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Sulfonic acids carbohydrates

A. Hasegawa and H. G. Fletcher, Jr., The behavior of some aldoses with 2 -diinetboxypropane-N, A dimethylfonnamide-p-toluene-sulfonic acid, Carbohydr. Res. 29 209 (1973). [Pg.34]

Larger organic anions aromatic carboxylic acids, aromatic sulfonic acids, carbohydrates (aldoses, ketoses), nucleotides, nucleic acids, proteins. [Pg.101]

Larger organic anions aromatic carboxylic acids, aromatic sulfonic acids, carbohydrates (aldoses, ketoses), nucleotides, nucleic acids, proteins, surfactants.Polarizable anions include those listed in Group 2 ofthe table. These anions have a relatively high affinity for the ion-exchange stationary phase and therefore require a stronger eluent for their separation. [Pg.131]

Orthoesters. The value of cycHc orthoesters as intermediates for selective acylation of carbohydrates has been demonstrated (73). Treatment of sucrose with trimethylorthoacetate and DMF in the presence of toluene-/)-sulfonic acid followed by acid hydrolysis gave the 6-0-acetylsucrose as the major and the 4-0-acetylsucrose [63648-80-6] as the minor component. The latter compound underwent acetyl migration from C-4 to C-6 when treated with an organic base, such as / fZ-butylamine, in DMF to give sucrose 6-acetate in >90% yield (74). When the kinetic reagent 2,2-dimethoxyethene was used,... [Pg.34]

For the synthesis of carbohydrate-substituted block copolymers, it might be expected that the addition of acid to the polymerization reactions would result in a rate increase. Indeed, the ROMP of saccharide-modified monomers, when conducted in the presence of para-toluene sulfonic acid under emulsion conditions, successfully yielded block copolymers [52]. A key to the success of these reactions was the isolation of the initiated species, which resulted in its separation from the dissociated phosphine. The initiated ruthenium complex was isolated by starting the polymerization in acidic organic solution, from which the reactive species precipitated. The solvent was removed, and the reactive species was washed with additional degassed solvent. The polymerization was completed under emulsion conditions (in water and DTAB), and additional blocks were generated by the sequential addition of the different monomers. This method of polymerization was successful for both the mannose/galactose polymer and for the mannose polymer with the intervening diol sequence (Fig. 16A,B). [Pg.232]

By treating Nafion (NR-50), a perfluorinated acidic ion exchanger based on sulfonic acid groups, with scandium(III) chloride hexahydrate Kobayashi et al. generated a solid scandium-derived catalyst (29) (Nafion-Sc) that proved to be effective in al-lylation reactions of carbonyl compounds with tetraallyltin (Scheme 4.15). Since the catalyst is stable in both organic solvents and water, even unprotected carbohydrates could be transformed directly in aqueous solvents. The resulting homo-allylic alcohols were separated by simple filtration [97]. [Pg.219]

Hydrolysis can detoxify a wide range of aliphatic and aromatic organics such as esters, ethers, carbohydrates, sulfonic acids, halogen compounds, phosphates, and nitriles. It can be conducted in simple equipment (in batches in open tanks) or in more complicated equipment (continuous flow in large towers). However, a potential disadvantage is the possibility of forming undesirable reaction products. This possibility must be evaluated in bench- and pilot-scale tests before hydrolysis is implemented. [Pg.531]

Because carbohydrates are so frequently used as substrates in kinetic studies of enzymes and metabolic pathways, we refer the reader to the following topics in Ro-byt s excellent account of chemical reactions used to modify carbohydrates formation of carbohydrate esters, pp. 77-81 sulfonic acid esters, pp. 81-83 ethers [methyl, p. 83 trityl, pp. 83-84 benzyl, pp. 84-85 trialkyl silyl, p. 85] acetals and ketals, pp. 85-92 modifications at C-1 [reduction of aldehydes and ketones, pp. 92-93 reduction of thioacetals, p. 93 oxidation, pp. 93-94 chain elongation, pp. 94-98 chain length reduction, pp. 98-99 substitution at the reducing carbon atom, pp. 99-103 formation of gycosides, pp. 103-105 formation of glycosidic linkages between monosaccharide residues, 105-108] modifications at C-2, pp. 108-113 modifications at C-3, pp. 113-120 modifications at C-4, pp. 121-124 modifications at C-5, pp. 125-128 modifications at C-6 in hexopy-ranoses, pp. 128-134. [Pg.110]

