Zinc applications

A common critical limit for Zn deficiency in soils has been 0.5 mg/kg DTPA-extractable Zn for different crops (maize, wheat, and rice) (Sillanpaa, 1982). DTPA-extractable Zn concentration of 0.5-1.0 mg/kg has been marginal for sensitive crops (Sillanpaa, 1982). Brown isohumic calcareous soils of New South Wales in Australia with 35-60 mg/kg of total Zn showed Zn deficiency due to the low bioavailability of Zn. Zinc deficiency has been reported to occur in wheat on solidized solonetz and solodic soils and other calcareous soils of South Australia. Zinc application at the rate of 0.6-28 kg/ha to cereals, pastures, and maize of Australia has been reported (Reuter, 1975). Zn deficiency occurs in Turkey, India, Iraq, Mexico, and Pakistan (Table 7.8). Zinc deficiency is frequently observed in rice on calcareous paddy soils. 

Newly galvanized steel is highly reactive due to stresses from the molten zinc application process, to surface imperfections resulting in potential differences, and to the development of electrochemical cells. 

Obviously, discrepancies in observed enzyme responses may also result from differences in concentration of the active free metal in the direct environment of the enzyme. Phosphoenolpyruvate carboxylase (EC 4.1.1.31) for instance, which is extremely sensitive to in-vitro zinc application, was also inhibited in intact 7 day old Zea mays seedlings, treated with very high amounts of zinc (Stiborova etai., 1988). In Phaseolus vulgaris grown on a substrate containing toxic amounts of zinc, on the contrary, the same enzyme showed a significant capacity increase as compared to the control (Clijsters et al., 1984). 

Satisfactory correlations between extractable heavy metals and pH for a variety of soils are notoriously poor. Thome et al, (233) found no consistent correlations for Utah soils between pH 3.2 acetic acid plus 0.05N potassium chloride extractable or total zinc with pH (or organic matter content). They concluded that total zinc differentiated zinc-deficient soils as well as the extraction procedure used. Brown et al, (38) observed no correlation between soil pH and either response to zinc application or ammonium acetate-dithizone extractable zinc. Kanehiro (129) did not find a satisfactory relation between soil pH and acid-extractable zinc however, if his samples which were more acid than pH 5.5 are ignored then there is a tendency for acid-extractable zinc to decrease with soil pH. Furthermore, if surface and subsurface samples are segregated the relationship is improved. This may be because of the presence of greater amounts of organic matter in the surface horizon samples hence, the hydrous oxides and their occluded metals were more soluble. 

Kynast G, Saling E. 1986. Effect of oral zinc application during pregnancy. Gynecol Obstet Invest 21 117-123. 

A number of variants of this approach have been proposed and evalnated bnt there are no fnll-scale commercial operations solely for the purpose of zinc recovery. Two processes closest to commercial development for zinc applications are the Horsehead Flame Reactor and the Contop Hame Cyclone Reactor. 

This type of battery can now replace many remotely activated silver oxide-zinc applications, resulting in an equal or smaller size, lightweight battery at lower cost. 

For practical applicability, several aspects have to be considered such as tire anode material (sacrificial (e.g. zinc) or inert (e.g. Pt/Ti or graphite)), tlie conductivity of tlie medium and tlie current distribution. Catliodic protection is typically used for buried constmctions (e.g. pipelines), off-shore stmctures or ship hulls. 

Reactor-grade zirconium is essentially free of hafnium. Zircaloy(R) is an important alloy developed specifically for nuclear applications. Zirconium is exceptionally resistant to corrosion by many common acids and alkalis, by sea water, and by other agents. Alloyed with zinc, zirconium becomes magnetic at temperatures below 35oK. 

Design Applications of Gravity Cast Zinc, International Lead Ziuc Research Organization/Zinc Institute, New York, 1972, 36 pp. 

H. E. Brown, Zinc Oxide, Properties and Applications, International Lead Zinc Organization, Inc., New York, 1976, pp. 56—59. 

