Tungsten rhenium

Thermal Conductivity Detector One of the earliest gas chromatography detectors, which is still widely used, is based on the mobile phase s thermal conductivity (Figure 12.21). As the mobile phase exits the column, it passes over a tungsten-rhenium wire filament. The filament s electrical resistance depends on its temperature, which, in turn, depends on the thermal conductivity of the mobile phase. Because of its high thermal conductivity, helium is the mobile phase of choice when using a thermal conductivity detector (TCD). 

Since detailed chemical structure information is not usually required from isotope ratio measurements, it is possible to vaporize samples by simply pyrolyzing them. For this purpose, the sample can be placed on a tungsten, rhenium, or platinum wire and heated strongly in vacuum by passing an electric current through the wire. This is thermal or surface ionization (TI). Alternatively, a small electric furnace can be used when removal of solvent from a dilute solution is desirable before vaporization of residual solute. Again, a wide variety of mass analyzers can be used to measure m/z values of atomic ions and their relative abundances. 

Molybdenum hexafluoride is used in the manufacture of thin films (qv) for large-scale integrated circuits (qv) commonly known as LSIC systems (3,4), in the manufacture of metallised ceramics (see MetaL-MATRIX COMPOSITES) (5), and chemical vapor deposition of molybdenum and molybdenum—tungsten alloys (see Molybdenumand molybdenum alloys) (6,7). The latter process involves the reduction of gaseous metal fluorides by hydrogen at elevated temperatures to produce metals or their alloys such as molybdenum—tungsten, molybdenum—tungsten—rhenium, or molybdenum—rhenium alloys. 

Rhenium hexafluoride is a cosdy (ca 3000/kg) material and is often used as a small percentage composite with tungsten or molybdenum. The addition of rhenium to tungsten metal improves the ductility and high temperature properties of metal films or parts (11). Tungsten—rhenium alloys produced by CVD processes exhibit higher superconducting transition temperatures than those alloys produced by arc-melt processes (12). 

Tungsten with the addition of as much as 5% thoria is used for thermionic emission cathode wires and as filaments for vibration-resistant incandescent lamps. Tungsten—rhenium alloys are employed as heating elements and thermocouples. Tantalum and niobium form continuous soHd solutions with tungsten. Iron and nickel are used as ahoy agents for specialized appHcations. 

ASTM E988-96. Standard Temperature-Electromotive Force (FMF) Tables for Tungsten-Rhenium Thermocouples. American Society for Testing and Materials, 1996. 

Cesium Barium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth FJonhun Astatine Radon... 

Field emission microscopy was the first technique capable of imaging surfaces at resolution close to atomic dimensions. The pioneer in this area was E.W. Muller, who published the field emission microscope in 1936 and later the field ion microscope in 1951 [23]. Both techniques are limited to sharp tips of high melting metals (tungsten, rhenium, rhodium, iridium, and platinum), but have been extremely useful in exploring and understanding the properties of metal surfaces. We mention the structure of clean metal surfaces, defects, order/disorder phenomena,... 

Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium... 

The work cited in sections 2.4 and 2.5 is representative of the SN1 substitution reactions of metal carbonyls. However, a much more extensive and detailed account has recently been published covering similar reactions of vanadium, chromium, molybdenum, tungsten, rhenium, iron and nickel carbonyls in addition to those of manganese and cobalt2 9a. 

Klotzbiicher WE, Ozin GA (1980) Optical spectra of hafnium, tungsten, rhenium and mthenium atoms and other heavy transition-metal atoms and small clusters (Zrl, 2, Pdl, 2, Aul, 2, 3) in noble-gas matrixes. Inorg Chem 19 3767-3776... 

Cerium, Titanium, Cobalt, Vanadium, Tungsten, Rhenium, Palladium,... 

B. Mononuclear Compounds of Iron, Molybdenum, Tungsten, Rhenium, Platinum, Nickel and Cobalt... 

Cesium Barium Lanthanum Hafnium Tantaium Tungsten Rhenium Osmium iridium... 

Two different kinds of metals are found in chondrites. Small nuggets composed of highly refractory siderophile elements (iridium, osmium, ruthenium, molybdenum, tungsten, rhenium) occur within CAIs. These refractory alloys are predicted to condense at temperatures above 1600 from a gas of solar composition. Except for tungsten, they are also the expected residues of CAI oxidation. 

Other materials may be used in addition to those shown in Figure 4. For example Chromel-Constantan is excellent for temperatures up to 2000°F Nickel/Nickel-Molybdenum sometimes replaces Chromel-Alumel and Tungsten-Rhenium is used for temperatures up to 5000°F. Some combinations used for specialized applications are Chromel-White Gold, Molybdenum-Tungsten, Tungsten-Iridium, and Iridium/Iridium-Rhodium. 

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