The Report Window

Reports are used to display numerical or text information, typically the result of an evaluation or the parameters associated with a spectrum, hiformation of this type is stored in report blocks double-clicking on a report block (exception peak tables) will automatically open a report window. A blank report window can be opened from the Window menu (see Chapter 9). As an example, the report of the peak picking data for the Raman spectrum of n-docosane is shown in Fig. 3.17. 

The information contained in the report block is displayed in the form of a tree on the left side of the report window. Highlight an item of the tree to display its data if you click on the column title you can sort the data according to this column. If the block also contains a header, this information will be displayed in an extra window. The report window also has a Properties dialog box associated see Fig. 3.18. Open this box by right-clicking on the displayed data of the report window. Furthermore, you can set the font and font size used for a printout of the report in the Font dialog box. Fig. 3.19, accessible by clicking on Printer Font. 

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By using the Solve option from the LINGO menu, we get the following results displayed on the Reports window ... 

Blank report windows can be opened using this command. OPUS uses report windows to display information other than spectra or interferograms. For example, the results of a peak pick operation a ipeak pick data block to the report window. 

The report window shown in Fig. 11.31 consists of four areas, which can be adjusted in size by moving the window bars. The list at the bottom of the window contains all spectra matching the search criteria. In the first column, the hits are... 

Display the query spectrum by clicking on the Show Query Spectrum button. Close the report window by clicking on Exit. 

Two types of reports can be viewed or printed from the PLAN feature a Summary Report and a Detailed Report. The package of Fact Sheets for the selected strategies in the active plan can also be printed. The reports are accessed by highlighting the desired plan and clicking on the buttons entitled Summary Report, Detailed Report and Fact Sheet Package (located to the left of the list of plans). The content of these reports (described below) can be directly printed to a printer or exported to Microsoft Excel, Microsoft Word or Adobe PDF using the toolbar at the top of the report window. 

SpartanBuild reports strain energies m kilocalories per mole (1 kcal/mol = 4 184 kJ/mol) m the lower left hand corner of the SpartanBuild window... 

From the LINGO menu, choose solve. LINGO will display a LINGO Solver Status window and a Reports window that shows the following solution to the previous program ... 

Print Preview - shows the report in the Report Viewer window. 

A Q-switched Nd YAG laser (7 ns pulse duration, Quanta-Ray DRC-1A) operated at 10 Hz was used as a light source. The 1064 nm fundamental was frequency doubled to 532 nm for some experiments. In all experiments reported here a geometry was used which focused the laser beam in front of the entrance window of the sample cell such that the laser beam was diverging as it passed through the sample cell. In this geometry the laser beam was about 3 mm in diameter at the region viewed by the light detection system. 

Within the potential range where Ru(bpy)3 remains in the aqueous phase, photocurrent responses are clearly observed with a slow rising time of the order of 10 s as shown in Fig. 14(a). According to the convention employed by these authors, positive currents correspond to the transfer of a negative charge from water to DCE. No photoresponses were observed in the absence of either the dye in the aqueous phase or TCNQ in DCE. Further analysis of the interfacial behavior of the product TCNQ revealed that the ion transfer occurred outside of the polarizable window [cf. Fig. 14(d)], confirming that these photoresponses are not affected by coupled ion-transfer processes. An earlier report also showed photoeffects for the photoreduction of the viologen under similar conditions [131]. 

The value of EM for a cooperative self-assembled structure provides a measure of the monomer concentration at which trivial polymeric structures start to compete, and therefore EM represents the upper limit of the concentration range within which the cooperative structure is stable (Scheme 2). The lower limit of this range is called the critical self-assembly concentration (csac) and is determined by the stoichiometry of the assembly and the strength of the non-covalent binding interactions weaker interactions and larger numbers of components raise the csac and narrow the stability window of the assembly (8). Theoretical treatments of the thermodynamics of the self-assembly process have been reported by Hunter (8), Sanders (9), and Mandolini (10). The value of EM is lowered by enthalpic contributions associated with... 

I had no hope, yet hope would not die. How could I hope, when all reports told of my boys servants dismissed How could I believe they lived, when the word was they were not seen even at the Tower windows seeking a breeze that might thin the stench of London s heat How could I not believe them dead, who had known what the sons of York had done to Henry of Lancaster, or... 

The electrochemical cell used in our laboratory has been fully described elsewhere (5). The cell body is made of chemically inert Kel-F and the electrode is mounted on a piston so that its surface can be pushed to the optical window, to a spacing of the order of 1-3 microns, in order to minimize the signal from the bulk electrolyte. For Raman scattering spectroscopy the window is of flat fused quartz, and the exciting laser beam is incident at about 60°. The scattered light is collected off-normal, but the geometry is not critical for SERS due to the high sensitivity. Details on the SERS measurements in our laboratory have been reported previously (6,7). 

In the frequency region where the i/(0H) vibrations of interfacial H20 are observed, the normal Raman scattering from the bulk solution can obscure the SERS of interfacial H20 if appropriate precautions are not taken. In the studies reported here, the SERS of interfacial H20 was acquired with the electrode surface positioned as close to the electrochemical cell window as possible to minimize contributions from the bulk solution. When altering the electrode potential to deposit Pb onto the Ag electrode surface, the electrode was pulled away from the window several mm, the surface allowed to equilibrate at the new conditions, and the electrode repositioned near the cell window for spectral acquisition. 

Chemical reactivity of unfunctionalized organosilicon compounds, the tetraalkylsilanes, are generally very low. There has been virtually no method for the selective transformation of unfunctionalized tetraalkylsilanes into other compounds under mild conditions. The electrochemical reactivity of tetraalkylsilanes is also very low. Kochi et al. have reported the oxidation potentials of tetraalkyl group-14-metal compounds determined by cyclic voltammetry [2]. The oxidation potential (Ep) increases in the order of Pb < Sn < Ge < Si as shown in Table 1. The order of the oxidation potential is the same as that of the ionization potentials and the steric effect of the alkyl group is very small. Therefore, the electron transfer is suggested as proceeding by an outer-sphere process. However, it seems to be difficult to oxidize tetraalkylsilanes electro-chemically in a practical sense because the oxidation potentials are outside the electrochemical windows of the usual supporting electrolyte/solvent systems (>2.5 V). 

The Butler-Volmer rate law has been used to characterize the kinetics of a considerable number of electrode electron transfers in the framework of various electrochemical techniques. Three figures are usually reported the standard (formal) potential, the standard rate constant, and the transfer coefficient. As discussed earlier, neglecting the transfer coefficient variation with electrode potential at a given scan rate is not too serious a problem, provided that it is borne in mind that the value thus obtained might vary when going to a different scan rate in cyclic voltammetry or, more generally, when the time-window parameter of the method is varied. 

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