Water liquid phase viscosity

One important characteristic of microemulsion viscosity is that it is a strong function of phase compositions. In UTCHEM, liquid phase viscosities are modeled as a function of pure component viscosities and the phase concentrations of the organic, water, and surfactant ... 

When super-dry chlorine (having a maximum water content of 10 mol ppm) is required, a fourth drying tower is used. This column removes very little water vapor, so that the liquid recirculated will be about 96 wt % sulfuric acid. Because of the high liquid-phase viscosity (greater than 15 cps), the absorption in this tower will be substantially liquid-film controlled. 

Miura (Y3) have studied the effect of the addition of glycerol to water on the reaction rate constant. The reaction in the liquid phase is second order. Their values for k" at 28°C, which indicate a slight increase with increasing viscosity, are given in Table I. 

In reactor design, it is very important to know how and where turbulence is generated and dissipated. In a liquid phase, it is also important that the smallest eddies are sufficiently small. The ratio between the reactor scale (I) and the smallest turbulent scale, the Kolmogorof scale rj), usually scales as L/x]aR . The Kolmogorov scale can also be estimated from the viscosity and the power dissipation T] = (v 30 xm in water with a power input of 1W kg and from the Bachelor scale 3 pm in liquids. For a liquid, the estimation of the time... 

Baxendale and Wardman (1973) note that the reaction of es with neutrals, such as acetone and CC14, in n-propanol is diffusion-controlled over the entire liquid phase. The values calculated from the Stokes-Einstein relation, k = 8jtRT/3jj, where 7] is the viscosity, agree well with measurement. Similarly, Fowles (1971) finds that the reaction of es with acid in alcohols is diffusion-controlled, given adequately by the Debye equation, which is not true in water. The activation energy of this reaction should be equal to that of the equivalent conductivity of es + ROH2+, which agrees well with the observation of Fowles (1971). 

IL. Dilute solution viscosity measurements were done at 30 with the appropriate Ostwald-Fenske capillary viscometers. The water content of all organic solvents, used as the liquid phase in solid-liquid PTC runs was analyzed by potentiometric Karl Fischer titration using a Metrohm AG CH 9100 model automatic titrator. 

This diversity in solvent properties results in large differences in the distribution ratios of extracted solutes. Some solvents, particularly those of class 3, readily react directly (due to their strong donor properties) with inorganic compounds and extract them without need for any additional extractant, while others (classes 4 and 5) do not dissolve salts without the aid of other extractants. These last are generally used as diluents for extractants, required for improving then-physical properties, such as density, viscosity, etc., or to bring solid extractants into solution in a liquid phase. The class 1 type of solvents are very soluble in water and are useless for extraction of metal species, although they may find use in separations in biochemical systems (see Chapter 9). 

The oil sands from the Athabasca deposits are a mixture of sand grains, water, and high-viscosity crude hydrocarbon called bitumen. At room temperature, bitumen is a semisolid, but will convert to a viscous liquid at about 300°F (149°C). Sand grains are about 0.075 to 0.25 mm in diameter with small amounts of attached clay. The grains are all in direct contact and wet with a thin continuous sheetlike layer of water. Bitumen fills the void between the wetted sand grains and forms a continuous phase through the pores. Bitumen is about 17% to 18% of the mass. The composition of Athabasca oil sand bitumen is provided in TABLE 12-6. 

While applications and analysis of ILs may provide some guidance on potential applications of SCIL-based phases in EC, these phases may also provide useful information about ILs. As Poole points out [16], a key requirement for the successful integration of ILs in industrial processes is the ability of being applied to rapid liquid-liquid phase separation systems. Shake-flask methods are commonly used to measure IL/water partition coefficients. However, the high viscosity and cost of these materials coupled with the time and effort required for traditional shake-flask methods render this... 

IL viscosity is extremely sensitive to additives [5]. Mixtures of IL and compatible solvents and water may produce biphasic liquid systems usable in CCC. The short-chain alcohol-[C4CiIm][PFg]-water and acetonitrile-[C4CiIm][PFJ-water ternary phase diagrams have been studied [7]. Alcohols were found to have a tendency to dissolve preferentially in the aqueous upper phase producing an IL lower phase of limited volume and high viscosity [7]. Acetonitrile partitions well between the upper aqueous phase and the lower IL phase, greatly reducing the viscosity of the IL-rich lower phase. 

The effects of broth viscosity on k a in aerated stirred tanks and bubble columns is apparent from Equations 7.37 and 7.41, respectively. These equations can be applied to ordinary non-Newtonian liquids with the use of apparent viscosity as defined by Equation 2.6. Although liquid-phase diffusivity generally decreases with increasing viscosity, it should be noted that at equal temperatures, the gas diffusivities in aqueous polymer solutions are almost equal to those in water. 

Ucon HTF-500. Union Carbide Corp. manufactures Ucon HTF-500, a polyalkylene glycol suitable for liquid-phase heat transfer. The fluid exhibits good thermal stability in the recommended temperature range and is inhibited against oxidation. The products of decomposition are soluble and viscosity increases as decomposition proceeds. The vapor pressure of the fluid is negligible and it is not feasible to recover the used fluid by distillation. Also, because the degradation products are soluble in the fluid, it is not possible to remove them by filtration any spent fluid usually must be burned as fuel or discarded. The fluid is soluble in water. 

Lyophilic sols are true solutions of large molecules in a solvent, Solutions of starch, proteins, or polyvinyl alcohol in water are representative of numerous examples. Properties of these solutions at equilibrium (for example, density and viscosity) are regular functions of concentration and temperature, independent of the method of preparation. The solvent-macromolecule compound system may consist uf more than one phase, each phase in general containing both components. Thus, if a solid polymer is added to a solvent in an amount exceeding the solubility limit, the system will consist of a liquid phase (solvent with dissolved polymer) and a solid phase (polymer swollen with solvent, i.e., a polymer with dissolved solvent). 

Supercritical water is neither a liquid nor a gas, but it has properties between the liquid and gas phases (i.e., density approaching its liquid phase and diffusivity and viscosity approaching its gas phase). At the critical point, hydrogen bonds disappear, and water becomes similar to a moderately polar solvent. Oxygen and almost all hydrocarbons become completely miscible... 

---