Viscosity practical

Temperature Dependence of Pure Metal Viscosity. Practically speaking, empirical and semiempirical relationships do a much better job of correlating viscosity with nsefnl parameters such as temperature than do equations like (4.7). There are nnmerons models and their resnlting equations that can be used for this purpose, and the interested student is referred to the many excellent references listed at the end of this chapter. A useful empirical relationship that we have already studied, and that is applicable to viscosity, is an Arrhenius-type relationship. For viscosity, this is... 

Division of the total tensile strain under conditions of F = const into several components 25,6R,69) produced interesting results (see Fig. 8). It has been found that the behavior of molten low-density polyethylene (Fig. 8a) is qualitatively different from polyisobutylene (Fig. 8 b) the extension of which was performed under temperature conditions where the high-elasticity modulus, relaxation time, and initial Newtonian viscosity practically coincided (in the linear range) in the compared polymers. Flow curves in the investigated range of strain velocities were also very close to one another (Fig. 21). It can be seen from the comparison of dependencies given in Fig. 8a,... 

The classification of motor oils has not been completed in the ISO standard because the technical differences between motors in different parts of the world, particularly Europe and the United States, make the implementation of a single system of classification and specifications very difficult. In practice, different systems coming from national or international organizations are used. The best known is the SAE viscosity classification from the Society of Automotive Engineers, developed in the United States. 

Viscosity is measured in poise. If a force of one dyne, acting on one cm, maintains a velocity of 1 cm/s over a distance of 1 cm, then the fluid viscosity is one poise. For practical purposes, the centipoise (cP) is commonly used. The typical range of gas viscosity in the reservoir is 0.01 - 0.05 cP. By comparison, a typical water viscosity is 0.5 -I.OcP. Lower viscosities imply higher velocity for a given pressure drop, meaning that gas in the reservoir moves fast relative to oils and water, and is said to have a high mobility. This is further discussed in Section 7. 

The field unit for permeability is the Darcy (D) or millidarcy (mD). For clastic oil reservoirs, a good permeability would be greater than 0.1 D (100 mD), while a poor permeability would be less than 0.01 D (10 mD). For practical purposes, the millidarcy is commonly used (1 mD = 10" m ). For gas reservoirs 1 mD would be a reasonable permeability because the viscosity of gas is much lower than that of oil, this permeability would yield an acceptable flowrate for the same pressure gradient. Typical fluid velocities in the reservoir are less than one metre per day. 

Colloidal dispersions often display non-Newtonian behaviour, where the proportionality in equation (02.6.2) does not hold. This is particularly important for concentrated dispersions, which tend to be used in practice. Equation (02.6.2) can be used to define an apparent viscosity, happ, at a given shear rate. If q pp decreases witli increasing shear rate, tire dispersion is called shear tliinning (pseudoplastic) if it increases, tliis is known as shear tliickening (dilatant). The latter behaviour is typical of concentrated suspensions. If a finite shear stress has to be applied before tire suspension begins to flow, tliis is known as tire yield stress. The apparent viscosity may also change as a function of time, upon application of a fixed shear rate, related to tire fonnation or breakup of particle networks. Thixotropic dispersions show a decrease in q, pp with time, whereas an increase witli time is called rheopexy. 

This argument is rather less convincing than it might appear, since in practice gas viscosities are found to vary with temperature rather more rapidly than. ... 

In discussing Fig. 4.1 we noted that the apparent location of Tg is dependent on the time allowed for the specific volume measurements. Volume contractions occur for a long time below Tg The lower the temperature, the longer it takes to reach an equilibrium volume. It is the equilibrium volume which should be used in the representation summarized by Fig. 4.15. In actual practice, what is often done is to allow a convenient and standardized time between changing the temperature and reading the volume. Instead of directly tackling the rate of collapse of free volume, we shall approach this subject empirically, using a property which we have previously described in terms of free volume, namely, viscosity. 

In practice, intermediate, Hquid resins, capable of further reaction are usually prepared. Polymerization is carried to an estabUshed end-point as determined by viscosity or other measurements. When the proper end-point has been reached, the reaction is terminated by adjusting the pH of the system to 5—8. Such hquid resins can be stored for six months or longer, then catalyzed and reacted further to obtain the final, desired product. 

CeUulose is the most abundant polymer, an estimated 10 t being produced aimuaUy by natural processes. SuppUes for the rayon industry can be obtained from many sources, but in practice, the wood-pulping processes used to supply the needs of the paper and board industries have been adapted to make the necessary speciaUy pure grade. Of the 3 x 10 t of wood used by the paper and board industry (13) in 1989, about 6 x 10 t were purified to provide the 2.5 x 10 t of dissolving pulp required by the viscose processes. 

The creation terms embody the changes in momentum arising from external forces in accordance with Newton s second law (F = ma). The body forces arise from gravitational, electrostatic, and magnetic fields. The surface forces are the shear and normal forces acting on the fluid diffusion of momentum, as manifested in viscosity, is included in these terms. In practice the vector equation is usually resolved into its Cartesian components and the normal stresses are set equal to the pressures over those surfaces through which fluid is flowing. 

Practically all lubricating oils contain at least one additive some oils contain several. The amount of additive that is used varies from < 0.01 to 30% or more. Additives can have detrimental side effects, especially if the dosage is excessive or if interactions with other additives occur. Some additives are multifimctional, eg, certain VI improvers also function as pour-point depressants or dispersants. The additives most commonly used in hydrautic fluids include pour-point depressants, viscosity index improvers, defoamers, oxidation inhibitors, mst and corrosion inhibitors, and antiwear compounds. 

Rheology. Flow properties of latices are important during processing and in many latex appHcations such as dipped goods, paint, inks (qv), and fabric coatings. For dilute, nonionic latices, the relative latex viscosity is a power—law expansion of the particle volume fraction. The terms in the expansion account for flow around the particles and particle—particle interactions. For ionic latices, electrostatic contributions to the flow around the diffuse double layer and enhanced particle—particle interactions must be considered (92). A relative viscosity relationship for concentrated latices was first presented in 1972 (93). A review of empirical relative viscosity models is available (92). In practice, latex viscosity measurements are carried out with rotational viscometers (see Rpleologicalmeasurement). 

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