Tungsten silicon carbides

Chrome—nickel alloy heating elements that commonly ate used in low temperature furnaces are not suitable above the very low end of the range. Elements commonly used as resistors are either silicon carbide, carbon, or high temperature metals, eg, molybdenum and tungsten. The latter impose stringent limitations on the atmosphere that must be maintained around the heating elements to prevent rapid element failure (3), or the furnace should be designed to allow easy, periodic replacement. 

Seal Face Combinations The dynamic of seal faces is better understood today. Seal-face combinations have come a long way in the past 8-10 years. Stellite is being phased out of the petroleum and petrochemical applications. Better grades of ceramic are available, cost of tungsten has come down, and relapping of tungsten are available near most industrial areas. Silicon carbide is being used in abrasive service. 

Also noted is the rapid expansion of a number of materials produced by CVD, which include copper, tungsten, diamond, silicon carbide, silicon nitride, titanium nitride, and others. The coverage of the chemistry and deposition techniques of these materials has been greatly expanded. 

Two fibers are presently produced by CVD on a commercial scale boron and silicon carbide. The production of these two fibers requires a monofilament starter core capable of being heated resistively such as a tungsten or graphite fiber. I l The deposition apparatus is shown schematically in Fig. 19.1. 

Beryllium oxide Zirconium oxide Aluminum nitride Boron carbide Silicon carbide and nitride Tungsten carbide Beryllium carbide... 

As noted above, the range of fibers employed does not precisely overlap with those employed for organic composites. Because the formation of the MMCs generally requires melting of the metal-matrix, the fibers need to have some stability to relatively high temperatures. Such fibers include graphite, silicon carbide, boron, alumina-silica, and alumina fibers. Most of these are available as continuous and discontinuous fibers. It also includes a number of thin metal wires made from tungsten, titanium, molybdenum, and beryllium. 

More reasonable choices include silicon carbide and alumina. In addition, our intuition tells us that similar materials like silicon nitride and tungsten carbide may fit into this category, even though they are not specifically listed in the chart. 

Whiskers (nonoxides) (aluminum nitride, boron carbide, silicon carbide, silicon nitride, tungsten carbide, beryllium carbide)... 

CARBIDES. A binary solid compound of carbon and another element. The most familiar carbides are those of calcium, tungsten, silicon, boron, and iron (cemcntitc) Two factors have an important bearing on the properties of carbides (1) the difference in electronegativity between carbon and the second elemenl. and (2) whether the second element is a transition metal. Saltlike carbides of alkali metals are obtained by reaction with acetylene. Those ohlained from silver, copper, and mercury sails are explosive. See also Carbon and Iron Metals, Alloys, and Steels. 

A Very practical application of infrared radiation is found in radiant heating. Solid radiators, such as hot tungsten filaments, alloy wires, and silicon carbide rods arc used widely as sources of infrared to provide surface healing by radiation. Commercially available infrared lamps are extensively used in specially designed ovens for drying painted and enameled surfaces. 

A variety of other ceramics are prepared by pyrolysis of preceramic polymers.32,38 Some examples are silicon carbide, SC, tungsten carbide, WC, aluminum nitride, AIN, and titanium nitride, TiN. In some cases, these materials are obtained by simple pyrolysis in an inert atmosphere or under vacuum. In other cases a reactive atmosphere such as ammonia is needed to introduce some of the atoms required in the final product. Additional details are given in Chapter 9. 

Although few applications have so far been found for ceramic matrix composites, they have shown considerable promise for certain military applications, especially in the manufacture of armor for personnel protection and military vehicles. Historically, monolithic ("pure") ceramics such as aluminum oxide (Al203), boron carbide (B4C), silicon carbide (SiC), tungsten carbide (WC), and titanium diboride (TiB2) have been used as basic components of armor systems. Research has now shown that embedding some type of reinforcement, such as silicon boride (SiBg) or silicon carbide (SiC), can improve the mechanical properties of any of these ceramics. 

---