Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

X-ray EXAFS

In a similar vein, it was shown that molybdenum amido derivatives of the isolobal terminal phosphide and carbide, " and related chalcogenide atoms,could be obtained. Detailed mechanistic studies of the Mo N(R)Ar 3/N2 system involving X-ray, EXAFS, magnetic, Raman, and isotopicaUy labelled NMR spectroscopy showed that the reaction proceeded through an intermediate involving an end-on bound N2 bridging the molybdenum centres (Scheme... [Pg.175]

In electrochemistry, because electrical quantities are easy to use and provide information directly relating to the behavior of the interface, they are particularly useful to identify interfacial processes. Contrary to other techniques, which require a vacuum chamber [low-energy electron diffraction (LEED), Auger electron spectroscopy, etc.] or electromagnetic radiation (optical ellipsometry, or X-rays EXAFS), which need no alteration of the electrode surface, electrical techniques can be used in situ on any surface state of the electrode. In addition, thanks to the advances in electronics, experimentalists can use more and more sophisticated... [Pg.113]

EXAFS Extended X-ray absorption fine structure spectroscopy. A spectroscopic technique which can determine interatomic distances very precisely. [Pg.170]

EXAFS Extended x-ray absorption fine structure [177, 178] Variation of x-ray absorption as a function of x-ray energy beyond an absorption edge the probability is affected by backscattering of the emitted electron from adjacent atoms Number and interatomic distance of surface atoms... [Pg.316]

As we have seen, the electron is the easiest probe to make surface sensitive. For that reason, a number of hybrid teclmiques have been designed that combine the virtues of electrons and of other probes. In particular, electrons and photons (x-rays) have been used together in teclmiques like PD [10] and SEXAFS (or EXAFS, which is the high-energy limit of XAES) [2, Hj. Both of these rely on diffraction by electrons, which have been excited by photons. In the case of PD, the electrons themselves are detected after emission out of the surface, limiting the depth of sampling to that given by the electron mean free path. [Pg.1756]

Kongingsberger D C and Prins R (ed) 988 X-Ray Absorption Principies, Appiications, Techniques of EXAFS, SEXAFS and XANES (New York Wiley)... [Pg.1798]

Very recently the first x-ray study (EXAFS) has been performed on hydrophobic hydration. ... [Pg.16]

Acronyms abound in phofoelecfron and relafed specfroscopies buf we shall use only XPS, UPS and, in Sections 8.2 and 8.3, AES (Auger elecfron specfroscopy), XRF (X-ray fluorescence) and EXAFS (exfended X-ray absorption fine sfmcfure). In addition, ESCA is worth mentioning, briefly. If sfands for elecfron specfroscopy for chemical analysis in which elecfron specfroscopy refers fo fhe various branches of specfroscopy which involve fhe ejection of an elecfron from an atom or molecule. Flowever, because ESCA was an acronym infroduced by workers in fhe field of XPS if is mosf often used to refer to XPS rather than to electron spectroscopy in general. [Pg.290]

Figure 8.34 Experimental method for extended X-ray absorption fine structure (EXAFS)... Figure 8.34 Experimental method for extended X-ray absorption fine structure (EXAFS)...
Work on EXAFS then progressed very little until the advent of the synchrotron radiation source (storage ring), described in Section 8.1.1.1. This type of source produces X-ray radiation of the order of 10 to 10 times as intense as that of a conventional source and is continuously tunable. These properties led to the establishment of EXAFS as an important structural tool for solid materials. [Pg.329]

Figure 8.38 Curve fitting of Mo extended X-ray absorption fine structure (EXAFS) for Mo(SC6H4NH)3, taking into account (a) sulphur and (b) sulphur and nitrogen atoms as near neighbours. (Reproduced, with permission, trom Winnick, H. and Doniach, S. (Eds), Synchrotron Radiation Research, p. 436, Plenum, New York, 1980)... Figure 8.38 Curve fitting of Mo extended X-ray absorption fine structure (EXAFS) for Mo(SC6H4NH)3, taking into account (a) sulphur and (b) sulphur and nitrogen atoms as near neighbours. (Reproduced, with permission, trom Winnick, H. and Doniach, S. (Eds), Synchrotron Radiation Research, p. 436, Plenum, New York, 1980)...
Extended x-ray absorption fine stmcture measurements (EXAFS) have been performed to iavestigate the short-range stmcture of TbFe films (46). It is observed that there is an excess number of Fe—Fe and Tb—Tb pairs ia the plane of the amorphous film and an excess number of Tb—Fe pairs perpendicular to film. The iacrease of K with the substrate temperature for samples prepared by evaporation is explained by a rearrangement of local absorbed atom configurations duting the growth of the film (surface-iaduced textuting) (47). [Pg.145]