Purification of food dyes can also be accomplished by means of anion-exchange resins. Theoretically, the anionic resin combines with sulfonic acid groups in the dye molecule to form a complex. Since food dyes may be adsorbed onto carbohydrates or chemically bound to proteins, the resin must have greater affinity for the color than to any of these adsorbents (156,161). Usually... [Pg.556]

Sulfonic acid esters of carbohydrates have been extensively studied. No attempt will be made to review the entire literature.s9a Only those investigations which make a significant contribution in illustrating the selective nature of sulfonylation as well as those in which the selective cleavage of sulfonic esters is concerned, will be considered. [Pg.24]

Potassium cyanide has been caused to react with salts and esters of sulfonic acids to give nitriles. Thus, an intimate mixture of finely powdered potassium cyanide with the compound may be fused 422 this method was successfully applied428 to tetrahydrofurfuryl p-toluenesul-fonate and methanesulfonate, but failed with l,2 3,4-di-0-isopropylidene-6-O-tosyl-D-galactose. Another method, consisting of treatment of the ester with a stirred, boiling, saturated, aqueous solution of potassium cyanide gave885 a 70 to 83% yield of nitrile with primary p-toluenesul-fonates (ethyl, n-butyl, and n-octyl) and a 43% yield with a secondary p-toluenesulfonate (isopropyl). Similar methods had been applied earlier98 841 to such simple esters, but have not apparently found use with sulfonic esters of carbohydrates. [Pg.212]

Electrochemical detectors measure the current resulting from the application of a potential (voltage) across electrodes in a flow cell. They respond to substances that are either oxidizable or reducible and may be used for the detection of compounds such as catecholamines, carboxylic acids, sulfonic acids, phosphonic acids, alcohols, glycols, aldehydes, carbohydrates, amines, and many other sulfur-containing species and inorganic anions and cations. Potentiometric, amperometric, and conductivity detectors are all classified as electrochemical detectors. [Pg.102]

SulfocUorination (similar to the photochemical reaction by UV), e.g. production of 10 sulfonic acid chlorides by irradiation of mixtures of carbohydrates, SO2 and CI2 Production of alkylsulfonic acids by irradiation of mixtures of carbohydrates, SO2 lO -lO ... [Pg.389]

Carbohydrate imidazolylsulfontUes (imidazylates) [36] are a type of sulfonic acid ester that deserves special cominent because these compounds react readily with nucleophiles in S 2 substitution processes. Althougb imidazylatra are not used as frequently as triflates in substitution reactions, th appear to be ocnnparaUe in reactivity (16) 37,38]. [Pg.55]

Saturation of a carbohydrate double bond is almost always carried out by catalytic hydrogenation over a noble metal. The reaction takes place at the surface of the metal catalyst that absorbs both hydrogen and the organic molecule. The metal is often deposited onto a support, typically charcoal. Palladium is by far the most commonly used metal for catalytic hydrogenation of olefins. In special cases, more active (and more expensive) platinum and rhodium catalysts can also be used [154]. All these noble metal catalysts are deactivated by sulfur, except when sulfur is in the highest oxidation state (sulfuric and sulfonic acids/esters). The lower oxidation state sulfur compounds are almost always catalytic poisons for the metal catalyst and even minute traces may inhibit the hydrogenation very strongly [154]. Sometimes Raney nickel can... [Pg.209]

Native and microcrystalline cellulose precoated plates are used in the life sciences for the separation of polar compounds (e.g. carbohydrates, carboxylic acids, amino acids, nucleic acid derivatives, phosphates, etc) [85]. These layers are unsuitable for the separation of compounds of low water solubility unless first modified, for example, by acetylation. Several chemically bonded layers have been described for the separation of enantiomers (section 10.5.3). Polyamide and polymeric ion-exchange resins are available in a low performance grade only for the preparation of laboratory-made layers [82]. Polyamide layers are useful for the reversed-phase separation and qualitative analysis of phenols, amino acid derivatives, heterocyclic nitrogen compounds, and carboxylic and sulfonic acids. Ion-exchange layers prepared from poly(ethyleneimine), functionalized poly(styrene-divinylbenzene) and diethylaminoethyl cellulose resins and powders and are used primarily for the separation of inorganic ions and biopolymers. [Pg.525]


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See also in sourсe #XX -- [ Pg.23 , Pg.238 ]




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