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Combination, acid-base

Apart from the isomeric relation between 7 and 1, the appearence of the ternary associate now showing coordinatoclathrate properties gives a reasonable motive for putting up these compounds for discussion here. The dimer formation of carboxylic acids known from the related inclusions of 1 and 26 does not occur here. Instead, one observes a well-balanced system of H-bonds between groups of different acid/base properties. It is left to future studies to find other acid/base combinations which give a comparable situation. Actually, such H-bonded systems remind one of the multiple non-bonded interactions at the active centers of enzymes. [Pg.99]

TABLE 5.1 Commonly Used Examples of Conjugate Acid-Base Combinations and Corresponding Useful pH Ranges... [Pg.116]

Biguanides usually behave as mono- and di-acid bases, combining with H+ ions to form the conjugate acid, but may also act as acids. The acid dissociation constants of many biguanides have been measured, and are collected in Tables 1 and 2. [Pg.28]

Asymmetric cyanohydrin synthesis from aldehydes using trimethylsilyl cyanide (TMSCN) has been carried out using a chiral Al(salen) complex-triphenylphosphine Lewis acid-base combination.263... [Pg.29]

The log scale is not quite general in the sense that a nnmber of acid-base combinations are excluded from equation 12. However phenols, as well as alcohols and strong NH donors, can be combined with all types of bases. [Pg.536]

Many attempts have been made to ascertain whether the acid- and base-catalyzed reactions are concerted or stepwise. In the concerted process, both the acid catalyst and the base catalyst take part in the transition state, with addition of a proton at one point in the molecule and with elimination of a proton at another point. Theoretically, the rate constant for a concerted reaction involving several acid-base combinations yields an equation of the form ... [Pg.16]

A number of methods to effect Nef-type reactions employ reducing agents in place of the acid/base combination. The most commonly used variant of this type was developed by McMurry in 1973 and involves treatment of nitroalkanes with aqueous TiCb. In a representative example, these conditions were used for the conversion of 20 to 21 in 85% yield. These reactions likely proceed through generation of a Ti-0 bond to afford 22, followed by N-0 bond cleavage to yield 23. Tautomerization of the nitroso species (23) would provide oxime 24, which is then hydrolyzed to afford 21. Although these conditions are still somewhat acidic, several functional groups are tolerated... [Pg.646]

The unique reactivity of the above system with H2 appears to arise from the unquenched Lewis basicity and acidity of the respective donor P and the acceptor B centers. This inference prompted questions about the nature and reactivity of other phosphine-borane systems and, more broadly, of Lewis acid/base combinations. Is it necessary to have a link between the donor and acceptor sites Could similar H2 activation arise from combinations of donors and acceptors in which steric encumbrance frustrates Lewis acid-base adduct formation If indeed such frustrated Lewis pairs could be uncovered, could one exploit them for the activation of small molecules and applications in catalysis ... [Pg.264]

Design of highly functional small-molecule catalysts and related reactions based on acid-base combination chemistry (particularly, synthesis of oxazolines and thiazolines and L-histidine-derived sulfonamide as a minimal artificial acylase for the kinetic resolution of racemic alcohols) 07SL686. [Pg.15]

Based on acid-base combination chemistry, Ishihara developed a catalytic enantioselective cyanosilylation of ketones by using chiral (J )-Ph2-BINOL-derived lithium phosphate, which was prepared in situ from phosphoric acid... [Pg.20]

Based on acid-base combination chemistry, Shibasaki developed chiral heterobimetallic aluminium(m) lithium(i) bis(binaphtholate) (18), which can catalyse the enantioselective Michael reaction of cyclic enones with... [Pg.21]

In this chapter, we reviewed recent developments regarding lithium, sodium, and potassium salt based-catalysis, with a particular focus on asymmetric catalysts. While these alkali-metal salts have traditionally been used as simple bases, recent advances based on chiral multifunctional acid-base combination chemistry, using chiral crown-alkali-metal complexes, chiral lanthanoid/alkali-metal complexes, chiral alkali-metal alkoxides, and chiral alkali-metal phosphates, have also been outstanding. These synergic acid-base catalyst systems should enable more efficient and/or new transformations that have not been possible thus far using conventional catalysts that only rely on Lewis acidity or Bronsted/Lewis basicity. [Pg.44]