The trimetaUic uranyl cluster (U02)3(C03) 3 has been the subject of a good deal of study, including nmr spectroscopy (179—182) solution x-ray diffraction (182), potentiometric titration (177,183,184), single crystal x-ray diffraction (180), and exafs spectroscopy in both the soHd and solution states (180). The data in this area have consistendy led to the proposal and verification of a trimeric (U02)3(C03) 3 cluster (181,182,185). [Pg.327]

Extended X-Ray Absorption Fine Structure, EXAFS 214 Surface Extended X-Ray Absorption Fine Structure and Near Et e X-Ray Absorption Fine Structure, SEXAFS/NEXAFS 227 X-Ray Photoelectron and Auger Diffraction,... [Pg.193]

This chapter contains articles on six techniques that provide structural information on surfaces, interfeces, and thin films. They use X rays (X-ray diffraction, XRD, and Extended X-ray Absorption Fine-Structure, EXAFS), electrons (Low-Energy Electron Diffraction, LEED, and Reflection High-Energy Electron Diffraction, RHEED), or X rays in and electrons out (Surfece Extended X-ray Absorption Fine Structure, SEXAFS, and X-ray Photoelectron Diffraction, XPD). In their usual form, XRD and EXAFS are bulk methods, since X rays probe many microns deep, whereas the other techniques are surfece sensitive. There are, however, ways to make XRD and EXAFS much more surfece sensitive. For EXAFS this converts the technique into SEXAFS, which can have submonolayer sensitivity. [Pg.193]


See other pages where X-ray EXAFS is mentioned: [Pg.422]    [Pg.111]    [Pg.4730]    [Pg.31]    [Pg.4729]    [Pg.1068]    [Pg.27]    [Pg.29]    [Pg.697]    [Pg.422]    [Pg.111]    [Pg.4730]    [Pg.31]    [Pg.4729]    [Pg.1068]    [Pg.27]    [Pg.29]    [Pg.697]    [Pg.692]    [Pg.568]    [Pg.1791]    [Pg.1792]    [Pg.1792]    [Pg.2725]    [Pg.2907]    [Pg.329]    [Pg.333]    [Pg.269]    [Pg.269]    [Pg.92]    [Pg.167]    [Pg.139]    [Pg.383]    [Pg.546]    [Pg.17]    [Pg.17]    [Pg.143]    [Pg.195]   
See also in sourсe #XX -- [ Pg.306 ]

See also in sourсe #XX -- [ Pg.79 ]




SEARCH



EXAF = extended X-ray absorption fine

EXAFS

EXAFS (extended X-ray

EXAFS (extended X-ray absorption

EXAFS (extended X-ray absorption fine oxide-support

EXAFS (extended X-ray absorption spectroscopy

EXAFS (extended X-ray adsorption fine

EXAFS (extended x-ray absorption fine

EXAFS and X-Ray Absorption Spectroscopy

EXAFS—See Extended X-ray absorption

EXAFS—See Extended x-ray

EXAFS—See Extended x-ray absorption fine structure

Edge X-ray absorption fine structure EXAFS)

Extended X-ray Absorption Fine Structure, EXAF

Extended X-ray absorption fine structure EXAFS) analysis

Extended X-ray absorption fine structure EXAFS) measurements

Extended X-ray absorption fine structure EXAFS) region

Extended X-ray absorption fine structure EXAFS) spectroscopy

Extended X-ray absorption fine structure EXAFS) technique

Extended X-ray adsorption fine structure EXAFS)

Extended x-ray absorption fine structure EXAFS

Extended x-ray absorption fine structure EXAFS) spectra

In-situ X-ray analysis and EXAFS

X-Ray Diffraction and EXAFS Analysis

X-ray absorption fine structure EXAFS)

X-ray absorption spectroscopy (EXAFS and XANES)

X-ray absorption spectroscopy (including EXAFS and XANES)

X-ray absorption spectroscopy EXAFS

X-ray spectroscopy EXAFS

XAS and Extended X-Ray Absorption Fine Structure (EXAFS) for Determination of the Short-Range Order

© 2024 chempedia.info