Water, generally

Methanol is more soluble in aromatic than paraffinic hydrocarbons. Thus varying gasoline compositions can affect fuel blends. At room temperature, the solubiUty of methanol in gasoline is very limited in the presence of water. Generally, cosolvents are added to methanol—gasoline blends to enhance water tolerance. Methanol is practically insoluble in diesel fuel. 

Dehydration of organics (removal of <1% water) generally feasible by molecular sieving, if kinetic diameter of organic >300 pm. 

Specific Conductance. The specific conductance depends on the total concentration of the dissolved ioni2ed substances, ie, the ionic strength of a water sample. It is an expression of the abiUty of the water to conduct an electric current. Freshly distilled water has a conductance of 0.5—2 ]lS/cm, whereas that of potable water generally is 50—1500 ]lS/cm. The conductivity of a water sample is measured by means of an a-c Wheatstone-bridge circuit with a null indicator and a conductance cell. Each cell has an associated constant which, when multiphed by the conductance, yields the specific conductance. 

Water generally is used for gases fairly soluble in water, oils for light hydrocarbons, and special chemical solvents for acid gases such as CO9, SO9, and H9S. Sometimes a reversible chemical reaction will result in a veiy high solubility and a minimum solvent rate. Data on actual systems are desirable when chemical reactions are involved, and those available are referenced later under Absorption with Chemical Reaction. ... 

Potable Water Systems Process Water General Service... 

All stated pK values in this book are for data in dilute aqueous solutions unless otherwise stated, although the dielectric constants, ionic strengths of the solutions and the method of measurement, e.g. potentiometric, spectrophotometric etc, are not given. Estimated values are also for dilute aqueous solutions whether or not the material is soluble enough in water. Generally the more dilute the solution the closer is the pK to the real thermodynamic value. The pK in mixed aqueous solvents can vary considerably with the relative concentrations and with the nature of the solvents. For example the pK values for V-benzylpenicillin are 2.76 and 4.84 in H2O and H20/EtOH (20 80) respectively the pK values for (-)-ephedrine are 9.58 and 8.84 in H2O and H20/Me0CH2CH20H (20 80) respectively and for cyclopentylamine the pK values are 10.65 and 4.05 in H2O and H20/EtOH (50 50) respectively. pK values in acetic acid or aqueous acetic acid are generally lower than in H2O. 

Cathodic protection (CP) is an electrochemical technique of corrosion control in which the potential of a metal surface is moved in a cathodic direction to reduce the thermodynamic tendency for corrosion. CP requires that the item to be protected be in contact with an electrolyte. Only those parts of the item that are electrically coupled to the anode and to which the CP current can flow are protected. Thus, the inside of a buried pipe is not capable of cathodic protection unless a suitable anode is placed inside the pipe. The electrolyte through which the CP current flows is usually seawater or soil. Fresh waters generally have inadequate conductivity (but the interiors of galvanized hot water tanks are sometimes protected by a sacrificial magnesium anode) and the conductivity... 

Traditionally, stabilization of unstable treated water generally is provided by simply lowering the treated water pH slightly or by using a threshold phosphate technique. Neither of these techniques is particularly suitable for boiler FW makeup because an alkaline FW is required and rapid reversion of the polyphosphate will take place under hot FW conditions, thus leading to phosphate deposits in the pre-boil-... 

The choice of emulsifier has a large part to play in which kind of emulsion you get. Emulsifiers that are soluble in water generally have shorter chains of fats. These make emulsions of oil in water. Emulsi-... 

Nucleophilic attack by water generally results in the cleavage of the amide, glycoside, or ester bonds that hold biopolymers together. This process is termed hydrolysis. Conversely, when monomer units are joined together to form biopolymers such as proteins or glycogen, water is a product, as shown below for the formation of a peptide bond between two amino acids. 

The natural composition of obsidian includes very little water, generally less than 0.1%. When new obsidian surfaces are created, either by the natural breakdown of obsidian bulks or by human activity, the exposure of a new surface to humidity in the air or to water brings about a process known as hydration the surface adsorbs (takes up) water and becomes... 

Water. Water generally occurs in air in low or relatively low concentrations, mostly in the form of atmospheric moisture. Its importance cannot, however, be overemphasized, since atmospheric moisture, unique to the surface of the earth, is a determining factor in the water cycle (see below) and in living and other processes. Moisture is, therefore, one of the most important and probably the most relevant atmospheric components for the majority of living processes. 

Carboxymethylcellulose, an excellent film-former, is a highly effective size on cellulosic substrates but has poor adhesion to synthetic fibres. It is easily desorbed, hot water generally being sufficient, although surfactant and alkali are usually added to increase the efficiency of... 

It is known that the RPLC retention parameters are often strongly correlated to the analyte s distribution coefficient in organic solvent/ water. Generally, the relationship between liquid/liquid (LL) distribution and RPLC retention are of the form of the dimensionless Collander-type equations, e.g., see Eq. (15.21)... 

Simple applicability of sweeteners is desirable. Good solubility in water generally facilitates application as many foods, and, of course, beverages contain substantial amounts of water. High solubility allows use of the sweeteners in stock solutions, which is advantageous for simple dosing and blending. 

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