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Water propane

Some liquids can vaporize with heat (water, propane). [Pg.189]

Carboxylic acids can also be formed by a reaction of small alkanes, carbon monoxide, and water on solid acid catalysts (93,94). By in situ C MAS NMR spectroscopy (93), the activation of propane and isobutane on acidic zeolite HZSM-5 was investigated in the presence of carbon monoxide and water. Propane was converted to isobutyric acid at 373 73 K, while isobutane was transformed into pivalic acid with a simultaneous production of hydrogen. On SZA, methyl isopropyl ketone was observed as evidence for the carbonylation of isobutane with carbon monoxide after the sample was held at 343 K for 1 h (94). When the reaction of isobutane and carbon monoxide was carried out in the presence of water, pivalic acid was identified as the main reaction product (94). These observations are rationalized by the existence of a small number of sites capable of generating carbenium ions, which can be further trapped by carbon monoxide (93). [Pg.177]

Figure 4.2b shows the equivalent of Figure 4.2a to be slightly more complex for systems such as ethane + water, propane + water, isobutane + water, or water with the two common noncombustibles, carbon dioxide or hydrogen sulfide. These systems have a three-phase (Lw-V-Lhc) line at the upper right in the diagram. This line is very similar to the vapor pressure ( V-Lhc) line of the pure hydrocarbon, because the presence of the almost pure water phase adds a very low vapor pressure (a few mmHg at ambient conditions) to the system. [Pg.200]

Similar to AATCC TM 118, but with 8 water-propan-2-ol mixtures with increasing alcohol content. [Pg.83]

Sodium hydroxide [CORROSIVE] Aqueous formaldehyde (37%) [TOXIC] Tetrahydrofuran (THF) [FLAMMABLE] Distilled water Propan-2-ol [FLAMMABLE]... [Pg.88]

Problem 14.30. For each of the following pairs of compounds, indicate which compound has the higher value of the property. Explain, (a) Boiling point methyl propyl ether versus butanone, (b) solubility in water methyl propyl ether versus butanone, (c) solubility in water propanal versus butanal, (d) boiling point butanone versus butanal. [Pg.293]

Some textbooks state that the pH scale runs from 0 to 14, while others that it runs from 1 to 14. They both state that 7 is in the middle It seems that the pH scale can rvm from a practical value of around -1.6 to around 15.6. Typical wide-range indicator paper available in schools runs from 3 to 11, and the same is true for universal indicator solutions. The colour of pH 7 is green for some universal indicator solutions, but yellow for others. The recipe used for the mixture of indicators determines the actual colour seen. Yamada created and patented the first recipe (water, propan-l-ol, phenolphthalein sodium salt, sodium hydroxide, methyl red, bromothymol blue monosodium salt and thymol blue monosodium salt) in 1923. [Pg.196]

Water Propane Carbon dioxide Nitrogen Argon.Polynomial... [Pg.104]

Zielkiewicz, J. Konitz, A. (Vapour -l- liquid) equilibria of (N,N-dimethylformamide + water + propan-l-ol) at the temperature... [Pg.3246]

A comparison with the known rate for the reaction in water reveals a kinetic isotope effect with the ratio kuiojkozo = 2.5 at 25 °C. Reaction of with Fe has also been studied in water-propan-2-ol. ... [Pg.25]

Redox studies of the Ghini complexes are of considerable interest, as the change of nuclearity of [Pt3(GO)6] from n to (n—l) corresponds to a reduction. In one paper, the reduction has been studied by time-resolved pulse radiolysis in a water/propan-2-ol solution, where alcohol radicals are generated. " The initial step has been demonstrated to be the formation of [Pt3(GO)6] , which then immediately splits into [Pt3(GO)6]4 and [Pt3(GO)6] -4 The fate of the [Pt3(GO)6] 4 ion depends on n with the smaller values of n (6 or 7), dimerization tends to occur, whereas with larger values (8 or 9), further reduction is more likely. An additional observation was that if small quantities of [Pt3(GO)6]4 are formed in the presence of excess [Pt3(GO)6]6 X comproportionation results giving 2 equiv. of [Pt3(GO)6]s -... [Pg.410]

The East Ohio plant used water, ammonia, ethylene, and methane. The Chicago District Pipeline plant was to have used water, propane, ethylene, methane, and nitrogen. A major consideration in the choice of refrigerants, aside from that of efficiency, is ease of replacement should a charge be lost. At some foreign locations it would be advisable to use refrigerants which could be derived from the charge stock itself. [Pg.341]

As the water propane ratio increases from 250 to 1000, the propane conversion and the selectivity of methanol formation decrease linearly i.e., as in the partial oxidation of methane, water in the SC state reduces the oxidation rate. With increasing air-to-propane ratio (Fig. 9.22), the propane conversion increases a monotonically, whereas the oxygen conversion passes through a maximum at an air-to-propane ratio of five. It is at this ratio (one oxygen molecule consumed per hydrocarbon molecule, as in the partial oxidation of methane) that the maximum selectivity of formation of methanol, methane, and some other organic compounds is achieved. The experimental results in the presence and absence of catalysts showed complete identity (Fig. 9.22). [Pg.164]


See other pages where Water propane is mentioned: [Pg.413]    [Pg.111]    [Pg.162]    [Pg.245]    [Pg.402]    [Pg.402]    [Pg.99]    [Pg.99]    [Pg.99]    [Pg.99]    [Pg.100]    [Pg.961]    [Pg.233]    [Pg.206]    [Pg.58]    [Pg.155]    [Pg.427]    [Pg.249]    [Pg.99]    [Pg.99]    [Pg.99]    [Pg.99]    [Pg.100]    [Pg.208]    [Pg.219]    [Pg.197]    [Pg.69]   
See also in sourсe #XX -- [ Pg.403 , Pg.407 ]




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