Viscosity coefficient, definition

POISE (P). A unit of dynamic viscosity. The unit is expressed in dyne second per square centimeter The centipoise (cP) is more commonly used The formal definition of viscosity arises from the concept put forward by Newton that under conditions of parallel flow, the shearing stress is proportional to the velocity giadieut. If lire force acting on each of two planes of aiea A parallel to each oilier, moving parallel lo each other with a relative velocity V, and separated by a perpendicular distance X, be denoted by F. the shearing stress is F/A and the velocity gradient, which will be linear for a true liquid, is V/X. Thus, Ft A = q V/X, where the constant if is the viscosity coefficient or dynamic viscosity of the liquid. The poise is the CGS unit of dynamic viscosity. 

Partial molar entropies of ions can, for example, be calculated assuming S (H+) = 0. Alternatively, because K+ and Cl ions are isoelectronic and have similar radii, the ionic properties of these ions in solution can be equated, e.g. analysis of B-viscosity coefficients (Gurney, 1953). In other cases, a particular theoretical treatment which relates solvation parameters to ionic radii indicates how the subdivision could be made. For example, the Bom equation requires that AGf (ion) be proportional to the reciprocal of the ionic radius (Friedman and Krishnan, 1973b). However, this approach involves new problems associated with the definition of ionic radius (Stem and Amis, 1959). In another approach to this problem, the properties of a series of salts in solution are plotted in such a way that the value for a common ion is obtained as the intercept. For example, when the partial molar volumes of some alkylammonium iodides, V (R4N+I ) in water (Millero, 1971) are plotted against the relative molecular mass of the cation, M+, the intercept at M + = 0 is equated to Ve (I-) (Conway et al., 1966). This procedure has been used to... 

By Newton s definition the viscosity or, more appropriately, the viscosity coefficient, jj, of a fluid in a laminar steady-state flow is expressed as the tangential force, F, per unit area. A, required to maintain a unit rate of shear (or velocity gradient), G, in the liquid. If the liquid fills the space between two parallel planes of area. A, one of which moves at a constant distance, r, from the other with a relative velocity, u, then we have... 

The first and the most easily understood definition was given by Newton as simply the resistance to flow. Newton showed that the shearing stress necessary to cause flow was proportional to the flow rate, with a constant of proportionality called the viscosity coefficient, given the symbol rj ... 

Figure 2. Definition of the shear viscosity coefficients 7)1, 7)2, and 773. The outer pair of arrows symbolizes the shear flow.

Viscosity coefficients measured in these geometries when n is immobilised by boMiesowicz viscosities. (Note, that in the literature a variety of alternative notations are common in particular the definitions of r i and r 2 are frequently interchanged.) If the orientation of n is fixed in an arbitrary direction with respect to v and Vv, then the effective viscosity coefficient is given by a linear combination of the Miesowicz viscosities, and another viscosity constant Tju, which cannot be visualised in a pure shear-flow ... 

This definition is in terms of a pool of liquid of depth h, where z is distance normal to the surface and ti and k are the liquid viscosity and thermal diffusivity, respectively [58]. (Thermal diffusivity is defined as the coefficient of thermal conductivity divided by density and by heat capacity per unit mass.) The critical Ma value for a system to show Marangoni instability is around 50-100. 

For example, the definition of a system as 10.0 g FI2O at 10.0°C at an applied pressure p= 1.00 atm is sufficient to specify that the water is liquid and that its other properties (energy, density, refractive index, even non-thennodynamic properties like the coefficients of viscosity and themial condnctivify) are uniquely fixed. 

Most distillation systems ia commercial columns have Murphree plate efficiencies of 70% or higher. Lower efficiencies are found under system conditions of a high slope of the equiHbrium curve (Fig. lb), of high Hquid viscosity, and of large molecules having characteristically low diffusion coefficients. FiaaHy, most experimental efficiencies have been for biaary systems where by definition the efficiency of one component is equal to that of the other component. For multicomponent systems it is possible for each component to have a different efficiency. Practice has been to use a pseudo-biaary approach involving the two key components. However, a theory for multicomponent efficiency prediction has been developed (66,67) and is amenable to computational analysis. 

The value of tire heat transfer coefficient of die gas is dependent on die rate of flow of the gas, and on whether the gas is in streamline or turbulent flow. This factor depends on the flow rate of tire gas and on physical properties of the gas, namely the density and viscosity. In the application of models of chemical reactors in which gas-solid reactions are caiTied out, it is useful to define a dimensionless number criterion which can be used to determine the state of flow of the gas no matter what the physical dimensions of the reactor and its solid content. Such a criterion which is used is the Reynolds number of the gas. For example, the characteristic length in tire definition of this number when a gas is flowing along a mbe is the diameter of the tube. The value of the Reynolds number when the gas is in streamline, or linear flow, is less than about 2000, and above this number the gas is in mrbulent flow. For the flow... 

The coefficient of viscosity was introduced in Chapter 2, Section 2.3a, but this parameter is elusive enough to warrant further comment. In this section we examine the definition of the coefficient of viscosity—the viscosity, for short —of a fluid. This definition leads directly to a discussion of some experimental techniques for measuring viscosity these are discussed in the following sections. 

Definition of terms a = diameter of inlet, A = electrode area, b = channel height, C = concentration (mM), F = Faraday constant, D = diffusion coefficient, v = kinematic viscosity, r = radius of tubular electrode, U = average volume flow rate, u = velocity (cm/s), n = number of electrons. Source Adapted from Ref. 84. 

MODES OF DEFORMATION AND DEFINITION OF VISCOSITY AND NORMAL STRESS COEFFICIENTS... 

From Eqs. (15.61) and (15.62) it follows that the shear stress and the first normal stress difference gradually increase from 0 to the steady state value. In this respect sometimes the following definitions are suggested for the transient values of viscosity and first normal stress coefficient... 

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