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Van der Waals forces, hydrogen

This involves deposition of the catalyst on the accessible surface of the support. The complex is held on the surface by rather weak interactions, such as van der Waals forces, hydrogen bonding, or a donating bond. The stability of the complex on the surface is determined by its solubility in the reaction solvent and/or the complexation of reagents and products. [Pg.151]

To design more effective medicines, chemists need to consider the structure of compounds that are active for a particular receptor or active site and to determine the Important functional groups present in these compounds. These functional groups allow the compound to interact with the active site. These Interactions can be any van der Waals forces (hydrogen, permanent dipole-permanent dipole interactions, London dispersion forces) and even ionic bonds. [Pg.80]

The relationship between odour quality and chemical structure is of considerable practical and theoretical interest. A numt r of methods have been used to determine quantitatively the relationships between the structure of a molecule and its odour quality (7). Though quantitative results were not obtained, a number of interesting theories were present in that the intermolecular interaction in olfaction involved electrostatic attraction, hydrophobic bonding, van der Waals forces, hydrogen bonding, and dipole-dipole interactions. Hydrophobic interactions also appeared to be a major force for substrate binding in olfaction. It had previously been shown that lipophilicity and water solubility were factors diat significandy influenced the odour thresholds of the pyrazines (8),... [Pg.101]

The strength of a hydrogen bond will depend upon the electronegativities of the donor and acceptor atoms. Because they tend to be stronger than van der Waals forces, hydrogen... [Pg.29]

In addition to the peptide bonds between individual amino acid residues, the three-dimensional structure of a protein is maintained by a combination of noncovalent interactions (electrostatic forces, van der Waals forces, hydrogen bonds, hydrophobic forces) and covalent interactions (disulfide bonds). [Pg.27]

Release of high-energy water Release of conformational strain Van der Waals forces Hydrogen bonding London dispersion forces Dipole-dipole interaction... [Pg.842]

Another AFM-based technique is chemical force microscopy (CFM) (Friedsam et al. 2004 Noy et al. 2003 Ortiz and Hadziioaimou 1999), where the AFM tip is functionalized with specific chemicals of interest, such as proteins or other food biopolymers, and can be used to probe the intermolecular interactions between food components. CFM combines chemical discrimination with the high spatial resolution of AFM by exploiting the forces between chemically derivatized AFM tips and the surface. The key interactions involved in food components include fundamental interactions such as van der Waals force, hydrogen bonding, electrostatic force, and elastic force arising from conformation entropy, and so on. (Dther interactions such as chemical bonding, depletion potential, capillary force, hydration force, hydrophobic/ hydrophobic force and osmotic pressure will also participate to affect the physical properties and phase behaviors of multicomponent food systems. Direct measurements of these inter- and intramolecular forces are of great interest because such forces dominate the behavior of different food systems. [Pg.131]

Some care in defining terms is required. On an atomic level all ionic and molecular interaction can be Interpreted as "electric . However, on the colloidal, or mesoscopic, level we may restrict the term "electric" to "Coulomblc". Consequently, all other interactions are by definition "non-electric", whatever their origin the three types of Van der Waals forces, hydrogen bonding, solvent structure-orl nated or real chemical bond formation. [Pg.247]

Adsorption could generally be classified as physical adsorption and chemical adsorption. Forces involved in adsorption include van der Waals force, hydrogen bonding or electrostatic force in physical adsorption, and covalent chemical bonds in chemical adsorption. Adsorption could occur between solid and solid, solid and liquid, or solid and gas. In pharmaceutical development, these adsorptions could take place during different processing stages, and affect the properties of the final products. There are cons and pros of these adsorptions, which will be discussed in this article. [Pg.34]

Increased temperatures can disrupt the strong solute-matrix interactions caused by van der Waals forces, hydrogen bonding, and dipole attractions of the solute molecules and active sites on the matrix. [Pg.130]


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