A-glycol

Oxidation of a glycol can lead to a variety of products. Periodic acid quantitatively cleaves 1,2-glycols to aldehydes and is used as an analysis method for glycols (12,13). The oxidation of propylene glycol over Pd/C modified with Pb, Bi, or Te forms a mixture of lactic acid, hydroxyacetone, and pymvic acid (14). Air oxidation of propylene glycol using an electrolytic crystalline silver catalyst yields pymvic aldehyde. 

Uses. About 35% of the isophthahc acid is used to prepare unsaturated polyester resins. These are condensation products of isophthahc acid, an unsaturated dibasic acid, most likely maleic anhydride, and a glycol such as propylene glycol. The polymer is dissolved in an inhibited vinyl monomer, usually styrene with a quinone inhibitor. When this viscous hquid is treated with a catalyst, heat or free-radical initiation causes cross-linking and sohdification. A range of properties is possible depending on the reactants used and their ratios (97). 

Because the heat distortion temperature of cured epoxy resins (qv) increases with the functionality of the curing agents, pyromellitic dianhydride is used to cross-link epoxy resins for elevated temperature service. The dianhydride may be added as a dispersion of micropulverized powder in liquid epoxy resin or as a glycol adduct (158). Such epoxies may be used as an insulating layer in printed circuit boards to improve heat resistance (159). Other uses include inhibition of corrosion (160,161), hot melt traffic paints (162), azo pigments (163), adhesives (164), and photoresist compounds (165). 

In practice, most of the appHcations have come where a small part (<5%) of the feed is removed. Examples include H2S /CO2 removal and gas drying with a glycol (see Distillation, AZEOTHOPic and exthactive). 

Perbenzoic acid gave a doubly unsaturated triol monobenzoate. Only two hydroxyl groups could be acetylated, and one was tertiary. The saturated triol reacted with lead tetracetate to give an a glycol. When reacted with chromic acid, it gave a hydroxy lactone. From these observations, Windaus and Gmndmann (11) described the correct stmcture for ergosterol (1). 

Ballard, D., How to Operate a Glycol Plant, Hydrocarbon Processing, lune 1966. 

The most obvious indication of a glycol dehydration malfunction is a high water content or dew point of the outgoing sales gas stream. In most cases, this is caused by an inadequate glycol circulation rate or by an insufficient reconcentration of the glycol. These two factors can be caused by a variety of contributing problems listed below. 

If a glycol pump has been operating in a clean system, no major service will probably be needed for several years. Only a yearly replacement of packing is usually required. Normally the pump will not stop pumping unless some internal part has been bent, worn, or broken. 

An alternative technique is that of condensation polymerisation. A simple example of this is seen in the manufacture of linear polyesters. Here a dibasic acid is reacted with a dihydroxy compound, e.g. a glycol (Figure 2.5). 

Condensation of polyhydroxy compounds with polybasic acids, e.g. a glycol with a dicarboxylic acid ... 

The starting point in the prepration of these rubbers is a polyester prepared by reacting a glycol such as ethylene or propylene glycol with adipic acid. This is then reacted with an excess of a bulky di-isocyanate such as 1,5-naphthylene di-isoyanate (Figure 27.3). 

Similar reactions occur when an amine is used instead of a glycol as chain extender ... 

Whenever a hydrocarbon backbone has two hydroxyl radicals attached to it, it becomes a special type of alcohol known as a glycol. The simplest of the glycols, and the most important, is ethylene glycol, whose molecular formula C2H4(OH)2. The molecular formula can also be written CHjOHCHjOH and may be printed as such on some labels. Ethylene glycol is a colorless, thick liquid with a sweet taste, is toxic by ingestion and by inhalation, and among its many uses is a permanent antifreeze and coolant for automobiles. It is a combustible liquid with a flash point of 240"F. 

Shanzer and Mayer-Shochet have utilized disubstituted stannoxanes as covalent templates for the formation of tetralactones. In this procedure, a dialkyl stannoxane is condensed with a glycol to form a cyclic-distannoxane as illustrated below. In a typical preparation, the distannoxane (i) was dissolved in CCI4 (ca. 0.04 At) at reflux and sebacoyl chloride (2 eq) was added dropwise at reflux. After heating for 20 h, the solution was concentrated to a solid. Chromatography afforded the tetralactone in 30% yield. ... 

Lclobanincs, CuHjjOaN (Formula XVIII). These are diketo-bases resulting from the chromic acid oxidation of the corresponding lelobanidines. Those recorded in Table B are Z- and dZ-forms, derived from ZI and ZII, and dl forms of lelobanidine respectively, dZ-lelobanine is the best known of these products. The methiodide, not isolated, on treatment with silver oxide yields dimethylamine and a neutral, deep-yellow oil convertible by hydrogenation into a glycol, b.p. 117-8°/0-03 mm.,... 

Nickel peroxide is a solid, insoluble oxidant prepared by reaction of nickel (II) salts with hypochlorite or ozone in aqueous alkaline solution. This reagent when used in nonpolar medium is similar to, but more reactive than, activated manganese dioxide in selectively oxidizing allylic or acetylenic alcohols. It also reacts rapidly with amines, phenols, hydrazones and sulfides so that selective oxidation of allylic alcohols in the presence of these functionalities may not be possible. In basic media the oxidizing power of nickel peroxide is increased and saturated primary alcohols can be oxidized directly to carboxylic acids. In the presence of ammonia at —20°, primary allylic alcohols give amides while at elevated temperatures nitriles are formed. At elevated temperatures efficient cleavage of a-glycols, a-ketols... 

Fnr stripping service, as in a glycol or amine contactor (see Chapt 7 a bubble cap trays are the most common. In recent years, there has b growing movement toward crimped sheet structured packing. Improved vapor and liquid distributor design in conjunction with struc-... 

In static systems, the cooling jackets are normally filled with a glycol and water mixture to provide for uniform heat distribution within the cylinder. This system may be used where the AT of the gas is less than 150°F and discharge gas temperature is less than 190°F. 

The facts in favour of the first are that cpiinonc, like a ])cioxicle, has a strong oxidising action, that on reduction it yields, not a glycol, but a dihydroxybenzene moreover, with I CI- instead of a tetra-chloro-deiivative, a dichloroben/cnc is foi ined. In favour of the ketone structure is the formation of a mono- ami di-o ime f(loldschiniclt). 

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