The transmetallation of lithio derivatives with either magnesium bromide or zinc chloride has been employed to increase further their range of synthetic application. While the reaction of l-methyl-2-pyrrolyllithium with iodobenzene in the presence of a palladium catalyst gives only a poor yield (29%) of coupled product, the yield can be dramatically improved (to 96%) by first converting the lithium compound into a magnesium or zinc derivative (Scheme 83) (81TL5319). 

Metal oxides, sulfides, and hydrides form a transition between acid/base and metal catalysts. They catalyze hydrogenation/dehydro-genation as well as many of the reactions catalyzed by acids, such as cracking and isomerization. Their oxidation activity is related to the possibility of two valence states which allow oxygen to be released and reabsorbed alternately. Common examples are oxides of cobalt, iron, zinc, and chromium and hydrides of precious metals that can release hydrogen readily. Sulfide catalysts are more resistant than metals to the formation of coke deposits and to poisoning by sulfur compounds their main application is in hydrodesulfurization. 

Simultaneous detenuination of Cu and Zn in the form of coloured PAR complexes is performed at pH 10 in the presence of pyrophosphate which binds the admixtures of Al, Fe and Mn into the inactive complexes. The measurements of the change in the optical density are made at 520 and 550 nm before and after the destmction of the complexes by EDTA, or at 530 nm before and after the destruction of the copper complexes by the thioglycolic acid and the destmction of the zinc complexes by EDTA. The detection limit for Cu is 2-5, for Zn - 3 p.g/diW. The application of these methodics at pH 8 enables one to determine simultaneously Cu and Zn at high excess of the latter. 

Concentration limits of the diphosphate-ion, admissible to determination of magnesium and cobalt, manganese and cobalt, zinc and cobalt by spectrophotometric method with application of the l-(2-pyridylazo)-resorcinol (PAR) are presented. Exceeding maintenance of the diphosphate-ion higher admissible supposes a preliminary its separation on the anionite in the H+-form. The optimum conditions of cobalt determination and amount of the PAR, necessary for its full fastening are established on foundation of dependence of optical density of the cobalt complex with PAR from concentration Co + and pH (buffer solutions citrate-ammoniac and acetate-ammoniac). 

Effective metal ion adsorbent has been prepai ed by the immobilization of propylthioethyleamine ligand onto the surface of silica gel (SN-SiO,).The effectiveness of this material to bind metal ions has been attributed to the complexation chemistry between the ligand and the metal. We are investigating properties of propylthioethyleamine grafted on the surface of silica and possibility of application of the obtained surface for preconcentration of heavy metals such as zinc, lead, cadmium, copper, etc. from water solutions. 

Separate the metal from the environment with a physical barrier. Many corrosion inhibitors make use of this principal to protect metals. Proper use of an appropriate inhibitor may reduce or eliminate pitting. Pits are frequently initiation sites for corrosion-fatigue cracks. The effectiveness of inhibitors depends upon their application to clean metal surfaces. An example of this method is the use of zinc coatings on steel to stifle pit formation. 

The procedures as outlined are applicable to both the aliphatic and aromatic series. They are superior to the common interchange method in that they avoid the fractional distillation which is very troublesome in the aliphatic series. They have been used in numerous instances and can be adapted to give mixed anli3"drides. Benzoic anhydride has been obtained, by closely related procedures, from benzoic acid and benzoyl chloride by heating under reduced pressure or in the presence of zinc chloride. 

The factor a varies considerably with individual alloys and is also dependent on the application conditions. It varies between wide limits from about 0.98 for zinc to below 0.5 for magnesium anodes. The a values given in Tables 6-1 to 6-4 apply to cold seawater. Deviations in application (i.e., cooling water) temperature and loading can lead to considerable changes. 

Potential control with zinc reference electrodes presented a problem because deposits of corrosion products are formed on zinc in hot water. This caused changes in the potential of the electrode which could not be tolerated. Other reference electrodes (e.g., calomel and Ag-AgCl reference electrodes) were not yet available for this application. Since then, Ag-AgCl electrodes have been developed which successfully operate at temperatures up to 100°C. The solution in the previous case was the imposition of a fixed current level after reaching stationary operating conditions [27]. 

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