Pearson envisages a chemical bond as being made up of an acid-base combination. One can always imaginarily dissect a compound into Lewis acid and Lewis base moieties for analysis. The properties of the intact molecule, including the ease of its formation, can be inferred by considering its acid and base components. The classes of acids and bases are named hard and soft the A or (a) metal ions belong to hard acids and the B or (b) metal ions (8,9) are soft acids. [Pg.2]

Acid-base combination chemistry is a promising and upcoming approach in modem asymmetric catalysis. This often involves salts, which due to a combination of a basic and an acidic site can activate and coordinate both the substrate and an acidic pronucleophile. A possible advantage is that they are generally more flexible in design than single-molecule catalysts. [Pg.366]

Scheme 5.42 Application of chiral Bi0nsted-acid-base combined salt catedyst in new Mannich reactions... Scheme 5.42 Application of chiral Bi0nsted-acid-base combined salt catedyst in new Mannich reactions...
Fig. 5.6 Formation of chiral Br0nsted-acid-base combined salt catalyst... Fig. 5.6 Formation of chiral Br0nsted-acid-base combined salt catalyst...
After repeated cycles, the salt concentration begins to increase. Normally, this does not pose a problem, as the large volume of fluid within the system allows for substantial dilution. If the use of salts in the drilling fluid is prohibited by regulation (i.e. KCl in some locations), an acid-base combination can be used, which forms an insoluble salt, removable by the mud cleaning equipment. [Pg.320]

In related fiel, some protic acid—base combinations have recently been utilized to make polymeric materials that are good proton conductors, " and nonstoichiometric acid-base combinations have been nsed to obtain good ionic conductivity. So far, a significant proportion of the... [Pg.27]

There are a vast number of potential acid—base combinations that can be nsed to prepare new PILs. As a class of solvents, PILs have a range of properties, though they share in cormnon that they ate nsnally highly polar solvents, capable of hydrogen bonding (donation and acceptance). The physicochemical properties and correlations reported herein have the potential to assist in the design of future PILs. [Pg.30]

Up to now, there are few results related to fuel cell performance by using PBI/IL composites, in spite of the potential of these materials in such devices. Van de Ven et al. [59] showed some fuel cell results in which they observed an enhancement in the performance with the increase in the temperature in the range of 30-150 °C compared to conventional Nafion membrane (Fig. 13.9). However, the open circuit voltage (OCV) was low compared to the standard Nafion -mem-brane. Furthermore, the cell performance was somehow insufficient for real fuel cell application, evidencing that further research are necessary in order to enhance the properties of this composite membrane materials. Greaves and Dmmmond [60] recently showed that the nature of EL allows the use of protic acid-base combinations, including nonstoichiometric ones. [Pg.289]

The stoichiometry of polyelectrolyte complexes is an important property, determined by viscosity measurements in solution (dilute enough such that precipitation does not occur) or by conductance measurements. For non-neutrahzed acid-base complexes (e.g., PSSA/PVBTAOH), a minimum in conductance occurs at the stoichiometric equivalence point as the charged groups are neutralized. For neutralized acid-base combinations (e.g., NaPSSA/PVBTACl), a maximum in conductance occurs as the interacting acid-base pairs release salt (e.g., NaCl), which is ionized in water yielding high conductance. This was well demonstrated by Michaels et al. [924] for the examples noted. Poly(4-vinyl pyridine-HCl)... [Pg.192]

SCHEME 11.31 Biysnsted acid-base combined salt catalyst for the asymmetric Mannich reaction. [Pg.407]

SCHEME 11.32 Effect of the achiral amine counterpart in the Biytnsted acid-base combined salt-catalyzed asymmetric Mannich reaction. [Pg.407]

Scheme 7.45 Catalysis of chiral Bransted acid-base combined salt. Scheme 7.45 Catalysis of chiral Bransted acid-base combined salt.

See other pages where Combination, acid-base is mentioned: [Pg.283]    [Pg.113]    [Pg.330]    [Pg.385]    [Pg.559]    [Pg.709]    [Pg.196]    [Pg.86]    [Pg.149]    [Pg.28]    [Pg.581]    [Pg.333]    [Pg.344]    [Pg.28]   
See also in sourсe #XX -- [ Pg.29 ]




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