Tensile fiber

Collagens are quantitatively the most abundant of animal proteins, representing 25% of the total. They form insoluble tensile fibers that occur as structural elements of the extracellular matrix and connective tissue throughout the body. Their name (which literally means glue-producers ) is derived from the gelatins that appear as a decomposition product when collagen is boiled. 

Fiber tensile Fiber tensile Bulk polymer Bulk poljuner... 

At RT, thermal conductivities of carbon fiber composites with high tensile fibers differ from those of high modulus fibers and are much higher than the thermal conductivity of the epoxy matrix. Below 7 K, they become similar within 25% and lower than the thermal conductivity of the epoxy matrix (37,47). The similarity is owing to the fact that at low temperatures only long phonon wavelengths are activated they cannot resolve different graphite microstructures of different carbon fiber types which are dominant at RT (36,43). In most cases, the specific heat of composites is lower than that of the polymeric matrix. 

Glass-fiber-reinforced (increased stiffness and tensile strength) and mineral filled (reduced shrink and warp) grades also have been developed. 

Normalised fiber mechanical properties are expressed in terms of unit linear density. For example, in describing the action of a load on a fiber in a tensile test, units of N/tex or gram force per denier (gpd) are generally used. If this is done, the term tenacity should be used in place of stress. The tme units of stress are force per unit cross-sectional area, and the term stress should be reserved for those instances where the proper units are used. 

Mitsubishi Rayon Co. has developed an acrylic asbestos replacement fiber with a tensile strength of almost 600 MPa (87,000 psi) (78,79). In addition, patents for acrylic asbestos replacement fibers have been obtained by Asahi (80), Wuestefeld (81), REDCO (82), and Hoechst (83). The Hoechst fiber, marketed under the trade name Dolanit (originally Dolan 10), is offered in two forms as shown in Table 4. 

Acetate and triacetate exhibit moderate changes in mechanical properties as a function of temperature. As the temperature is raised, the tensile modulus of acetate and triacetate fibers is reduced, and the fibers extend more readily under stress (see Fig. 4). Acetate and triacetate are weakened by prolonged exposure to elevated temperatures in ah (see Fig. 5). 

Other elastomeric-type fibers iaclude the biconstituents, which usually combine a polyamide or polyester with a segmented polyurethane-based fiber. These two constituents ate melt-extmded simultaneously through the same spinneret hole and may be arranged either side by side or ia an eccentric sheath—cote configuration. As these fibers ate drawn, a differential shrinkage of the two components develops to produce a hehcal fiber configuration with elastic properties. An appHed tensile force pulls out the helix and is resisted by the elastomeric component. Kanebo Ltd. has iatroduced a nylon—spandex sheath—cote biconstituent fiber for hosiery with the trade name Sidetia (6). 

In the late 1980s, new fully aromatic polyester fibers were iatroduced for use ia composites and stmctural materials (18,19). In general, these materials are thermotropic Hquid crystal polymers that are melt-processible to give fibers with tensile properties and temperature resistance considerably higher than conventional polyester textile fibers. Vectran (Hoechst-Celanese and Kuraray) is a thermotropic Hquid crystal aromatic copolyester fiber composed of -hydroxyben2oic acid [99-96-7] and 6-hydroxy-2-naphthoic acid. Other fully aromatic polyester fiber composites have been iatroduced under various tradenames (19). 

In conventional tenter orientation, the sequence of steps is as described above (MD—TD). In some cases it is advantageous to reverse the draw order (TD—MD) or to use multiple draw steps, eg, MD—TD—MD. These other techniques are used to produce "tensilized" films, where the MD tensile properties are enhanced by further stretching. The films are generally unbalanced in properties and in extreme cases may be fibrillated to give fiber-like elements for special textile appHcations. Tensilized poly(ethylene terephthalate) is a common substrate for audio and video magnetic tape and thermal transfer tape. 

High performance fibers are generally characterized by remarkable unit tensile strength and resistance to heat, flame, and chemical agents that normally degrade conventional fibers. Applications include uses in the aerospace, biomedical, civil engineering, constmction, protective apparel, geotextiles, and electronic areas. 

The copolymer fiber shows a high degree of drawabiUty. The spun fibers of the copolymer were highly drawn over a wide range of conditions to produce fibers with tensile properties comparable to PPT fibers spun from Hquid crystalline dopes. There is a strong correlation between draw ratio and tenacity. Typical tenacity and tensile modulus values of 2.2 N/tex (25 gf/den) and 50 N/tex (570 gf/den), respectively, have been reported for Technora fiber (8). 

Table 13 is a representative Hst of nickel and cobalt-base eutectics for which mechanical properties data are available. In most eutectics the matrix phase is ductile and the reinforcement is britde or semibritde, but this is not invariably so. The strongest of the aHoys Hsted in Table 13 exhibit ultimate tensile strengths of 1300—1550 MPa. Appreciable ductiHty can be attained in many fibrous eutectics even when the fibers themselves are quite britde. However, some lamellar eutectics, notably y/y —5, reveal Htde plastic deformation prior to fracture. 

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