Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Sulfonates and Esters

SAFETY PROFILE Confirmed carcinogen with experimental carcinogenic, neoplastigenic, mmorigenic, and teratogenic data. Poison by ingestion and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also SULFONATES and ESTERS. [Pg.637]

Functional alkanes bearing a 2,3-dihydroxylated pattern are readily obtained, for example, aldehydes from l-acetoxy-2-alkenyl phenyl sulfones and esters from ketene acetals. ... [Pg.302]

Numerous other reactions of carbanions are efficiently executed in two-phase systems using concentrated aqueous NaOH and PT catalysts for deprotonation of the carbanion precursors. These conditions are particularly suitable for synthesis of oxiranes via condensation of aldehydes and ketones with carbanions of, e.g., ot-chloronitriles, sulfones, and esters of a-chlorocarboxylic acids, known as the Darzens reaction, or with sulfonium... [Pg.178]

The main use of normal phase chromatograph is in separation of classes of anionics from each other, rather than characterization of a single surfactant. For example, LAS, AOS, paraffin sulfonate, and ester sulfonate were separated from each other after formation of the methyl esters (12). Other sulfates and sulfonates were separated from each other without derivatization by using an ion pairing agent consisting of the crown ether complex of a metal salt (10). [Pg.196]

The mechanisms by which sulfonate esters undergo nucleophilic substitution are the same as those of alkyl halides Inversion of configuration is observed m 8 2 reac tions of alkyl sulfonates and predominant inversion accompanied by racemization m 8 1 processes... [Pg.353]

The process by which a solubility differential between exposed and unexposed areas occurs is well known (74). Photodegradation products of the naphthoquinone diazide sensitizer, eg, a l,2-naphthoquinonediazide-5-sulfonic acid ester (11), where Ar is an aryl group, to an indene carboxylic acid confers much increased solubility in aqueous alkaline developer solutions. [Pg.44]

In sulfamation, also termed A/-sulfonation, compounds of the general stmcture R2NSO2H are formed as well as their corresponding salts, acid hahdes, and esters. The reagents are sulfamic acid (amido—sulfuric acid), SO —pyridine complex, SO —tertiary amine complexes, ahphatic amine—SO. adducts, and chlorine isocyanate—SO complexes (3). [Pg.74]

Fig. 1. Sulfonated and sulfated acid products viscosities after 98% conversions at varying temperatures where the vertical line indicates the maximum temperature for batch sulfonation using SO to minimi2e color deterioration lines A—C represent branched C 2 alkyl ben2ene (BAB) sulfonic acid from SO, oleum (settied), and oleum (whole mixture), respectively lines D and E, lauryl alcohol 3-ethoxylate sulfuric ester (SO ) and lauryl alcohol sulfuric ester... Fig. 1. Sulfonated and sulfated acid products viscosities after 98% conversions at varying temperatures where the vertical line indicates the maximum temperature for batch sulfonation using SO to minimi2e color deterioration lines A—C represent branched C 2 alkyl ben2ene (BAB) sulfonic acid from SO, oleum (settied), and oleum (whole mixture), respectively lines D and E, lauryl alcohol 3-ethoxylate sulfuric ester (SO ) and lauryl alcohol sulfuric ester...
General Reaction Chemistry of Sulfonic Acids. Sulfonic acids may be used to produce sulfonic acid esters, which are derived from epoxides, olefins, alkynes, aHenes, and ketenes, as shown in Figure 1 (10). Sulfonic acids may be converted to sulfonamides via reaction with an amine in the presence of phosphoms oxychloride [10025-87-3] POCl (H)- Because sulfonic acids are generally not converted directiy to sulfonamides, the reaction most likely involves a sulfonyl chloride intermediate. Phosphoms pentachlotide [10026-13-8] and phosphoms pentabromide [7789-69-7] can be used to convert sulfonic acids to the corresponding sulfonyl haUdes (12,13). The conversion may also be accompHshed by continuous electrolysis of thiols or disulfides in the presence of aqueous HCl [7647-01-0] (14) or by direct sulfonation with chlorosulfuric acid. Sulfonyl fluorides are typically prepared by direct sulfonation with fluorosulfutic acid [7789-21-17, or by reaction of the sulfonic acid or sulfonate with fluorosulfutic acid. Halogenation of sulfonic acids, which avoids production of a sulfonyl haUde, can be achieved under oxidative halogenation conditions (15). [Pg.95]

