not for the permethylated radialene 72, which was inert even to the reactive dienophiles TCNE and Af-phenyltriazolinedione [67]. The sterically least hindered radialene 5 reacted with acetylenic and olefinic dienophiles in a 1 3 ratio to give triphenylene derivatives such as 139 in low yield (Scheme 4.30) [5, 95]. On the other hand, radi-alenes 113 and 115 gave linear,/)-quinodimethane-type 1 2-adducts, when they were exposed to an excess of various common dienophiles inter alia maleic anhydride, tetracyanoethylene, />-benzoquinone, acrolein, ethyl acrylate, acetylenedi-carboxylic acid) [89, 96, 97]. The 1 1 adduct 140, which was isolated so far only from the reaction with an equimolar amount of TCNE (92% yield) [97], presumably prefers the second cycloaddition step in the linear (para) position (141) over that in the angular (meta) position (142) for steric reasons. [Pg.103]

If the original ester is a fat or oil and produces an odour of acrolein when heated, it may be a glyceride. Esters of ethylene glycol and of glycol with simple fatty acids are viscous and of high b.p. They are hydrolysed (method I) and the ethyl alcohol distilled ofl. The residue is diluted (a soap may be formed) and acidified with hydrochloric acid (Congo red paper). The acid is filtered or... [Pg.391]

To a mixture of 250 ml of ether and 3 moles of freshly distilled acrolein ivere added about 3 moles of bromine at a rate such that the temperature could easily be maintained between -30 and -90°C (bath of dry-ice-acetone or liquid Nj). After persisting of the browncolour, the temperature was allowed to rise to 0°C. Freshly distilled ethyl orthoformate (3.25 moles) and 96% ethanol (30 ml) were added. [Pg.149]

Historically, the development of the acrylates proceeded slowly they first received serious attention from Otto Rohm. AcryUc acid (propenoic acid) was first prepared by the air oxidation of acrolein in 1843 (1,2). Methyl and ethyl acrylate were prepared in 1873, but were not observed to polymerize at that time (3). In 1880 poly(methyl acrylate) was reported by G. W. A. Kahlbaum, who noted that on dry distillation up to 320°C the polymer did not depolymerize (4). Rohm observed the remarkable properties of acryUc polymers while preparing for his doctoral dissertation in 1901 however, a quarter of a century elapsed before he was able to translate his observations into commercial reaUty. He obtained a U.S. patent on the sulfur vulcanization of acrylates in 1912 (5). Based on the continuing work in Rohm s laboratory, the first limited production of acrylates began in 1927 by the Rohm and Haas Company in Darmstadt, Germany (6). Use of this class of compounds has grown from that time to a total U.S. consumption in 1989 of approximately 400,000 metric tons. Total worldwide consumption is probably twice that. [Pg.162]

The performance of many metal-ion catalysts can be enhanced by doping with cesium compounds. This is a result both of the low ionization potential of cesium and its abiUty to stabilize high oxidation states of transition-metal oxo anions (50). Catalyst doping is one of the principal commercial uses of cesium. Cesium is a more powerflil oxidant than potassium, which it can replace. The amount of replacement is often a matter of economic benefit. Cesium-doped catalysts are used for the production of styrene monomer from ethyl benzene at metal oxide contacts or from toluene and methanol as Cs-exchanged zeofltes ethylene oxide ammonoxidation, acrolein (methacrolein) acryflc acid (methacrylic acid) methyl methacrylate monomer methanol phthahc anhydride anthraquinone various olefins chlorinations in low pressure ammonia synthesis and in the conversion of SO2 to SO in sulfuric acid production. [Pg.378]

Acrolein Acetal (ir, i) By treating acrolein with ethyl orthoformate in the presence of ammonium nitrate. Fischer and Baer, Helv. Chim. Acta i8, 514 (1935). [Pg.91]

Simple alkyl radicals such as methyl are considered to be nonnucleophilic. Methyl radicals are somewhat more reactive toward alkenes bearing electron-withdrawing substituents than towards those with electron-releasing substituents. However, much of this effect can be attributed to the stabilizing effect that these substiments have on the product radical. There is a strong correlation of reaction rate with the overall exothermicity of the reaction. Hydroxymethyl and 2-hydroxy-2-propyl radicals show nucleophilic character. The hydroxymethyl radical shows a slightly enhanced reactivity toward acrylonitrile and acrolein, but a sharply decreased reactivity toward ethyl vinyl ether. Table 12.9 gives some of the reactivity data. [Pg.701]

Ethyl Grignard added chorrosoloctivcly to acrolein (17) in good yield, but iso-propyl Grignard failed to give the reaction. The alternative straieg (6) was successful In this case. [Pg.197]

ETHYLENE GLYCOL ETHYL MERCAPTAN DIMETHYL SULPHIDE ETHYL AMINE DIMETHYL AMIDE MONOETHANOLAMINE ETHYLENEDIAMINE ACRYLONITRILE PROPADIENE METHYL ACETYLENE ACROLEIN ACRYLIC ACID VINYL FORMATE ALLYL CHLORIDE 1 2 3-TRICHLOROPROPANE PROPIONITRILE CYCLOPROPANE PROPYLENE 1 2-DICHLOROPROPANE ACETONE ALLYL ALCOHOL PROPIONALDEHYDE PROPYLENE OXIDE VINYL METHYL ETHER PROPIONIC ACID ETHYL FORMATE METHYL ACETATE PROPYL CHLORIDE ISOPROPYL CHLORIDE PROPANE... [Pg.942]


See other pages where Acrolein 2-ethyl is mentioned: [Pg.494]    [Pg.12]    [Pg.22]    [Pg.494]    [Pg.287]    [Pg.1767]    [Pg.494]    [Pg.481]    [Pg.857]    [Pg.756]    [Pg.757]    [Pg.511]    [Pg.191]    [Pg.202]    [Pg.419]    [Pg.318]    [Pg.208]    [Pg.217]    [Pg.530]    [Pg.129]    [Pg.51]    [Pg.63]    [Pg.492]    [Pg.89]    [Pg.118]    [Pg.678]    [Pg.125]    [Pg.906]   
See also in sourсe #XX -- [ Pg.988 ]




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Acrolein

Acroleine

Diels-Alder reaction, of acrolein with vinyl ether, and ethyl isopropenyl

Ethyl propyl acrolein

Transetherification of acrolein and ethyl

Transetherification of acrolein and ethyl orthoformate

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