Washing machine powder

The alkylphenols behave in the same manner as fatty alcohols. The nonyl (or octyl) phenol is widely used with 8 to 12 molecules of ethylene oxide. Nonylphenol is completely soluble in water at room temperature and exhibits excellent detergency. Dodecylphenol ethoxylate is used in certain agriculture emulsifiers and dinonylphenol as low or nonfoaming ingredients of household washing machine powders [3, 4]. 

The uses in the glass and ceramics industries reflect the diagonal relation between boron and silicon and the similarity of vitreous borate and silicate networks (pp. 203, 206 and 347). In the UK and continental Europe (but not in the USA or Japan) sodium perborate (p. 206) is a major constituent of washing powders since it hydrolyses to H2O2 and acts as a bleaching agent in very hot water ( 90°C) in the USA domestic washing machines rarely operate above 70°, at which temperature perborates are ineffective as bleaches. 

Powder and liquid detergents can be used in washing machines. The a-sulfo fatty acid esters are used in both product types, but their solubility in water has... 

Uses. The major applications of phenol are phenolic resins, Bisphenol A, and caprolactam. The reaction of phenol with formaldehyde gives liquid phenolic resins (used extensively as the adhesive in plywood) and solid resins (used as engineering plastics in electrical applications). In powder form, the phenolic resin can be molded easily and are completely nonconductive. These phenolic resins or plastics can be found in panel boards, switchgears, and telephone assemblies. The agitator in your washing machine is probably a phenolic resin. 

The first two components are the active surfactants, whereas the other components are added for a variety of reasons. The polyphosphate chelate Ca ions which are present (with Mg ions also) in so-called hard waters and prevents them from coagulating the anionic surfactants. Zeolite powders are often used to replace phosphate because of their nutrient properties in river systems. Sodium silicate is added as a corrosion inhibitor for washing machines and also increases the pH. The pH is maintained at about 10 by the sodium carbonate. At lower pH values the acid form of the surfactants are produced and in most cases these are either insoluble or much less soluble than the sodium salt. Sodium sulphate is added to prevent caking and ensures free-flowing powder. The cellulose acts as a protective hydrophilic sheath around dispersed dirt particles and prevents re-deposition on the fabric. Foam stabilizers (non-ionic surfactants) are sometimes added to give a... 

Laundry powders in Europe use sodium percarbonate and a bleach activator, tetraacetylethylenediamine ( ED), to form peracetic acid in the washing machine that then reacts with bleachable stains such as tea, red wine, coffee, and curry to remove /bleach them from cloth. Transition metal ions, in particular copper, cause first decomposition of peracetic add before it can bleach stains and second react with peroxide to form highly readive hydroxyl radicals that can cause dye and fabric damage [32]. Chelants bind with copper and other metals to prevent these unwanted side readions. 

An initial screening test was developed to measure the peracid release of a fully formulated chelant-free detergent powder to which equimolar amounts of chelants were added. Peracid release was measured at 40 °C over 30 min in a synthetic hard water with transition metal ions added at ppm levels representative of those found in wash liquors of a typical washing machine with added soil [36] Ca 76, Mg 15, Fe... 

Silicates. Both sodium and potassium silicate solids or solutions have valued functionality including emulsification, buffering, deflocculation, and antiredeposition ability. Silicates also provide corrosion protection to metal parts in washing machines, as well as to the surfaces of china patterns and metal utensils in automatic dishwashers. Silicates are manufactured in liquid, crystalline, or powdered forms and with different degrees of alkalinity. The alkalinity of the silicate provides buffering capacity in the presence of acidic soils and enhances the sequestration ability of the builder system in the formulation. The sili-cate/alkali ratios of the silicates are selected by the formulator to meet specific product requirements. Silicate ratios of 1/1 are commonly used in dry blending applications with silicate ratios of 2/1 and higher commonly used in laundry and autodish applications. 

The methods in the left side of Figure 4-11 are mostly related to devices those in the right side to matter. However, this division is seldom straightforward you will have realized that understanding detergent powder (matter) requires understanding of the washing machine (a device). 

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