Anhydrous sulfonic acids, particularly linear alkylben2enesulfonic acids, are typically stored ia stainless steel containers, preferably type 304 or 316 stainless steel. Use of other metals, such as mild steel, contaminates the acid with iron (qv), causiag a darkening of the acid over time (27). The materials are usually viscous oils which may be stored and handled at 30—35°C for up to two months (27). AH other detergent-grade sulfonic acids, eg, alcohol sulfates, alcohol ether sulfates, alpha-olefin sulfonates, and alpha-sulfomethyl esters, are not stored owiag to iastabiUty. These are neutrali2ed to the desired salt. [Pg.98]

An example of a sulfite ester made from thionyl chloride is the commercial iasecticide endosulfan [115-29-7]. A stepwise reaction of thionyl chloride with two different alcohols yields the commercial miticide, propaigite [2312-35-8] (189). Thionyl chloride also has appHcations as a co-reactant ia sulfonations and chlorosulfonations. A patent describes the use of thionyl chloride ia the preparation of a key iatermediate, bis(4-chlorophenyl) sulfone [80-07-9] which is used to make a commercial polysulfone engineering thermoplastic (see Polymers CONTAINING SULFUR, POLYSULFONe) (190). The sulfone group is derived from chlorosulfonic acid the thionyl chloride may be considered a co-reactant which removes water (see Sulfolanes and sulfones). [Pg.142]

Reactions of the hydrocarbon chain in alkanoic acids include a-sulfonation and halogenation (51—54). The a-sulfonated fatty ester salts have excellent lime-dispersing properties and are valuable surface-active agents. [Pg.85]

Huang, W-Y, Chen, Q -Y In The Chemistry of Sulfonic Acids, Esters and... [Pg.973]

R Cu, or litliium or magnesium homocuprates RfCuM fM = Li, MgX), are fre-quently used, but a number of catalytic processes have also been developed. These processes nornnally utilize a catalytic amount of a copper salt CuY and a stoichiometric amount of an organometallic reagent R M IM = Li, MgX, ZnX, etc.). Hie leaving groups used include balides, esters, sulfonates, and epoxides, among others. [Pg.260]


See other pages where Sulfonates and Esters is mentioned: [Pg.10]    [Pg.10]    [Pg.233]    [Pg.233]    [Pg.5]    [Pg.181]    [Pg.377]    [Pg.37]    [Pg.377]    [Pg.429]    [Pg.14]    [Pg.10]    [Pg.10]    [Pg.233]    [Pg.233]    [Pg.5]    [Pg.181]    [Pg.377]    [Pg.37]    [Pg.377]    [Pg.429]    [Pg.14]    [Pg.502]    [Pg.391]    [Pg.469]    [Pg.44]    [Pg.75]    [Pg.83]    [Pg.95]    [Pg.99]    [Pg.100]    [Pg.103]    [Pg.109]    [Pg.198]    [Pg.200]    [Pg.244]    [Pg.65]    [Pg.150]    [Pg.138]    [Pg.81]    [Pg.1444]    [Pg.65]    [Pg.569]    [Pg.251]   


SEARCH



Ball, D. H., and Parrish, F. W., Sulfonic Esters of Carbohydrates

Formation of Ethers and Esters (Except Sulfonates)

Sulfonate 7 and

Sulfonate ester, formation from sulfonyl chloride and alcohol

Sulfonate esters

Sulfonic acids and esters

Sulfonic esters

Synthesis of Sulfonate and Phosphate Esters by PTC

© 2024 chempedia.info