Surface corona discharge

Articles fabricated from FEP resins can be made bondable by surface treatment with a solution of sodium in Hquid ammonia, or naphthalenyl sodium in tetrahydrofuran (64) to faciUtate subsequent wetting. Exposing the surface to corona discharge (65) or amines at elevated temperatures in an oxidizing atmosphere (66) also makes the resins bondable. Some of the more recent work is described in References 67—69. 

PBDs may occur on plastic surfaces with no metal substrate, for example the wall of a plastic pipe conveying charged material, in this case the double layer forms between the inner charged wall of the pipe and a countercharge which accumulates on the outer wall via conduction or via corona discharge. in the latter case both layers of charge reside on nonconductive sur-... 

Corona discharge treatment results in the formation of high-polarity functional groups, such as carbonyl, at the polymer surface. Various mechanisms have been proposed for the improvement of the adhesive properties... 

Several environment-friendly surface preparation for the treatment of mbber soles with radiations have been recently studied. These treatments are clean (no chemicals or reactions by-products are produced) and fast, and furthermore online bonding at shoe factory can be produced, so the future trend in surface modification of substrates in shoe industry will be likely directed to the industrial application of those treatments. Corona discharge, low-pressure RF gas plasma, and ultraviolet (UV) treatments have been successfully used at laboratory scale to improve the adhesion of several sole materials in shoe industry. Recently, surface modification of SBR and TR by UV radiation has been industrially demonstrated in shoe industry... 

Corona discharge has been successfully used to improve the adhesion of TRs to polyurethane adhesive. The treatment with corona discharge improves the wettability of TR due to the surface... 

Romero-Sanchez M.D., Pastor-Bias M.M., Martm-Martmez J.M., Zhdan P.A., and Watts J.M., 2001, Surface modifications in a vulcanized rubber using corona discharge and ultraviolet radiation treatments, J. Materials Sci., 36(24), 5789-5799. 

The corona discharges produces oxygen ions and ozone, which may react with the photoconductor [634], As a means to circumvent possible degradation of the surface layer, an extra, protective thin layer was proposed, with high carbon content [101, 635, 636]. This would reduce silicon-oxygen reactions at the surface. Excellent electrophotographic characteristics have been obtained with a thin device comprising a 0.1-/rm-thick n-type a-Si H layer, a 1.0-/rm intrinsic a-Si H layer, a 0.1-/irm undoped a-SiCo i H layer, and a 0.014-/xm undoped a-SiCoj H layer [101]. 

Corona discharge is the simplest type of plasma generator. A feature of the corona discharge, which differentiates it from the other discharges, is that no dielectric is involved. Instead, an electron avalanche is initiated from a sharp metallic surface where the radius of curvature is small. The electric field has to be pulsed in order to prevent the plasma from going into the thermal mode and forming an arc. The electric field in corona reactors is about 50 kV/cm. 

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