Thinning stretching

In the body of a liquid, intermolecular forces pull the molecules in all directions. At the surface of the liquid, the molecules pull down into the body of the liquid and from the sides. There are no molecules above the surface to pull in that direction. The effect of this unequal attraction is that the liquid tries to minimize its surface area. The minimum surface area for a given quantity of matter is a sphere. In a large pool of liquid, where sphere formation is not possible, the surface behaves as if it had a thin stretched elastic membrane or skin over it. The surface tension is the resistance of a liquid to an increase in its surface area. It requires force to break the attractive forces at the surface. The greater the intermolecular force, the greater the surface tension. Polar liquids, especially those that utilize hydrogen bonding, have a much higher surface tension than nonpolar liquids. 

The adoption of a wait and see approach to avoid formalizing the problem means the immediate problem of the mother s incapacity has to be dealt with informally and within the resources of the staff present. In a busy clinic such resources might be thinly stretched which, as the following drug worker acknowledged, could mean it was not addressed ... 

Stretched weld. Wil break at thin stretched points. 

Some of the earliest observations on the effect of stress upon crystallization were made by Andrews upon thin stretched films of natural rubber. It was found that crystals formed transverse to the direction of the applied stress as shown in Fig. 4.22(a) for isotactic polystyrene. The... 

In the case of solids, there is no doubt that a lateral tension (which may be anisotropic) can exist between molecules on the surface and can be related to actual stretching or compression of the surface region. This is possible because of the immobility of solid surfaces. Similarly, with thin soap films, whose thickness can be as little as 100 A, stretching or extension of the film may involve a corresponding variation in intermolecular distances and an actual tension between molecules. 

As a point of interest, it is possible to form very thin films or membranes in water, that is, to have the water-film-water system. Thus a solution of lipid can be stretched on an underwater wire frame and, on thinning, the film goes through a succession of interference colors and may end up as a black film of 60-90 A thickness [109]. The situation is reminiscent of soap films in air (see Section XIV-9) it also represents a potentially important modeling of biological membranes. A theoretical model has been discussed by Good [110]. 

One important application of amperometry is in the construction of chemical sensors. One of the first amperometric sensors to be developed was for dissolved O2 in blood, which was developed in 1956 by L. C. Clark. The design of the amperometric sensor is shown in Figure 11.38 and is similar to potentiometric membrane electrodes. A gas-permeable membrane is stretched across the end of the sensor and is separated from the working and counter electrodes by a thin solution of KCl. The working electrode is a Pt disk cathode, and an Ag ring anode is the... 

Both high bulk and surface shear viscosity delay film thinning and stretching deformations that precede bubble bursting. The development of ordered stmctures in the surface region can also have a stabilizing effect. Liquid crystalline phases in foam films enhance stabiUty (18). In water-surfactant-fatty alcohol systems the alcohol components may serve as a foam stabilizer or a foam breaker depending on concentration (18). 

In addition to electrical uses, epoxy casting resins are utilized in the manufacture of tools, ie, contact and match molds, stretch blocks, vacuum-forrning tools, and foundry patterns, as weU as bench tops and kitchen sinks. Systems consist of a gel-coat formulation designed to form a thin coating over the pattern which provides a perfect reproduction of the pattern detail. This is backed by a heavily filled epoxy system which also incorporates fiber reinforcements to give the tool its strength. For moderate temperature service, a Hquid bisphenol A epoxy resin with an aHphatic amine is used. For higher temperature service, a modified system based on an epoxy phenol novolak and an aromatic diamine hardener may be used. 

String instruments all work on the same basic principle. A thin string, of gut or metal, is stretched tightly between two rigid supports. If the string is plucked, or hit, or bowed, it will go into sideways vibrations of precisely defined frequency which can... 

The DNA molecules in each cell of an organism contain all the genetic information necessary to ensure the normal development and function of that organism. This genetic information is encoded in the precise linear sequence of the nucleotide bases from which the DNA is built. DNA is a linear molecule while its diameter is only about 20 A, if stretched out its length can reach many millimeters. This means that concentrated solutions of DNA can be pulled into fibers in which the long thin DNA molecules are oriented with their long axes parallel. 

FIGURE 17.21 A drawing of the arrangement of the elastic protein titin in the skeletal mnscle sarcomere. Titin filaments originate at the periphery of the M band and extend along the myosin filaments to the Z lines. These titin filaments produce the passive tension existing in myofibrils that have been stretched so that the thick and thin filaments no longer overlap and cannot interact. (Adapted from Ohtsuki, ., Maruyama, K, and Ebashi,. S ., 1986. Advances ia Protein Chemisti y 38 1—67.)... 

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