High-energy waters

The expulsion of high-energy waters which were found in the empty cyclodextrins (4b, 35). 

Water molecules in cyclodextrin s cavity (H dw + 2//H bond = —16 kcal mol-1) comprise high-energy water, as suggested by Hingerty and Saenger (9), compared with those in the liquid phase (2 A/f p = —20.92 kcal mol-1). 

Ch.H. Grant, USP 3307986(1967) CA 66, 117567u (1967) [High-energy water-resistant AN-alkali metal nitrate expls contg A1 of particular size distribution and processes for their production were described. A 1000-lb batch of expl was prepd as follows ... 

Release of high-energy water Release of conformational strain Van der Waals forces Hydrogen bonding London dispersion forces Dipole-dipole interaction... 

It is evident that there is ample evidence to support the view that the initial stage of water vapour adsorption is dependent on the presence of a number of polar sites on the carbon surface. In the theory of Dubinin and Seipinski (1981), these sites are pictured as primary adsorption centres of uniformly high energy. Water molecules are first adsorbed on the primary centres in a 1 1 ratio and these molecules then act as secondary adsorption centres for the adsorption (by H-bonding) of other molecules. 

Coasts pounded by high-energy water endure powerful waves and frequent storms. The coasts of the eastern United States and Canada, as well as the southern tips of South America and South Africa, are high-energy areas. Low-energy coasts, where few big waves and storms appear, are often in protected locations such as gulfs. 

Sponges occur in a variety of forms. In the intertidal zone, their shapes are often dictated by the conditions in which they live. Sponges in high-energy water, where the wave action is strong, may be thin and flat. Those in quieter water may grow into vase or finger shapes. 

The distribution of energies of water molecules is shown in Figure 3 (presumably trapped) high-energy waters that occured in an earlier Monte Carlo simulation (7) and molecular dynamics study... 

Relief of high-energy water from the CD cavity... 

Beuming, T., Farid, R., and Sherman, W. (2009) High-energy water sites... 

The different interactions between different chemical species (molecules, ions, and radicals) do not involve covalent bonds (Charoenchaitrakool et al., 2002). The driving forces between hosts and guests, which have been proposed to justify the complex formation are hydrogen bonds, van der Waals forces, hydrophobic interactions, and the release of high energy water molecules from the cavity (Cabral Marques, 1994b Sun et al., 2006). 

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